114. The influence of electrolytic dissociation upon rates of reactions. Part III. The aquation of chloropentamminecobalt(III) in acidic salt solutions

1965 ◽  
pp. 724 ◽  
Author(s):  
S. H. Laurie ◽  
C. B. Monk
Keyword(s):  
Salt Solutions ◽  
Electrolytic Dissociation ◽  
Acidic Salt

ON THE MECHANISM OF THE DISSOLUTION OF MAGNESIUM IN ACIDIC SALT SOLUTIONS: I. PHYSICAL CONTROL BY SURFACE FILMS

1953 ◽  
Vol 31 (9) ◽  
pp. 849-867 ◽  
Author(s):  
E. J. Casey ◽  
R. E. Bergeron
Keyword(s):  
Ionic Strength ◽  
Chemical Control ◽  
Corrosion Potential ◽  
Surface Film ◽  
Surface Films ◽  
Salt Solutions ◽  
Acidic Solutions ◽  
Activity Temperature ◽  
Acidic Salt ◽  
High Concentrations

A kinetic study and analysis has been made of the effects of ionic strength, acid activity, temperature, and salt type on the dissolution of magnesium in acidic salt solutions. This is an example of the simplest type of corrosion involving hydrogen evolution. The results are interpreted in terms of the effects of the various factors on the structure of a surface film which must be magnesium oxide and/or hydroxide even in acidic solutions. The importance of internal dissolutions in the film at high concentrations of attacking reagent, for this and other cases, is shown. Owing to complex formation, under certain conditions an odd case of "chemical control" of the dissolution rate in this simplest case becomes evident. Corrosion potential measurements aid in the interpretation.

scholarly journals Dissolution of noble metals in highly concentrated acidic salt solutions

2020 ◽  
Vol 56 (59) ◽  
pp. 8230-8232
Author(s):  
Federica Forte ◽  
Sofia Riaño ◽  
Koen Binnemans
Keyword(s):  
Noble Metals ◽  
Environmentally Friendly ◽  
Platinum Group Metals ◽  
Salt Solutions ◽  
Concentrated Solutions ◽  
Aqua Regia ◽  
Acidic Salt ◽  
Platinum Group

Highly concentrated solutions of AlCl3·6H2O and Al(NO3)3·9H2O are safer and more environmentally friendly alternatives to aqua regia for the dissolution of gold and platinum group metals (Pd, Pt, Rh).

Congruent and Incongruent Dissolution of Labradorite in Dilute, Acidic, Salt Solutions

1991 ◽  
Vol 99 (3) ◽  
pp. 429-442 ◽  
Author(s):  
H. W. Nesbitt ◽  
N. D. MacRae ◽  
W. Shotyk
Keyword(s):  
Salt Solutions ◽  
Incongruent Dissolution ◽  
Acidic Salt

Isomorphous replacement in electron diffraction of wet crystals of rat hemoglobin

1983 ◽  
Vol 41 ◽  
pp. 446-447
Author(s):  
William F. Tivol ◽  
Murray Vernon King ◽  
D. F. Parsons
Keyword(s):  
Electron Diffraction ◽  
Heavy Atom ◽  
Isomorphous Substitution ◽  
X Ray Diffraction ◽  
Salt Solutions ◽  
X Ray ◽  
Isomorphous Replacement ◽  
Structure Factors ◽  
Diffraction Structure ◽  
The Mean

Feasibility of isomorphous substitution in electron diffraction is supported by a calculation of the mean alteration of the electron-diffraction structure factors for hemoglobin crystals caused by substituting two mercury atoms per molecule, following Green, Ingram & Perutz, but with allowance for the proportionality of f to Z3/4 for electron diffraction. This yields a mean net change in F of 12.5%, as contrasted with 22.8% for x-ray diffraction.Use of the hydration chamber in electron diffraction opens prospects for examining many proteins that yield only very thin crystals not suitable for x-ray diffraction. Examination in the wet state avoids treatments that could cause translocation of the heavy-atom labels or distortion of the crystal. Combined with low-fluence techniques, it enables study of the protein in a state as close to native as possible.We have undertaken a study of crystals of rat hemoglobin by electron diffraction in the wet state. Rat hemoglobin offers a certain advantage for hydration-chamber work over other hemoglobins in that it can be crystallized from distilled water instead of salt solutions.

Bulk standards for low-temperature biological x-ray microanalysis

1984 ◽  
Vol 42 ◽  
pp. 282-283
Author(s):  
P. Echlin ◽  
M. McKoon ◽  
E.S. Taylor ◽  
C.E. Thomas ◽  
K.L. Maloney ◽  
...  
Keyword(s):  
Phase Separation ◽  
Low Temperature ◽  
Analytical Method ◽  
Salt Solutions ◽  
Absolute Concentration ◽  
Cooling Process ◽  
X Ray ◽  
The Absolute ◽  
Analytical Procedures ◽  
Electrical Conductors

Although sections of frozen salt solutions have been used as standards for x-ray microanalysis, such solutions are less useful when analysed in the bulk form. They are poor thermal and electrical conductors and severe phase separation occurs during the cooling process. Following a suggestion by Whitecross et al we have made up a series of salt solutions containing a small amount of graphite to improve the sample conductivity. In addition, we have incorporated a polymer to ensure the formation of microcrystalline ice and a consequent homogenity of salt dispersion within the frozen matrix. The mixtures have been used to standardize the analytical procedures applied to frozen hydrated bulk specimens based on the peak/background analytical method and to measure the absolute concentration of elements in developing roots.

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