Morphological and optical properties of ultra‐thin nanostructured Cu films deposited by RF sputtering on nanoporous anodic alumina substrate

2016 ◽  
Vol 11 (6) ◽  
pp. 295-298 ◽  
Author(s):  
Mohamed Shaban ◽  
Ashour M. Ahmed ◽  
Ehab Abdel‐ Rahman ◽  
Hany Hamdy
Catalysts ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 10
Author(s):  
Yang Dang ◽  
Yu Cheng ◽  
Yukun Zhou ◽  
Yifei Huang ◽  
Kaige Wang

The treatment of organic dye contaminants in wastewaters has now becoming more imperative. Fenton-like degradation of methylene blue (MB) and methyl orange (MO) in aqueous solution was investigated by using a nanostructure that a layer of CuCl2 nanoflake film grown on the top surface of nanoporus anodic alumina substrate (nano-PAA-CuCl2) as catalyst. The new nano-PAA-CuCl2 composite was fabricated with self-assembly approach, that is, a network porous structure film composed of CuCl2 nanoflake grown on the upper surface of nanoporous anodic alumina substrate, and the physical and chemical properties are characterized systematically with the X-ray diffraction (XRD), field emission scanning electron microscope (FE-SEM), and high-resolution transmission electron microscopy (HRTEM), Energy Dispersive Spectrometer (EDS), X-ray photoelectron spectroscopy (XPS). The experimental results showed that the nano-PAA-CuCl2 catalyst presented excellent properties for the degradation of two typical organic pollutants such as MB and MO, which were almost completely degraded with 8 × 10−4mol/L nano-PAA-CuCl2 catalyst after 46 min and 60 min at reaction conditions of H2O2 18 mM and 23 mM, respectively. The effects of different reaction parameters such as initial pH, H2O2 concentration, catalyst morphology and temperature were attentively studied. And more, the stability and reusability of nano-PAA-CuCl2 were examined. Finally, the mechanism of MB and MO degradation by the nano-PAA-CuCl2/H2O2 system was proposed, based on the experimental data of the BCA and the temperature-programmed reduction (H2-TPR) and theoretical analysis, the reaction kinetics belonged to the pseudo-first-order equation. This new nanoporous composite material and preparation technology, as well as its application in Fenton-like reaction, provide an effective alternative method with practical application significance for wastewater treatment.


Author(s):  
Josep Ferré-Borrull ◽  
Elisabet Xifré-Pérez ◽  
Josep Pallarès ◽  
Lluis F. Marsal

2015 ◽  
Vol 2015 ◽  
pp. 1-9 ◽  
Author(s):  
Mohamed Shaban

Hexagonal nanoarrays of Au particles were deposited on nanoporous anodic alumina membrane (NAAM) utilizing r.f. magnetron sputtering. The thickness of the NAAMs is adjusted by changing the second anodization time from 5 min to 20 min. The surface morphology, composition, and optical properties are characterized by using SEM, EDX, and spectrophotometer, respectively. The effects of the NAAM thickness and state of polarization on the morphological changes and on the optical properties of the fabricated nanoarrays were addressed. According to the measured optical spectra, the rate of decrease of NAAMs refractive index was found to be 3.825 × 10−4 nm−1. Using the modified Kubelka-Munk radiative transfer model, the energy gap of NAAMs was calculated from diffused reflectance and was decreased from 1.682 to 1.376 as the anodization time increased from 5 to 20 min. Also, the saturation of interference fringes is substantially enhanced, and field enhancement can be achieved due to the excitation and constructive interference of surface plasmon waves by coating NAAMs with the hexagonal nanoarrays of Au. Based on the advantages of the fabrication approach and the enhanced and controlled properties, this new generation of samples can be used as promising building blocks for nanophotonic and nanoelectronics devices.


2019 ◽  
Vol 489 ◽  
pp. 239-246 ◽  
Author(s):  
Sara M. Aguilar-Sierra ◽  
Josep Ferré-Borrull ◽  
Félix E. Echeverría ◽  
Lluís F. Marsal

2014 ◽  
Vol 9 (1) ◽  
pp. 414 ◽  
Author(s):  
Laura P Hernández-Eguía ◽  
Josep Ferré-Borrull ◽  
Gerard Macias ◽  
Josep Pallarès ◽  
Lluís F Marsal

2015 ◽  
Vol 27 (19) ◽  
pp. 3019-3024 ◽  
Author(s):  
Tushar Kumeria ◽  
Jingxian Yu ◽  
Mohammed Alsawat ◽  
Mahaveer D. Kurkuri ◽  
Abel Santos ◽  
...  

Nanoscale ◽  
2021 ◽  
Author(s):  
Luis Pla ◽  
Felix Sancenón ◽  
M.Carmen Martinez-Bisbal ◽  
Celia Banuls ◽  
Nuria Estañ ◽  
...  

Many important human diseases, and specially cancer, have been related to the overproduction of 8-oxo-7,8-dihydro-2´-deoxyguanosine (8-oxo-dG). This molecule is a product of oxidative stress processes over nucleophilic bases in DNA....


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