The Equilibrium and Kinetics of the Thermal Isomerization of Dichloroethylene Catalyzed by Iodine

1939 ◽  
Vol 61 (12) ◽  
pp. 3259-3263 ◽  
Author(s):  
Reuben E. Wood ◽  
Roscoe G. Dickinson
2012 ◽  
Vol 27 (2) ◽  
pp. 139-145 ◽  
Author(s):  
Dong XU ◽  
Jun ZHANG ◽  
Gang LI ◽  
Penny XIAO ◽  
Paul WEBLEY ◽  
...  

Water ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2031
Author(s):  
Ruben Miranda ◽  
Isabel Latour ◽  
Angeles Blanco

Effluent reuse is a common practice for sustainable industrial water use. Salt removal is usually carried out by a combination of membrane processes with a final reverse osmosis (RO). However, the presence of silica limits the RO efficiency due to its high scaling potential and the difficulty of cleaning the fouled membranes. Silica adsorption has many advantages compared to coagulation and precipitation at high pHs: pH adjustment is not necessary, the conductivity of treated waters is not increased, and there is no sludge generation. Therefore, this study investigates the feasibility of using pseudoboehmite and its calcination product (γ-Al2O3) for silica adsorption from a paper mill effluent. The effect of sorbent dosage, pH, and temperature, including both equilibrium and kinetics studies, were studied. γ-Al2O3 was clearly more efficient than pseudoboehmite, with optimal dosages around 2.5–5 g/L vs. 7.5–15 g/L. The optimum pH is around 8.5–10, which fits well with the initial pH of the effluent. The kinetics of silica adsorption is fast, especially at high dosages and temperatures: 80–90% of the removable silica is removed in 1 h. At these conditions, silica removal is around 75–85% (<50 mg/L SiO2 in the treated water).


1975 ◽  
Vol 53 (12) ◽  
pp. 1735-1738 ◽  
Author(s):  
William R. Cullen ◽  
Frank L. Hou

The kinetics of the unimolecular isomerization reaction[Formula: see text]have been studied. The ΔH≠ values in kcal mol−1 are 36.8 ± 2.0 (M = M′ = Mn ), 46.8 ± 0.5 (M = M′ = Re ), 39.2 ± 2.8 (M = Mn, M′ = Re ). The mechanism of the rearrangement is discussed.


1999 ◽  
Vol 103 (3) ◽  
pp. 362-364 ◽  
Author(s):  
Bansi L. Kalra ◽  
Janet Y. Cho ◽  
David K. Lewis

2014 ◽  
Vol 258 ◽  
pp. 412-419 ◽  
Author(s):  
Naresh Kumar Rotte ◽  
Subbareddy Yerramala ◽  
Jeyaraj Boniface ◽  
Vadali V.S.S. Srikanth

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