Oxidative decarboxylation of amino acids by plant extracts

1988 ◽  
Vol 16 (6) ◽  
pp. 972-973 ◽  
Author(s):  
TERENCE A. SMITH ◽  
JACQUELINE H. A. MARSHALL
Keyword(s):  
Amino Acids ◽  
Plant Extracts ◽  
Oxidative Decarboxylation

Evaluation of different analytical methodologies for the analysis of amino acids in plant extracts

Planta Medica ◽  
2008 ◽  
Vol 74 (09) ◽  
Author(s):  
M Nasimullah Qureshi ◽  
G Stecher ◽  
MA Hashir ◽  
T Sultana ◽  
G Abel ◽  
...  
Keyword(s):  
Amino Acids ◽  
Plant Extracts

Chichibabin pyridinium synthesis via oxidative decarboxylation of photoexcited α-enamine acids

2021 ◽  
Author(s):  
Zhiqiang Pan ◽  
Fengchi Hu ◽  
Di Jiang ◽  
Yuchang Liu ◽  
Chengfeng Xia
Keyword(s):  
Amino Acids ◽  
Oxidative Decarboxylation

The photoexcited enamines derived from α-amino acids could undergo an oxidative decarboxylation followed by a Chichibabin cyclization to afford highly substituted pyridiniums.

ChemInform Abstract: Oxidative Decarboxylation of Cyclic Amino Acids and Dehydrogenation of Cyclic Secondary Amines with Iodosobenzene.

ChemInform ◽  
1989 ◽  
Vol 20 (26) ◽  
Author(s):  
M. OCHIAI ◽  
M. INENAGA ◽  
Y. NAGAO ◽  
R. M. MORIARTY ◽  
R. K. VAID ◽  
...  
Keyword(s):  
Amino Acids ◽  
Secondary Amines ◽  
Oxidative Decarboxylation ◽  
Cyclic Amino Acids

scholarly journals Greener Approach towards Corrosion Inhibition

2013 ◽  
Vol 2013 ◽  
pp. 1-10 ◽  
Author(s):  
Neha Patni ◽  
Shruti Agarwal ◽  
Pallav Shah
Keyword(s):  
Heavy Metals ◽  
Amino Acids ◽  
Plant Extracts ◽  
Corrosion Inhibitors ◽  
Organic Dyes ◽  
Plant Origin ◽  
Toxic Compounds ◽  
Green Inhibitors ◽  
Protective Films ◽  
Organic Corrosion Inhibitors

Corrosion control of metals is technically, economically, environmentally, and aesthetically important. The best option is to use inhibitors for protecting metals and alloys against corrosion. As organic corrosion inhibitors are toxic in nature, so green inhibitors which are biodegradable, without any heavy metals and other toxic compounds, are promoted. Also plant products are inexpensive, renewable, and readily available. Tannins, organic amino acids, alkaloids, and organic dyes of plant origin have good corrosion-inhibiting abilities. Plant extracts contain many organic compounds, having polar atoms such as O, P, S, and N. These are adsorbed on the metal surface by these polar atoms, and protective films are formed, and various adsorption isotherms are obeyed. Various types of green inhibitors and their effect on different metals are mentioned in the paper.

THE DIAGNOSIS OF MAPLE SYRUP URINE DISEASE (Branched-chain Ketoaciduria)

PEDIATRICS ◽  
1963 ◽  
Vol 32 (2) ◽  
pp. 234-238
Author(s):  
Joseph Dancis ◽  
Joel Hutzler ◽  
Mortimer Levitz
Keyword(s):  
Amino Acids ◽  
Maple Syrup Urine Disease ◽  
Oxidative Decarboxylation ◽  
Maple Syrup ◽  
Peripheral Leukocyte ◽  
Metabolic Block ◽  
Urine Disease ◽  
Branched Chain ◽  
Normal Leukocyte

The metabolism of the three branched-chain amino acids has been investigated in vitro, using the peripheral leukocyte. The normal leukocyte can transaminate and decarboxylate the three amino acids. These functions are demonstrable at birth. Five cases of maple syrup urine disease (branched-chain ketoaciduria) were studied. The peripheral leukocyte could transaminate the three amino acids, but decarboxylation was greatly reduced or absent. This confirms the site of metabolic block in maple syrup urine disease, and suggests an early and specific approach to diagnosis. Oxidative-decarboxylation of the branched-chain ketoacids involves an enzyme common to all three ketoacids.

scholarly journals Identification of Auxin Metabolites in Brassicaceae by Ultra-Performance Liquid Chromatography Coupled with High-Resolution Mass Spectrometry

Molecules ◽  
2019 ◽  
Vol 24 (14) ◽  
pp. 2615 ◽  
Author(s):  
Panagiota-Kyriaki Revelou ◽  
Maroula G. Kokotou ◽  
Violetta Constantinou-Kokotou
Keyword(s):  
Mass Spectrometry ◽  
Amino Acids ◽  
Liquid Chromatography ◽  
High Resolution ◽  
Plant Extracts ◽  
High Resolution Mass Spectrometry ◽  
Ultra Performance Liquid Chromatography ◽  
Charge Ratio ◽  
High Resolution Mass ◽  
Resolution Mass

Auxins are signaling molecules involved in multiple stages of plant growth and development. The levels of the most important auxin, indole-3-acetic acid (IAA), are regulated by the formation of amide and ester conjugates with amino acids and sugars. In this work, IAA and IAA amide conjugates with amino acids bearing a free carboxylic group or a methyl ester group, along with some selected IAA metabolites, were studied in positive and negative electrospray ionization (ESI) modes, utilizing high-resolution mass spectrometry (HRMS) as a tool for their structural analysis. HRMS/MS spectra revealed the fragmentation patterns that enable us to identify IAA metabolites in plant extracts from eight vegetables of the Brassicaceae family using a fast and reliable ultra-performance liquid chromatography quadrupole time-of-flight mass spectrometry (UPLC-QToF-MS) method. The accurate m/z (mass to charge) ratio and abundance of the molecular and fragment ions of the studied compounds in plant extracts matched those obtained from commercially available or synthesized compounds and confirmed the presence of IAA metabolites.

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