scholarly journals X-RAY ABSORPTION MEASUREMENTS OF ORGANIC SOLUTIONS OF ORGANOMETALLICS WITH SCINTILLATION COUNTING METHODS

1986 ◽  
Vol 47 (C8) ◽  
pp. C8-153-C8-157
Author(s):  
T. K. SHAM ◽  
R. A. HOLROYD ◽  
R. C. MUNOZ
1959 ◽  
Vol 31 (10) ◽  
pp. 1748-1748
Author(s):  
J. O. Hibbits ◽  
S. S. Cooper ◽  
M. R. Menke

1947 ◽  
Vol 19 (11) ◽  
pp. 861-865 ◽  
Author(s):  
H. A. Liebhafsky ◽  
H. M. Smith ◽  
H. E. Tanis ◽  
E. H. Winslow

1991 ◽  
Vol 257 ◽  
Author(s):  
Catherine Chisholm-Brause ◽  
Steven D. Conradson ◽  
P. Gary Eller ◽  
David E. Morris

ABSTRACTThe speciation of UO22+ and UO22+/ TBP mixtures has been investigated in solution and intercalated with the reference smectite clay SAz-1 using x-ray absorption, Raman, andluminescence spectroscopies. Neither aquated UO22+ nor its TBP complex undergoes any detectable changes in uranium oxidation state on intercalation. Further, at the pH values employed in this work, there is no evidence for hydrolysis of the uranium species to generate dimeric or higher order uranium oligomers. However, we do find indications that the structures of the solution complexes are altered on intercalation, particularly for the UO22+TBP system and for more dilute UO22+/aqueous systems. In addition, several lines of evidence suggest that, at the loading levels used in this study, the uranyl species is interacting with two or more spectroscopically distinguishable sites on SAz-1.


2020 ◽  
Vol 11 (31) ◽  
pp. 8306-8311
Author(s):  
Dmitri Mitcov ◽  
Mikhail Platunov ◽  
Christian D. Buch ◽  
Anders Reinholdt ◽  
Anders R. Døssing ◽  
...  

Magnetochiral Dichroism of chiral mononuclear lanthanoid complexes is for the first time detected by X-ray absorption measurements on single crystals of Holmium oxydiacetate, at the Ho L3-edge. The effect is of opposite sign for the two enantiomers.


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