Electrochromic semiconductor nanocrystal films

2002 ◽  
Vol 80 (1) ◽  
pp. 4-6 ◽  
Author(s):  
Congjun Wang ◽  
Moonsub Shim ◽  
Philippe Guyot-Sionnest
Nano Letters ◽  
2012 ◽  
Vol 12 (11) ◽  
pp. 5903-5906 ◽  
Author(s):  
Maximilian J. Berr ◽  
Florian F. Schweinberger ◽  
Markus Döblinger ◽  
Kai E. Sanwald ◽  
Christian Wolff ◽  
...  

Nanoscale ◽  
2018 ◽  
Vol 10 (17) ◽  
pp. 8042-8057 ◽  
Author(s):  
Willi Aigner ◽  
Oliver Bienek ◽  
Bruno P. Falcão ◽  
Safwan U. Ahmed ◽  
Hartmut Wiggers ◽  
...  

The exploitation of semiconductor nanocrystal (NC) films in novel electronic and optoelectronic applications requires a better understanding of charge transport in these systems.


2012 ◽  
Vol 86 (7) ◽  
Author(s):  
Stefan Kudera ◽  
Yang Zhang ◽  
Enzo Di Fabrizio ◽  
Liberato Manna ◽  
Roman Krahne

2019 ◽  
Author(s):  
Je-Ruei Wen ◽  
Benjamin Roman ◽  
Freddy Rodriguez Ortiz ◽  
Noel Mireles Villegas ◽  
Nicholas Porcellino ◽  
...  

Lack of detailed understanding of the growth mechanism of CsPbBr3 nanocrystals has hindered sophisticated morphological and chemical control of this important emerging optoelectronic material. Here, we have elucidated the growth mechanism by slowing the reaction kinetics. When 1-bromohexane is used as an alternative halide source, bromide is slowly released into the reaction mixture, extending the reaction time from ~3 seconds to greater than 20 minutes. This enables us to monitor the phase evolution of products over the course of reaction, revealing that CsBr is the initial species formed, followed by Cs4PbBr6, and finally CsPbBr3. Further, formation of monodisperse CsBr nanocrystals is demonstrated in a bromide-deficient and lead-abundant solution. The CsBr can only be transformed into CsPbBr3 nanocubes if additional bromide is added. Our results indicate a fundamentally different growth mechanism for CsPbBr3 in comparison with more established semiconductor nanocrystal systems and reveal the critical role of the chemical availability of bromide for the growth reactions.<br>


2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Chenhui Wang ◽  
Dengbao Han ◽  
Junhui Wang ◽  
Yingguo Yang ◽  
Xinyue Liu ◽  
...  

AbstractIn the field of perovskite light-emitting diodes (PeLEDs), the performance of blue emissive electroluminescence devices lags behind the other counterparts due to the lack of fabrication methodology. Herein, we demonstrate the in situ fabrication of CsPbClBr2 nanocrystal films by using mixed ligands of 2-phenylethanamine bromide (PEABr) and 3,3-diphenylpropylamine bromide (DPPABr). PEABr dominates the formation of quasi-two-dimensional perovskites with small-n domains, while DPPABr induces the formation of large-n domains. Strong blue emission at 470 nm with a photoluminescence quantum yield up to 60% was obtained by mixing the two ligands due to the formation of a narrower quantum-well width distribution. Based on such films, efficient blue PeLEDs with a maximum external quantum efficiency of 8.8% were achieved at 473 nm. Furthermore, we illustrate that the use of dual-ligand with respective tendency of forming small-n and large-n domains is a versatile strategy to achieve narrow quantum-well width distribution for photoluminescence enhancement.


Nano Letters ◽  
2021 ◽  
Author(s):  
James K. Utterback ◽  
Aditya Sood ◽  
Igor Coropceanu ◽  
Burak Guzelturk ◽  
Dmitri V. Talapin ◽  
...  

2010 ◽  
Vol 97 (22) ◽  
pp. 221105 ◽  
Author(s):  
S. S. Pan ◽  
Y. H. Tian ◽  
Y. Y. Luo ◽  
Y. X. Zhang ◽  
S. Wang ◽  
...  

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