The stabilities of Meisenheimer complexes. Part XIII. Kinetic and equilibrium data for spiro-complex formation from 1-(2-mercaptoethylthio)- and 1-(2-hydroxyethylthio)-2,4,6-trinitrobenzene in water

1976 ◽  
pp. 901 ◽  
Author(s):  
Michael R. Crampton ◽  
Michael J. Willison
Keyword(s):  
Complex Formation ◽  
Meisenheimer Complexes ◽  
Equilibrium Data

scholarly journals Hydride-induced Meisenheimer complex formation reflects activity of nitro aromatic anti-tuberculosis compounds

2021 ◽  
Author(s):  
Rui Liu ◽  
Lowell Markley ◽  
Patricia A. Miller ◽  
Scott Franzblau ◽  
Gauri Shetye ◽  
...  
Keyword(s):  
Complex Formation ◽  
Nitroaromatic Compounds ◽  
Meisenheimer Complexes ◽  
Formation Efficiency ◽  
Nitro Aromatic

The formation efficiency of hydride-induced Meisenheimer complexes of nitroaromatic compounds is consistent with their anti-TB activities exemplied by MDL860 and benzothiazol N-oxide (BTO) analogs.

Possible Complex Formation of Actinides with Organic Matter and Phosphate in Deep Groundwaters. Speciation Calculations and Data Evaluation

1988 ◽  
Vol 127 ◽  
Author(s):  
Karin Aidersson
Keyword(s):  
Organic Matter ◽  
Humic Acid ◽  
Complex Formation ◽  
Data Evaluation ◽  
Deep Groundwater ◽  
Trivalent Actinides ◽  
Equilibrium Data ◽  
Phosphate Species ◽  
Solid Phases

ABSTRACTCalculations of solubility and speciation of U, Th, Ip, Pu, and An in a deep groundwater, containing humlc acid and phosphate have been performed, using the PHRBEQB equilibrium code. Where equilibrium data are missing, estimates have been made.Some of the studied complexes and solid phases may be of importance to the actinide behaviour in deep groundwaters, eg AmPO4(s) and several aqueous phosphate species and also humic acid for trivalent actinides.

Sign in / Sign up

Export Citation Format

Share Document