Vacuum ultraviolet high‐resolution and high‐flux beamline for the Aladdin storage ring

1995 ◽  
Vol 66 (2) ◽  
pp. 2194-2196 ◽  
Author(s):  
R. Reininger ◽  
M. C. Severson ◽  
R. W. C. Hansen ◽  
W. R. Winter ◽  
M. A. Green ◽  
...  
Keyword(s):  
High Resolution ◽  
Storage Ring ◽  
Vacuum Ultraviolet ◽  
High Flux

Performance of the vacuum ultraviolet high-resolution and high-flux beamline for chemical dynamics studies at the Advanced Light Source

1997 ◽  
Vol 68 (5) ◽  
pp. 1945-1951 ◽  
Author(s):  
P. A. Heimann ◽  
M. Koike ◽  
C. W. Hsu ◽  
D. Blank ◽  
X. M. Yang ◽  
...  
Keyword(s):  
High Resolution ◽  
Light Source ◽  
Vacuum Ultraviolet ◽  
High Flux ◽  
Chemical Dynamics ◽  
Advanced Light Source

A compact vacuum-ultraviolet beamline for synchrotron radiation photoelectron spectroscopy combined with an ion-scattering spectrometer, SORIS

1998 ◽  
Vol 5 (3) ◽  
pp. 557-558 ◽  
Author(s):  
Hidetoshi Namba ◽  
Makoto Obara ◽  
Daisuke Kawakami ◽  
Tomoaki Nishimura ◽  
Yonglian Yan ◽  
...  
Keyword(s):  
High Resolution ◽  
Synchrotron Radiation ◽  
Storage Ring ◽  
Photoelectron Spectroscopy ◽  
Vacuum Ultraviolet ◽  
Beam Size ◽  
Medium Energy ◽  
Ion Scattering ◽  
Atomic Structures ◽  
Medium Energy Ion Scattering

Apparatus for high-resolution synchrotron radiation photoelectron spectroscopy combined with high-resolution medium-energy ion scattering, named `SORIS', has been developed for simultaneous investigations of electronic states and atomic structures on surfaces. For this purpose, a compact vacuum-ultraviolet beamline of photon energy from 5 to 700 eV has been designed for the small storage ring `Aurora' installed at Ritsumeikan University. Owing to the small electron-beam size in the storage ring, an energy resolution E/dE of >5000 can be obtained.

scholarly journals Kinetics of 1- and 2-methylallyl + O2 reaction, investigated by photoionisation using synchrotron radiation

2021 ◽  
Author(s):  
Domenik Schleier ◽  
Engelbert Reusch ◽  
Marius Gerlach ◽  
Tobias Preitschopf ◽  
Deb Pratim Mukhopadhyay ◽  
...  
Keyword(s):  
Synchrotron Radiation ◽  
Reaction Kinetics ◽  
Molecular Oxygen ◽  
Light Source ◽  
Storage Ring ◽  
Vacuum Ultraviolet ◽  
Flow Tube ◽  
Tube Reactor ◽  
Swiss Light Source ◽  
Kinetics Of

The reaction kinetics of the isomers of the methylallyl radical with molecular oxygen has been studied in a flow tube reactor at the vacuum ultraviolet (VUV) beamline of the Swiss Light Source storage ring.

scholarly journals Elemental ratio measurements of organic compounds using aerosol mass spectrometry: characterization, improved calibration, and implications

2015 ◽  
Vol 15 (1) ◽  
pp. 253-272 ◽  
Author(s):  
M. R. Canagaratna ◽  
J. L. Jimenez ◽  
J. H. Kroll ◽  
Q. Chen ◽  
S. H. Kessler ◽  
...  
Keyword(s):  
High Resolution ◽  
Vacuum Ultraviolet ◽  
Laboratory Data ◽  
Detailed Examination ◽  
Relative Difference ◽  
Data Set ◽  
Elemental Ratios ◽  
Standard Data ◽  
Aerosol Mass ◽  
Relative Errors

Abstract. Elemental compositions of organic aerosol (OA) particles provide useful constraints on OA sources, chemical evolution, and effects. The Aerodyne high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) is widely used to measure OA elemental composition. This study evaluates AMS measurements of atomic oxygen-to-carbon (O : C), hydrogen-to-carbon (H : C), and organic mass-to-organic carbon (OM : OC) ratios, and of carbon oxidation state (OS C) for a vastly expanded laboratory data set of multifunctional oxidized OA standards. For the expanded standard data set, the method introduced by Aiken et al. (2008), which uses experimentally measured ion intensities at all ions to determine elemental ratios (referred to here as "Aiken-Explicit"), reproduces known O : C and H : C ratio values within 20% (average absolute value of relative errors) and 12%, respectively. The more commonly used method, which uses empirically estimated H2O+ and CO+ ion intensities to avoid gas phase air interferences at these ions (referred to here as "Aiken-Ambient"), reproduces O : C and H : C of multifunctional oxidized species within 28 and 14% of known values. The values from the latter method are systematically biased low, however, with larger biases observed for alcohols and simple diacids. A detailed examination of the H2O+, CO+, and CO2+ fragments in the high-resolution mass spectra of the standard compounds indicates that the Aiken-Ambient method underestimates the CO+ and especially H2O+ produced from many oxidized species. Combined AMS–vacuum ultraviolet (VUV) ionization measurements indicate that these ions are produced by dehydration and decarboxylation on the AMS vaporizer (usually operated at 600 °C). Thermal decomposition is observed to be efficient at vaporizer temperatures down to 200 °C. These results are used together to develop an "Improved-Ambient" elemental analysis method for AMS spectra measured in air. The Improved-Ambient method uses specific ion fragments as markers to correct for molecular functionality-dependent systematic biases and reproduces known O : C (H : C) ratios of individual oxidized standards within 28% (13%) of the known molecular values. The error in Improved-Ambient O : C (H : C) values is smaller for theoretical standard mixtures of the oxidized organic standards, which are more representative of the complex mix of species present in ambient OA. For ambient OA, the Improved-Ambient method produces O : C (H : C) values that are 27% (11%) larger than previously published Aiken-Ambient values; a corresponding increase of 9% is observed for OM : OC values. These results imply that ambient OA has a higher relative oxygen content than previously estimated. The OS C values calculated for ambient OA by the two methods agree well, however (average relative difference of 0.06 OS C units). This indicates that OS C is a more robust metric of oxidation than O : C, likely since OS C is not affected by hydration or dehydration, either in the atmosphere or during analysis.

scholarly journals High Resolution Photoionization Spectrum of HBr Measured With Frequency Tripled Laser Radiation

1987 ◽  
Vol 7 (2-4) ◽  
pp. 129-139 ◽  
Author(s):  
Toshiaki Munakata ◽  
Tadahiko Mizukuki ◽  
Akira Misu ◽  
Motowo Tsukakoshi ◽  
Takahiro Kasuya
Keyword(s):  
Laser Radiation ◽  
High Resolution ◽  
Ultraviolet Radiation ◽  
Ground State ◽  
Vacuum Ultraviolet ◽  
Second Harmonic ◽  
Rydberg Series ◽  
Vacuum Ultraviolet Radiation ◽  
Ionization Limit ◽  
Photoionization Spectrum

The photoionization spectrum of HBr around the first ionization limit was measured at resolution of up to 5 x 10−4 nm. The ionizing vacuum ultraviolet radiation was generated by frequency tripling of the second harmonic output of a dye laser. Three sets of Rydberg series, each converging to the ground state (2Π3/2) of HBr+, were observed on the longer wavelength side of the ionization limit. By extrapolation of the Rydberg series, the ionization potential of HBr was determined to be 11.666 ± 0.001 eV.

Electronic structure of hexafluorobenzene by high-resolution vacuum ultraviolet photo-absorption and He(I) photoelectron spectroscopy

2006 ◽  
Vol 328 (1-3) ◽  
pp. 183-189 ◽  
Author(s):  
C. Motch ◽  
A. Giuliani ◽  
J. Delwiche ◽  
P. Limão-Vieira ◽  
N.J. Mason ◽  
...  
Keyword(s):  
Electronic Structure ◽  
High Resolution ◽  
Photoelectron Spectroscopy ◽  
Vacuum Ultraviolet
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