scholarly journals Sulphuretted hydrogen as a factor in the determination of free and bound amylase in ungerminated cereals

1936 ◽  
Vol 30 (3) ◽  
pp. 342-344 ◽  
Author(s):  
Tadeusz Chrząszcz ◽  
Józef Janicki
1883 ◽  
Vol 35 (224-226) ◽  
pp. 44-48

Our attention has been directed for some time to a new determination of the atomic weight of manganese. This communication gives a succinct account of the results of the preliminary stages of such an inquiry, and although the further progress of the investigation may reveal some errors, still we feel convinced the final numbers can in no way differ materially from the present values, and therefore further delay in publication is unnecessary. The atomic weight of manganese has been determined by many chemists, but the resulting values vary considerably according to the special method selected. The results of the different investigators may be divided into two classes—those giving approximately 55 as the number, and those making it about 54. To the former class belong Turner, Berzelius, and Dumas, all of whom use the same method, viz., the determination of the silver chloride yielded by a weighed amount of chloride of manganese. Turner also made determinations from the analysis of the carbonate, and from the conversion of the monoxide into sulphate. Von Hauer used the same method as that employed by him in the determination of the atomic weight of cadmium, viz., the reduction of manganous sulphate to sulphide by ignition in a current of sulphuretted hydrogen. It is probable that this method is not very trustworthy, as, according to Schneider, the sulphide may be contaminated by oxysulphide. Schneider and Rawack belong to the second class of observers, the former employing the oxalate, and from its analysis calculating the atomic weight by deducting the weight of water and carbon dioxide obtained. Rawack, whose experiments were conducted in Schneider’s laboratory, weighed the water obtained by reducing manganoso-manganic oxide to manganous oxide.


An advance in the technique of using the Jamin interferometer for the determination of the dispersion of gases has been effected by making a systematic allowance for fringe-drift by means of photographic measurements. New values of the refraction and dispersion of sulphur dioxide and sulphuretted hydrogen have been determined, reduced to ‘infinite dilution’ by means of newly measured pressure coefficients, in order to allow for departure from the gas laws. The refraction and dispersion of carbon oxysulphide have been measured for the first time.


1925 ◽  
Vol 15 (3) ◽  
pp. 307-326 ◽  
Author(s):  
WM. Goodwin ◽  
H. Martin

1. The reaction between lime sulphur and acid lead arsenate is shown to be small and to have little effect on the chemical properties of either material as a spray.2. It is shown that the oxidation of lime sulphur proceeds according to the empirical formula:CaS.Sx + 30 = CaS2O3 + Sx-1and that the calcium sulphides are hydrolysed in aqueous solution.3. The addition of lead arsenate has no effect on the amount of sulphur precipitated from the lime sulphur by oxidation or by the action of carbondioxide.4. Lead arsenate is only slightly decomposed by lime sulphur or by the oxidation products of lime sulphur, the main decomposition being due to the action of sulphuretted hydrogen formed by the hydrolysis of the calcium sulphides. This decomposition becomes marked in the presence of carbon dioxide which reacts on the calcium sulphide to form sulphuretted hydrogen.5. The fungicidal value of the mixed spray—as judged by the mildew killing properties of the polysulphides—is not less than that of lime sulphur alone. Additional fungicidal properties may be expected from the presence in the spray of soluble arsenates and thioarsenates.6. Judging by the chemical changes which take place in the mixed spray the insecticidal value of the lead arsenate would not appear to be greatly affected by the addition of lime sulphur.7. There is an increased amount of soluble arsenic formed by the action of carbon dioxide on the mixed spray which may prove sufficient in amount to cause spray injury.8. The A.O.A.C. method for the determination of sulphate sulphur in lime sulphur solutions is shown to be inaccurate. A method yielding more concordant results is proposed.


1966 ◽  
Vol 25 ◽  
pp. 93-97
Author(s):  
Richard Woolley

It is now possible to determine proper motions of high-velocity objects in such a way as to obtain with some accuracy the velocity vector relevant to the Sun. If a potential field of the Galaxy is assumed, one can compute an actual orbit. A determination of the velocity of the globular clusterωCentauri has recently been completed at Greenwich, and it is found that the orbit is strongly retrograde in the Galaxy. Similar calculations may be made, though with less certainty, in the case of RR Lyrae variable stars.


1999 ◽  
Vol 190 ◽  
pp. 549-554
Author(s):  
Nino Panagia

Using the new reductions of the IUE light curves by Sonneborn et al. (1997) and an extensive set of HST images of SN 1987A we have repeated and improved Panagia et al. (1991) analysis to obtain a better determination of the distance to the supernova. In this way we have derived an absolute size of the ringRabs= (6.23 ± 0.08) x 1017cm and an angular sizeR″ = 808 ± 17 mas, which give a distance to the supernovad(SN1987A) = 51.4 ± 1.2 kpc and a distance modulusm–M(SN1987A) = 18.55 ± 0.05. Allowing for a displacement of SN 1987A position relative to the LMC center, the distance to the barycenter of the Large Magellanic Cloud is also estimated to bed(LMC) = 52.0±1.3 kpc, which corresponds to a distance modulus ofm–M(LMC) = 18.58±0.05.


1961 ◽  
Vol 13 ◽  
pp. 29-41
Author(s):  
Wm. Markowitz
Keyword(s):  

A symposium on the future of the International Latitude Service (I. L. S.) is to be held in Helsinki in July 1960. My report for the symposium consists of two parts. Part I, denoded (Mk I) was published [1] earlier in 1960 under the title “Latitude and Longitude, and the Secular Motion of the Pole”. Part II is the present paper, denoded (Mk II).


1972 ◽  
Vol 1 ◽  
pp. 27-38
Author(s):  
J. Hers

In South Africa the modern outlook towards time may be said to have started in 1948. Both the two major observatories, The Royal Observatory in Cape Town and the Union Observatory (now known as the Republic Observatory) in Johannesburg had, of course, been involved in the astronomical determination of time almost from their inception, and the Johannesburg Observatory has been responsible for the official time of South Africa since 1908. However the pendulum clocks then in use could not be relied on to provide an accuracy better than about 1/10 second, which was of the same order as that of the astronomical observations. It is doubtful if much use was made of even this limited accuracy outside the two observatories, and although there may – occasionally have been a demand for more accurate time, it was certainly not voiced.


2000 ◽  
Vol 179 ◽  
pp. 205-208
Author(s):  
Pavel Ambrož ◽  
Alfred Schroll

AbstractPrecise measurements of heliographic position of solar filaments were used for determination of the proper motion of solar filaments on the time-scale of days. The filaments have a tendency to make a shaking or waving of the external structure and to make a general movement of whole filament body, coinciding with the transport of the magnetic flux in the photosphere. The velocity scatter of individual measured points is about one order higher than the accuracy of measurements.


1975 ◽  
Vol 26 ◽  
pp. 341-380 ◽  
Author(s):  
R. J. Anderle ◽  
M. C. Tanenbaum

AbstractObservations of artificial earth satellites provide a means of establishing an.origin, orientation, scale and control points for a coordinate system. Neither existing data nor future data are likely to provide significant information on the .001 angle between the axis of angular momentum and axis of rotation. Existing data have provided data to about .01 accuracy on the pole position and to possibly a meter on the origin of the system and for control points. The longitude origin is essentially arbitrary. While these accuracies permit acquisition of useful data on tides and polar motion through dynamio analyses, they are inadequate for determination of crustal motion or significant improvement in polar motion. The limitations arise from gravity, drag and radiation forces on the satellites as well as from instrument errors. Improvements in laser equipment and the launch of the dense LAGEOS satellite in an orbit high enough to suppress significant gravity and drag errors will permit determination of crustal motion and more accurate, higher frequency, polar motion. However, the reference frame for the results is likely to be an average reference frame defined by the observing stations, resulting in significant corrections to be determined for effects of changes in station configuration and data losses.


1979 ◽  
Vol 44 ◽  
pp. 349-355
Author(s):  
R.W. Milkey

The focus of discussion in Working Group 3 was on the Thermodynamic Properties as determined spectroscopically, including the observational techniques and the theoretical modeling of physical processes responsible for the emission spectrum. Recent advances in observational techniques and theoretical concepts make this discussion particularly timely. It is wise to remember that the determination of thermodynamic parameters is not an end in itself and that these are interesting chiefly for what they can tell us about the energetics and mass transport in prominences.


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