The heats of formation of metal halides. Titanium tetrabromide, with revised data on titanium tetrachloride

1957 ◽  
Vol 53 ◽  
pp. 1601 ◽  
Author(s):  
P. Gross ◽  
C. Hayman ◽  
D. L. Levi
Keyword(s):  
Titanium Tetrachloride ◽  
Heats Of Formation ◽  
Metal Halides ◽  
Titanium Tetrabromide

CO-ORDINATION COMPLEXES OF GROUP (IV) HALIDES: PREPARATION AND INFRARED SPECTRA OF THE CO-ORDINATION COMPOUNDS OF TITANIUM TETRACHLORIDE, TITANIUM TETRABROMIDE, ZIRCONIUM TETRACHLORIDE, TIN TETRACHLORIDE, AND BORON TRICHLORIDE WITH ETHYL CYANOACETATE AS LIGAND

1964 ◽  
Vol 42 (5) ◽  
pp. 1079-1083 ◽  
Author(s):  
Sumer Chand Jain ◽  
Roland Rivest
Keyword(s):  
Infrared Spectra ◽  
Titanium Tetrachloride ◽  
Ethyl Cyanoacetate ◽  
Group Iv ◽  
Membered Ring ◽  
Zirconium Tetrachloride ◽  
Experimental Conditions ◽  
Boron Trichloride ◽  
Titanium Tetrabromide ◽  
Tin Tetrachloride

Co-ordination compounds between ethyl cyanoacetate and boron trichloride, titanium tetrabromide, and tetrachlorides of titanium, zirconium, and tin have been prepared. The analytical results indicate that under similar experimental conditions, 1:1 addition compounds are obtained in each case. On the basis of infrared spectra it has been postulated that the compounds obtained are six-membered ring chelates, satisfying the most common co-ordination number six for the elements of group IV.

The heats of formation of metal halides. Niobium and tantalum pentachlorides

1960 ◽  
Vol 56 ◽  
pp. 318 ◽  
Author(s):  
P. Gross ◽  
C. Hayman ◽  
D. L. Levi ◽  
G. L. Wilson
Keyword(s):  
Heats Of Formation ◽  
Metal Halides

Some Metal Halide – Phosphorus Halide – Alkyl Halide Complexes. Part III. The µ-Trihalohexahalodimetallate Ions of Titanium and Zirconium

1974 ◽  
Vol 52 (16) ◽  
pp. 2880-2888 ◽  
Author(s):  
Joseph I. Bullock ◽  
Frederick W. Parrett ◽  
Nicholas J. Taylor
Keyword(s):  
Vibrational Spectroscopy ◽  
Titanium Tetrachloride ◽  
Alkyl Halide ◽  
Metal Halide ◽  
The Other ◽  
Butyl Chloride ◽  
Halide Complexes ◽  
Titanium Tetrabromide

Titanium tetrachloride reacts rapidly with trichloro-, tribromo- and methyldichlorophosphine in the presence of t-butyl chloride to give compounds containing a phosphonium cation R1R2PX2+ (R1 = t-butyl, R2 = chloride, bromide, or methyl, X = chloride or bromide) and the principal metal-containing anion, Ti2Cl9−. For tribromophosphine and t-butyl chloride a stoichiometric product, [ButPBr3][Ti2Cl9] was obtained which was characterized using vibrational spectroscopy. The other reactions gave non-stoichiometric materials, the sublimates of which may contain higher polymeric anions whilst the residues contained TiCl5− along with the parent dimeric anion.Zirconium tetrachloride and titanium tetrabromide reacted in a similar way to give the new ions Zr2Cl9− and Ti2Br9− in stoichiometric reactions.

COORDINATION COMPLEXES OF GROUP (IV) HALIDES: PREPARATION OF THE COMPLEXES OF TITANIUM TETRACHLORIDE, TITANIUM TETRABROMIDE, AND TIN TETRACHLORIDE WITH SOME THIO-, ISOTHIO-, AND ISO-CYANATE LIGANDS

1965 ◽  
Vol 43 (4) ◽  
pp. 787-791 ◽  
Author(s):  
Sumer Chand Jain ◽  
Roland Rivest
Keyword(s):  
Lewis Acid ◽  
Titanium Tetrachloride ◽  
Coordination Complexes ◽  
Group Iv ◽  
Experimental Conditions ◽  
Type Formula ◽  
Analytical Results ◽  
Ethyl Isocyanate ◽  
Titanium Tetrabromide ◽  
Tin Tetrachloride

Coordination complexes between ethyl thiocyanate, ethyl isothiocyanate, ethylene dithiocyanate, ethyl isocyanate, and tetrachlorides of titanium and tin and titanium tetrabromide have been prepared. The analytical results indicate that under different experimental conditions one can obtain compounds of the following type:[Formula: see text]where MX4 is a Lewis acid and L, L—L are mono- and bi-dentate ligands respectively. The complexes obtained are compared with the dinitrile complexes prepared by us previously (1).

Heats of formation of metal halides: pentabromides of niobium and tantalum

1962 ◽  
Vol 58 ◽  
pp. 890 ◽  
Author(s):  
P. Gross ◽  
C. Hayman ◽  
D. L. Levi ◽  
G. L. Wilson
Keyword(s):  
Heats Of Formation ◽  
Metal Halides

The heats of formation of metal halides. Aluminium fluoride

1954 ◽  
Vol 50 ◽  
pp. 477 ◽  
Author(s):  
P. Gross ◽  
C. Hayman ◽  
D. L. Levi
Keyword(s):  
Heats Of Formation ◽  
Metal Halides ◽  
Aluminium Fluoride
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