Strain effects in acyl transfer reactions. Part II. The kinetics of aminolysis of some N-aryl-lactams

1973 ◽  
pp. 981 ◽  
Author(s):  
G. Michael Blackburn ◽  
John D. Plackett
Keyword(s):  
Acyl Transfer ◽  
Transfer Reactions ◽  
Strain Effects ◽  
Acyl Transfer Reactions ◽  
Kinetics Of

The role of N-acetylcycloserine in the acyl transfer reactions

1970 ◽  
Vol 48 (2) ◽  
pp. 218-220
Author(s):  
W. J. D. Whish ◽  
T. Viswanatha
Keyword(s):  
Acyl Transfer ◽  
Transfer Reactions ◽  
Acyl Transfer Reactions ◽  
Kinetics Of

The ability of α-N-acetylcycloserine to participate in acyl transfer reactions has been investigated. The reaction with cinnamoylimidazole yields a stable monocinnamoyl intermediate, while that with p-nitrophenyl acetate yields a derivative which undergoes facile deacylation. The kinetics of acylation of α-N-acetylcycloserine and of the deacylation of its acetyl intermediate are reported.

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