Bond Lengths from X‐Ray Absorption‐Edge Fine Structure

1965 ◽  
Vol 43 (5) ◽  
pp. 1846-1847 ◽  
Author(s):  
Richard M. Levy
2002 ◽  
Vol 57 (5) ◽  
pp. 277-280 ◽  
Author(s):  
Yoshihiro Okamoto ◽  
Haruhiko Motohashi

The local structure of motlen ZrCl4 in LiCl-KCl eutectic was investigated by using an X-ray absorption fine structure (XAFS) of the Zr K-absorption edge. The nearest Zr4+-Cl- distance and coordination number from the curve fitting analysis were (2.51±0.02) Å and 5.9±0.6, respectively. These suggest that a 6-fold coordination (ZrCl6)2- is predominant in the molten mixture.


1986 ◽  
Vol 25 (Part 1, No. 2) ◽  
pp. 231-233 ◽  
Author(s):  
Toru Sasaki ◽  
Tomohiro Onda ◽  
Ryoichi Ito ◽  
Nagaatsu Ogasawara

2007 ◽  
Vol 22 (2) ◽  
pp. 122-125 ◽  
Author(s):  
T. N. Blanton ◽  
D. R. Whitcomb ◽  
S. T. Misture

Silver K edge extended X-ray absorption fine structure (EXAFS) spectroscopy of films containing silver behenate (AgBeh) in the unprocessed, fully processed, and step-processed states has been performed. The results of the EXAFS analysis indicate that the intensity for the real-space peak for the Ag-O distance (∼2.3 Å) decreases while the real-space peak for the Ag-Ag distance (∼2.9 Å) grows with increasing thermal processing of the film. The changes observed in the real-space EXAFS signal indicate the growth of metallic silver at the expense of AgBeh. The X-ray absorption near-edge spectroscopy (XANES) portion of the signal shows that the absorption edge position varies stepwise, with unprocessed films and pure AgBeh having an edge location at 25 506 eV, films processed from steps 1 through 10 have an absorption edge at 25 508 eV, and the fully processed film has an edge location at 25 512 eV.


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