Chapter 6. Pulse radiolysis studies on reactive intermediates in organic chemical processes

1968 ◽  
Vol 65 ◽  
pp. 223 ◽  
Author(s):  
G. E. Adams
Author(s):  
Gerardo León Albert ◽  
Juan Ignacio Moreno Sánchez ◽  
José Manuel Moreno Angosto ◽  
José Antonio Fernández López ◽  
Beatriz Miguel Hernández

2001 ◽  
Vol 79 (2) ◽  
pp. 166-170 ◽  
Author(s):  
Z Abedinzadeh

Sulphur compounds play a central role in the structure and activity of many vital systems. In the living cell, sulfur constitutes an essential part of the defense against oxidative damage and is transformed into a variety of sulfur free radical species. Many studies of the chemistry of sulfur-centered radicals using pulse radiolysis and photolysis techniques to detect and measure the kinetics of these radicals have been published and reviewed. This paper discusses the present state of research on the formation and reactivity of certain sulfur-centered radicals [RS·, RSS·, RS·+, (RSSR)·+] and their implications for biological systems.Key words: sulfur-centered radicals, thiylradicals, sulfur-centered radical cation, cation radicals.


CCS Chemistry ◽  
2021 ◽  
pp. 1-18
Author(s):  
Carolin Schneider ◽  
Thomas Leischner ◽  
Pavel Ryabchuk ◽  
Ralf Jackstell ◽  
Kathrin Junge ◽  
...  

2013 ◽  
Vol 66 (2) ◽  
pp. 131 ◽  
Author(s):  
Ian R. Baxendale ◽  
Christian Hornung ◽  
Steven V. Ley ◽  
Juan de Mata Muñoz Molina ◽  
Anders Wikström

A bespoke microwave reactor with a glass containment cell has been developed for performing continuous flow reactions under microwave heating. The prototype unit has been evaluated using a series of standard organic chemical transformations enabling scale-up of these chemical processes. As part of the development, a carbon-doped PTFE reactor insert was utilized to allow the heating of poorly absorbing reaction media, increasing the range of solvents and scope of reactions that can be performed in the device.


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