Strain effects in acyl transfer reactions. Part I. The kinetics of hydrolysis of some N-aryl-lactams

1972 ◽  
pp. 1366 ◽  
Author(s):  
G. M. Blackburn ◽  
J. D. Plackett
Keyword(s):  
Acyl Transfer ◽  
Transfer Reactions ◽  
Strain Effects ◽  
Kinetics Of Hydrolysis ◽  
Acyl Transfer Reactions ◽  
Kinetics Of ◽  
Hydrolysis Of

The role of N-acetylcycloserine in the acyl transfer reactions

1970 ◽  
Vol 48 (2) ◽  
pp. 218-220
Author(s):  
W. J. D. Whish ◽  
T. Viswanatha
Keyword(s):  
Acyl Transfer ◽  
Transfer Reactions ◽  
Acyl Transfer Reactions ◽  
Kinetics Of

The ability of α-N-acetylcycloserine to participate in acyl transfer reactions has been investigated. The reaction with cinnamoylimidazole yields a stable monocinnamoyl intermediate, while that with p-nitrophenyl acetate yields a derivative which undergoes facile deacylation. The kinetics of acylation of α-N-acetylcycloserine and of the deacylation of its acetyl intermediate are reported.

Sign in / Sign up

Export Citation Format

Share Document