Field Test for Dissolved Ferrous Iron

Keyword(s):  
Soil Research ◽  
1981 ◽  
Vol 19 (2) ◽  
pp. 175 ◽  
Author(s):  
CW Childs

A 1 M solution of ammonium acetate containing �, �-dipyridyl indicator is recommended for use in field tests for exchangeable and water-soluble ferrous iron in soils. In using the test, a soil sample may be added to a vial containing the solution, or the solution can be sprayed on to a freshly exposed soil face. A field test for ferric-organic complexes in soils, using the same vials, is proposed. This is based on the photochemical nature of the reduction of ferric to ferrous iron in the presence of oxidizable organic ligands. Two subsamples of soil are added to separate vials, and light is excluded from one. After 5-15 min, a positive test for ferrous iron in the vial exposed to light, and a negative test in the other, indicates the presence of ferric-organic complexes.


Soil Research ◽  
1982 ◽  
Vol 20 (3) ◽  
pp. 261 ◽  
Author(s):  
JA Kennedy ◽  
HKJ Powell ◽  
JM White

A modification to Childs' field test for water-soluble and exchangeable ferrous iron in soils is described. To prevent redox decomposition of ferric-organic species, which is induced by the reagent �,�' -dipyridyl, a mixed NTA (nitrilotriacetic acid)-�,�-dipyridyl reagent at pH 7 is recommended.


2001 ◽  
Vol 70 (1) ◽  
pp. 33-46 ◽  
Author(s):  
Doncaster C. Patrick ◽  
Rondinini Carlo ◽  
Johnson Paul C. D.

Author(s):  
Richard D. Blomberg ◽  
David F. Preusser ◽  
Allen Hale ◽  
William A. Leaf

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