Photochemical generation and detection of an elusive rotamer of matrix-isolated mesityl oxide. Dispersive kinetics of the thermal isomerization: twisted s-trans? s-cis forms

1990 ◽  
pp. 2051 ◽  
Author(s):  
Jerzy Gebicki ◽  
Andrzej Plonka ◽  
Allen Krantz
Keyword(s):  
Thermal Isomerization ◽  
Mesityl Oxide ◽  
Photochemical Generation ◽  
Kinetics Of

A Kinetic Study of the Thermal Isomerization of and Related Complexes

1975 ◽  
Vol 53 (12) ◽  
pp. 1735-1738 ◽  
Author(s):  
William R. Cullen ◽  
Frank L. Hou
Keyword(s):  
Kinetic Study ◽  
Thermal Isomerization ◽  
Isomerization Reaction ◽  
Kinetics Of

The kinetics of the unimolecular isomerization reaction[Formula: see text]have been studied. The ΔH≠ values in kcal mol−1 are 36.8 ± 2.0 (M = M′ = Mn ), 46.8 ± 0.5 (M = M′ = Re ), 39.2 ± 2.8 (M = Mn, M′ = Re ). The mechanism of the rearrangement is discussed.

Kinetics of the Thermal Isomerization of Methylcyclopropane†

1999 ◽  
Vol 103 (3) ◽  
pp. 362-364 ◽  
Author(s):  
Bansi L. Kalra ◽  
Janet Y. Cho ◽  
David K. Lewis
Keyword(s):  
Thermal Isomerization ◽  
Kinetics Of

The Kinetics of the Thermal Isomerization of trans-Dichloroethylene

1940 ◽  
Vol 62 (12) ◽  
pp. 3480-3485 ◽  
Author(s):  
J. Leslie Jones ◽  
Robert L. Taylor
Keyword(s):  
Thermal Isomerization ◽  
Kinetics Of

Simultaneous photochemical generation of ozone in the gas phase and photolysis of aqueous reaction systems using one VUV light source

1997 ◽  
Vol 35 (4) ◽  
pp. 41-48 ◽  
Author(s):  
T.M. Hashem ◽  
M. Zirlewagen ◽  
A. M. Braun
Keyword(s):  
Gas Phase ◽  
Light Source ◽  
Organic Pollutants ◽  
Vacuum Ultraviolet ◽  
Oxidative Degradation ◽  
Reaction System ◽  
Photochemical Reactions ◽  
Experimental Conditions ◽  
Photochemical Generation ◽  
Kinetics Of

A more efficient use of vacuum ultraviolet (VUV) radiation produced by an immersed Xe-excimer light source (172 nm) was investigated for the oxidative degradation of organic pollutants in aqueous systems. All emitted VUV radiation from one light source was used in two simultaneous but separate photochemical reactions: (1) photochemical generation of ozone by irradiating oxygen in the gas phase and (2) photolysis of the aqueous reaction system. The gas stream containing the generated ozone is sparged into the reaction system, thus enhancing the oxidative degradation of organic pollutants. The photochemically generated ozone in the gas phase was quantitatively analyzed, and the kinetics of the degradation of 4-chlorophenol (4-CP) and of the dissolved organic carbon (DOC) were determined under different experimental conditions. The results show that the rates of degradation of the substrate and of the DOC decrease in the order of the applied processes, VUV/O3 > O3 > VUV.

Sign in / Sign up

Export Citation Format

Share Document