183. Metal chelates. Part I. A micromethod for the determination of the valency of a metal in a phthalocyanine complex

Author(s):  
J. A. Elvidge
1971 ◽  
Vol 43 (11) ◽  
pp. 1515-1516 ◽  
Author(s):  
Deenis. Gaede ◽  
Clifton E. Meloan

1994 ◽  
Vol 59 (10) ◽  
pp. 2209-2226 ◽  
Author(s):  
Josef Doležal ◽  
Lumír Sommer

The behaviour of stable and inert metal chelates of 4-(2-pyridylazo)resorcinol and 4-(2-thiazolylazo)resorcinol in RP HPLC and in its ion-pair modification (IP RP HPLC) on Separon SGX RPS silica gel was studied. Good results were obtained by the ion-pair variant in water methanol solutions at pH 7 in the presence of cetyltrimethylammonium bromide. The technique proved to be convenient for the preconcentration, separation and quantitation of low concentrations of Fe, Co, and Ni in waters.


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