Intensity Perturbations and Breakdown of the Ordinary Selection Rules in the Infrared Spectrum of the Asymmetric Rotor

1970 ◽  
Vol 53 (6) ◽  
pp. 2147-2150
Author(s):  
J. Braslawsky
1955 ◽  
Vol 23 (3) ◽  
pp. 541-543 ◽  
Author(s):  
Girard L. Ordway ◽  
Paul C. Cross ◽  
Edward J. Bair

1996 ◽  
Vol 89 (4) ◽  
pp. 1145-1155
Author(s):  
JACQUES WALRAND ◽  
GHISLAIN BLANQUET ◽  
JEAN-FRANCOIS BLAVIER ◽  
HARALD BREDOHL ◽  
IWAN DUBOIS

1988 ◽  
Vol 49 (11) ◽  
pp. 1901-1910 ◽  
Author(s):  
F. Masset ◽  
L. Lechuga-Fossat ◽  
J.-M. Flaud ◽  
C. Camy-Peyret ◽  
J.W.C. Johns ◽  
...  

2003 ◽  
Vol 40 (12) ◽  
pp. 1014-1018 ◽  
Author(s):  
Shigeki TOKITA ◽  
Yasukazu IZAWA ◽  
Hideaki NIKI ◽  
Fumiyoshi KUWASHIMA

1962 ◽  
Vol 41 (2) ◽  
pp. 234-246 ◽  
Author(s):  
H. J. van der Molen

ABSTRACT A procedure for the quantitative determination of 5β-pregnan-3α-ol-20-one in urine is described. After acid hydrolysis of the pregnanolone-conjugates in urine, the free steroids are extracted with toluene. Pregnanolone is isolated in a pure form as its acetate; after chromatographic separation of the free steroids on alumina, the fraction containing pregnanolone is acetylated and rechromatographed on alumina. Quantitative determination of the isolated pregnanolone-acetate is carried out with the aid of the infrared spectrum recorded by a micro KBr-wafermethod. The reliability of the method under various conditions is discussed under the headings, specificity, accuracy, precision and sensitivity. It is possible to determine 30–40 μg pregnanolone in a 24-hours urine portion with a precision of 25%.


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