Solubilization of some tetramethylammonium salts and of ethyltrimethylammonium bromide by their homologues in chloroform

Author(s):  
Jan Czapkiewicz
1996 ◽  
Vol 52 (3) ◽  
pp. 562-568 ◽  
Author(s):  
N. Nagel ◽  
P. Eller ◽  
H. Bock

Crystal structures of the dipotassium and potassium tetramethylammonium salts of benzene-1,2-disulfonic acid have been determined at 200 K and a PM3 enthalpy hypersurface for the substituent rotations of the free benzene-1,2-disulfonate dianion was calculated. The cogging of the two sulfonate groups as well as the possible pathways of conformational isomerization are discussed and compared with already investigated molecules containing adjacent threefold substituents.


2001 ◽  
Vol 66 (25) ◽  
pp. 8302-8308 ◽  
Author(s):  
Arturo Arduini ◽  
Giovanna Giorgi ◽  
Andrea Pochini ◽  
Andrea Secchi ◽  
Franco Ugozzoli

1975 ◽  
Vol 30 (3-4) ◽  
pp. 210-214 ◽  
Author(s):  
Rainer Mattes ◽  
Mohamed Moumen ◽  
Ingeborg Pernoll

The infrared and Raman spectra of potassium and tetramethylammonium salts of the dinuclear anions M2OX104- and M2NX8(H2O)23-, with M=Ru, Re and X=Cl, Br, have been registered and assigned on the basis of a normal coordinate analysis. The totally symmetric vibrations νsΜ2Ο (νsM2N), νsMXa,x(νsM—OH2) and δsOMX (δsNMX) show considerable mixing. The force constants of the bridge bonds are 3.9 mdyn/Å for the μ-oxo-and 5.1 mdyn/Å for the μ-nitrido-compounds, the respective stretch-stretch interaction constants 0.45 and 0.6 mdyn/Å.


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