Preparation and characterisation of some nitrogen-bridged phosphorus fluorides

1971 ◽  
pp. 1547 ◽  
Author(s):  
J. S. Harman ◽  
M. E. McCartney ◽  
D. W. A. Sharp
Keyword(s):  
Phosphorus Fluorides

Chemistry of phosphorus fluorides

1960 ◽  
Vol 16 (1-2) ◽  
pp. 52-59 ◽  
Author(s):  
E.L. Muetterties ◽  
T.A. Bither ◽  
M.W. Farlow ◽  
D.D. Coffman
Keyword(s):  
Phosphorus Fluorides

Chemistry of phosphorus fluorides. Part II. Secondary alkylamino derivatives of phosphoryl fluoride

1967 ◽  
Vol 45 (12) ◽  
pp. 1309-1319 ◽  
Author(s):  
R. G. Cavell
Keyword(s):  
Fluoride Salt ◽  
Equimolar Ratio ◽  
Hydrogen Halides ◽  
Physical Data ◽  
Phosphorus Fluorides ◽  
Derivatives Of

Phosphoryl fluoride reacts with dimethylamine in an equimolar ratio to yield volatile dimethylaminophosphoryldifluoride. The residual solid is a mixture of dimethylammonium hexafluorophosphate and dimethylammonium difluorophosphate salts rather than the simple fluoride salt. Dimethylamine reacts slowly with dimethylaminophosphoryldifluoride to yield bis(dimethylamino)phosphorylfluoride and the same complex fluorophosphate anions in the solid products. Physical data are reported on the alkylamino phosphoryl fluorides. The reaction of the difluorophosphoryl compound with hydrogen halides has been studied.

The reactions of phosphorus fluorides with lithium bis-trimethylsilylamide

1976 ◽  
Vol 28 ◽  
pp. 5-7 ◽  
Author(s):  
Leo Kling ◽  
Charles B. Colburn ◽  
William E. Hill
Keyword(s):  
Phosphorus Fluorides

Phosphorus-Fluorine Chemistry.

1964 ◽  
Vol 19 (12) ◽  
pp. 1101-1103 ◽  
Author(s):  
R. Schmutzler
Keyword(s):  
Lewis Acid ◽  
Fluorine Chemistry ◽  
Phosphorus Fluorides

Lewis acid phosphorus fluorides, such as C6H5PF4 and (C6H5) 2PF3, react with hexamethyl-disilazane to give polymeric iminophenyl-phosphonic- or -phosphinic fluorides, which can be dehydrofluorinated to phosphonitrilic type products.

Reactions of phosphorus fluorides and ortho-carborane ditertiary aminophosphines

1982 ◽  
Vol 21 (1) ◽  
pp. 22 ◽  
Author(s):  
C.B. Colburn ◽  
W.E. Hill ◽  
L.M. Silva-Trivino ◽  
R.D. Verma
Keyword(s):  
Phosphorus Fluorides

Reaction mechanisms of phosphorus fluorides: An ab initio study

1997 ◽  
Vol 83 (1) ◽  
pp. 27-30 ◽  
Author(s):  
Alexander F. Janzen ◽  
Xiaobo Ou ◽  
Michael G. Sowa
Keyword(s):  
Ab Initio ◽  
Reaction Mechanisms ◽  
Ab Initio Study ◽  
Phosphorus Fluorides

Phosphorus Fluorides

1970 ◽  
Vol 39 (1) ◽  
pp. 1-19 ◽  
Author(s):  
G I Drozd
Keyword(s):  
Phosphorus Fluorides
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