scholarly journals Hard X-ray magnetochiral dichroism in a paramagnetic molecular 4f complex

2020 ◽  
Vol 11 (31) ◽  
pp. 8306-8311
Author(s):  
Dmitri Mitcov ◽  
Mikhail Platunov ◽  
Christian D. Buch ◽  
Anders Reinholdt ◽  
Anders R. Døssing ◽  
...  

Magnetochiral Dichroism of chiral mononuclear lanthanoid complexes is for the first time detected by X-ray absorption measurements on single crystals of Holmium oxydiacetate, at the Ho L3-edge. The effect is of opposite sign for the two enantiomers.

2004 ◽  
Vol 18 (20n21) ◽  
pp. 2841-2848 ◽  
Author(s):  
B. DALELA ◽  
S. DALELA ◽  
N. L. Saini ◽  
R. K. SINGHAL ◽  
C. T. Chen ◽  
...  

X-ray absorption measurements have been made on Cu L 3 and O K-edge on BSCCO (2212) single crystals annealed under two different conditions at 1 bar O 2 (under-doped) and another annealed in 1:4 ratio of O 2: Ar (optimally doped) using the F. Y. detection technique. Our results clearly indicate that hole density decreases while going towards c-axis from the ab plane. Our results shows that the doping holes have predominantly x, y symmetry compared to those having pz symmetry. The T c for both the crystals does not depend on the density of doping holes in the apical oxygen. However, the matter needs to be further explored.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Fridtjof Kielgast ◽  
Ivan Baev ◽  
Torben Beeck ◽  
Federico Pressacco ◽  
Michael Martins

AbstractMass-selected V and Fe monomers, as well as the heterodimer $${\text{Fe}}_1{\text{V}}_1$$ Fe 1 V 1 , were deposited on a Cu(001) surface. Their electronic and magnetic properties were investigated via X-ray absorption (XAS) and X-ray magnetic circular dichroism (XMCD) spectroscopy. Anisotropies in the magnetic moments of the deposited species could be examined by means of angle resolving XMCD, i.e. changing the X-ray angle of incidence. A weak adatom-substrate-coupling was found for both elements and, using group theoretical arguments, the ground state symmetries of the adatoms were determined. For the dimer, a switching from antiparallel to parallel orientation of the respective magnetic moments was observed. We show that this is due to the existence of a noncollinear spin-flop phase in the deposited dimers, which could be observed for the first time in such a small system. Making use of the two magnetic sublattices model, we were able to find the relative orientations for the dimer magnetic moments for different incidence angles.


1959 ◽  
Vol 31 (10) ◽  
pp. 1748-1748
Author(s):  
J. O. Hibbits ◽  
S. S. Cooper ◽  
M. R. Menke

2012 ◽  
Vol 20 (1) ◽  
pp. 166-171
Author(s):  
Vasil Koteski ◽  
Jelena Belošević-Čavor ◽  
Petro Fochuk ◽  
Heinz-Eberhard Mahnke

The lattice relaxation around Ga in CdTe is investigated by means of extended X-ray absorption spectroscopy (EXAFS) and density functional theory (DFT) calculations using the linear augmented plane waves plus local orbitals (LAPW+lo) method. In addition to the substitutional position, the calculations are performed for DX- and A-centers of Ga in CdTe. The results of the calculations are in good agreement with the experimental data, as obtained from EXAFS and X-ray absorption near-edge structure (XANES). They allow the experimental identification of several defect structures in CdTe. In particular, direct experimental evidence for the existence of DX-centers in CdTe is provided, and for the first time the local bond lengths of this defect are measured directly.


1947 ◽  
Vol 19 (11) ◽  
pp. 861-865 ◽  
Author(s):  
H. A. Liebhafsky ◽  
H. M. Smith ◽  
H. E. Tanis ◽  
E. H. Winslow

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