Medium Rearrangement Energy in the Theory of the Solvated Electron

1972 ◽  
Vol 57 (1) ◽  
pp. 587-588 ◽  
Author(s):  
Joshua Jortner
Keyword(s):  
Solvated Electron ◽  
Rearrangement Energy

Electric field impact on solvated electron reactions: Trapping of randomly walking electron

1999 ◽  
Vol 111 (13) ◽  
pp. 6016-6025 ◽  
Author(s):  
S. G. Fedorenko ◽  
E. B. Krissinel ◽  
A. I. Burshtein
Keyword(s):  
Electric Field ◽  
Solvated Electron

Cells Containing Solvated Electron Lithium Negative Electrodes

1989 ◽  
Vol 136 (12) ◽  
pp. 3559-3565 ◽  
Author(s):  
Francisco A. Uribe ◽  
Krystyna W. Semkow ◽  
Anthony F. Sammells
Keyword(s):  
Solvated Electron ◽  
Negative Electrodes

Solvated electron in irradiated melts of alkaline halides

1982 ◽  
Vol 19 (5) ◽  
pp. 377-387 ◽  
Author(s):  
A.K. Pikaev ◽  
I.E. Makarov ◽  
T.N. Zhukova
Keyword(s):  
Solvated Electron

Article

1998 ◽  
Vol 76 (4) ◽  
pp. 411-413
Author(s):  
Yixing Zhao ◽  
Gordon R Freeman
Keyword(s):  
Absorption Spectrum ◽  
Optical Absorption ◽  
Temperature Dependence ◽  
Optical Absorption Spectrum ◽  
Infrared Light ◽  
Solvated Electron ◽  
Solvated Electrons ◽  
Tert Butanol ◽  
Solvent Dependence ◽  
Increasing Temperature

The energy and asymmetry of the optical absorption spectrum of solvated electrons, es- , change in a nonlinear fashion on changing the solvent through the series HOH, CH3OH, CH3CH3OH, (CH3)2CHOH, (CH3)3COH. The ultimate, quantum-statistical mechanical, interpretation of solvated electron spectra is needed to describe the solvent dependence. The previously reported optical spectrum of es- in tert-butanol was somewhat inaccurate, due to a small amount of water in the alcohol and to limitations of the infrared light detector. The present note records the remeasured spectrum and its temperature dependence. The value of the energy at the absorption maximum (EAmax) is 155 zJ (0.97 eV) at 299 K and 112 zJ (0.70 eV) at 338 K; the corresponding values of G epsilon max (10-22 m2 aJ-1) are 1.06 and 0.74. These unusually large changes are attributed to the abnormally rapid decrease of dielectric permittivity of tert-butanol with increasing temperature. The band asymmetry at 299 K is Wb/Wr = 1.8.Key words: optical absorption spectrum, solvated electron, solvent effects, tert-butanol, temperature dependence.

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