Chemistry of phosphorus fluorides. Part II. Secondary alkylamino derivatives of phosphoryl fluoride

1967 ◽  
Vol 45 (12) ◽  
pp. 1309-1319 ◽  
Author(s):  
R. G. Cavell
Keyword(s):  
Fluoride Salt ◽  
Equimolar Ratio ◽  
Hydrogen Halides ◽  
Physical Data ◽  
Phosphorus Fluorides ◽  
Derivatives Of

Phosphoryl fluoride reacts with dimethylamine in an equimolar ratio to yield volatile dimethylaminophosphoryldifluoride. The residual solid is a mixture of dimethylammonium hexafluorophosphate and dimethylammonium difluorophosphate salts rather than the simple fluoride salt. Dimethylamine reacts slowly with dimethylaminophosphoryldifluoride to yield bis(dimethylamino)phosphorylfluoride and the same complex fluorophosphate anions in the solid products. Physical data are reported on the alkylamino phosphoryl fluorides. The reaction of the difluorophosphoryl compound with hydrogen halides has been studied.

Chemistry of phosphorus fluorides. Part III. The reaction of thiophosphoryl-fluoride with dimethylamine and some properties of the dimethylaminothio- phosphoryl fluorides

1968 ◽  
Vol 46 (4) ◽  
pp. 613-621 ◽  
Author(s):  
R. G. Cavell
Keyword(s):  
Volatile Compound ◽  
Spectroscopic Data ◽  
Boron Trifluoride ◽  
Fluoride Salt ◽  
Hydrogen Halides ◽  
Unstable Complex ◽  
Phosphorus Fluorides ◽  
Complex Ion

Dimethylamine reacts with thiophosphoryl fluoride with non-integral stoichiometry to yield the volatile compound dimethylaminothiophosphoryldifluoride and the solid products contained hexafluoro-phosphate and difluorodithiophosphate ions, and an unstable complex ion containing phosphorus and fluorine. The reaction of dimethylaminothiophosphoryldifluoride with dimethylamine to form bis-(dimethylamino)thiophosphorylfluoride has also been studied. The solid residues of this reaction contained hexafluorophosphate and difluorodithiophosphate ions and an unidentified phosphorus-fluoride salt. Dimethylaminothiophosphoryldifluoride did not complex with boron trifluoride but reacted with hydrogen halides to yield the halogenothiophosphoryldifluorides. Physical and spectroscopic data on the alkylaminothiophosphoryl fluorides are reported.

ChemInform Abstract: Reaction of α-Polynitroalkyl Derivatives of Sulfur and Selenium with Hydrogen Halides and Halide Ions.

ChemInform ◽  
1990 ◽  
Vol 21 (19) ◽  
Author(s):  
V. I. ERASHKO ◽  
A. T. BARYSHNIKOV ◽  
N. I. ZUBANOVA ◽  
A. A. TISHANINOVA
Keyword(s):  
Halide Ions ◽  
Hydrogen Halides ◽  
Derivatives Of

Reaction of ?-polynitroalkyl derivatives of sulfur and selenium with hydrogen halides and halide ions

1989 ◽  
Vol 38 (9) ◽  
pp. 1939-1944
Author(s):  
V. I. Erashko ◽  
A. T. Baryshnikov ◽  
N. I. Zubanova ◽  
A. A. Tishaninova
Keyword(s):  
Halide Ions ◽  
Hydrogen Halides ◽  
Derivatives Of

Reaction of nido-[6,9-C2B8H10]2–with hydrogen halides. General synthesis of 5-substituted derivatives of arachno-6,9-C2B8H14

1985 ◽  
pp. 1365-1366 ◽  
Author(s):  
Bohumil Štibr ◽  
Zbyněk Janoušek ◽  
Jaromir Plešek ◽  
Tomáš Jelinek ◽  
Stanislav Heřmánek
Keyword(s):  
Hydrogen Halides ◽  
Derivatives Of ◽  
General Synthesis

Physical Properties of TCNQ Salts with N-Methyl Derivatives of Pyridine

1982 ◽  
Vol 85 (1) ◽  
pp. 257-263 ◽  
Author(s):  
A. Graja ◽  
M. Przybylski ◽  
B. Butka ◽  
R. Swietlik
Keyword(s):  
Physical Properties ◽  
Methyl Derivatives ◽  
Derivatives Of
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