Optical Absorption and Fluorescence Spectra of Single‐Crystal TbF3

1969 ◽  
Vol 51 (9) ◽  
pp. 4006-4011 ◽  
Author(s):  
D. C. Krupka ◽  
H. J. Guggenheim
1968 ◽  
Vol 48 (5) ◽  
pp. 2342-2348 ◽  
Author(s):  
J. L. Fry ◽  
H. H. Caspers ◽  
H. E. Rast ◽  
S. A. Miller

1967 ◽  
Vol 47 (11) ◽  
pp. 4505-4514 ◽  
Author(s):  
H. H. Caspers ◽  
H. E. Rast ◽  
J. L. Fry

1989 ◽  
Vol 42 (12) ◽  
pp. 2201 ◽  
Author(s):  
J Ferguson ◽  
RJ Robbins ◽  
GJ Wilson

The absorption and fluorescence spectra of [2.21(9,10) anthraceno (1,4) naphthalenophane are reported. The anisotropy of the absorption bands was measured by two methods, ( i ) from fluorescence polarization ratios in a rigid glass and (ii) from single crystal absorption spectra at 23 K. The two states arising from the 1La states of the two chromophores were identified together with two states arising from other chromophore 1B2u states. Two states arising from the 1La states of the two chromophores were also identified. Whereas a coupled chromophore model accounts reasonably well for the latter two states, the energies and intensities of the bands arising from 1La chromophore states cannot be reconciled with this approach. Long axis polarized absorption intensity lying under the 1La, bands appears to be vibronically induced and not due to the 1Lb states. The absorption spectrum, fluorescence spectrum and fluorescence polarization ratios of a stable dimer were also observed. Its structure is similar to that of the stable dimer of anthracene in which the molecular long axes are parallel but the short axes make an angle of about 70� with each other.


2013 ◽  
Vol 17 (01n02) ◽  
pp. 99-103 ◽  
Author(s):  
Hui He ◽  
Jian-Yong Liu ◽  
Dennis K.P. Ng

This paper describes the preparation and spectral properties of a near-infrared fluorophore in which two bis(2-picolyl)amino moieties are axially linked to a silicon(IV) phthalocyanine core. The effects of various metal ions on its absorption and fluorescence spectra have been examined. The results indicate that this compound shows a high sensitivity and moderate selectivity toward Zn2+ ion.


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