Conversion of carbon monoxide into methanol at room temperature and atmospheric pressure

1985 ◽  
Vol 81 (1) ◽  
pp. 267 ◽  
Author(s):  
Kotaro Ogura ◽  
Shinji Yamasaki
Keyword(s):  
Carbon Monoxide ◽  
Atmospheric Pressure ◽  
Room Temperature

scholarly journals Cat-CrNP as new material with catalytic properties for 2-chloro-2-propen-1-ol and ethylene oligomerizations

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Jacek Malinowski ◽  
Dagmara Jacewicz ◽  
Artur Sikorski ◽  
Mariusz Urbaniak ◽  
Przemysław Rybiński ◽  
...  
Keyword(s):  
Complex Compound ◽  
Atmospheric Pressure ◽  
Room Temperature ◽  
Organometallic Compounds ◽  
Ethylene Oligomerization ◽  
High Catalytic Activity ◽  
New Material ◽  
Activity Requirement ◽  
Olefin Oligomerization ◽  
Xrd Method

AbstractThe contemporary search for new catalysts for olefin oligomerization and polymerization is based on the study of coordinating compounds and/or organometallic compounds as post-metallocene catalysts. However known catalysts are suffered by many flaws, among others unsatisfactory activity, requirement of high pressure or instability at high temperatures. In this paper, we present a new catalyst i.e. the crystalline complex compound possesing high catalytic activity in the oligomerization of olefins, such as 2-chloro-2-propen-1-ol and ethylene under very mild conditions (room temperature, 0.12 bar for ethylene oligomerization, atmospheric pressure for 2-chloro-2-propen-1-ol oligomerization). New material—Cat-CrNP ([nitrilotriacetato-1,10-phenanthroline]chromium(III) tetrahydrate) has been obtained as crystalline form of the nitrilotriacetate complex compound of chromium(III) with 1,10-phenanthroline and characterized in terms of its crystal structure by the XRD method and by multi-analytical investigations towards its physicochemical propeties The yield of catalytic oligomerization over Cat-CrNP reached to 213.92 g · mmol−1 · h−1· bar−1 and 3232 g · mmol−1 · h−1 · bar−1 for the 2-chloro-2-propen-1-ol and ethylene, respectively. Furthemore, the synthesis of Cat-CrNP is cheap, easy to perform and solvents used during preparation are environmentally friendly.

Carbon monoxide formation as an intermediate product in photocatalytic steam reforming of methane with lanthanum-doped sodium tantalate

2021 ◽  
Author(s):  
Wirya Sarwana ◽  
Akihiko Anzai ◽  
Daichi Takami ◽  
Akira Yamamoto ◽  
Hisao Yoshida
Keyword(s):  
Carbon Monoxide ◽  
Solar Energy ◽  
Steam Reforming ◽  
Intermediate Product ◽  
Room Temperature ◽  
Carbon Monoxide Formation ◽  
Steam Reforming Of Methane

Photocatalytic steam reforming of methane (PSRM) has been studied as an attractive method to produce hydrogen by utilizing photoenergy like solar energy around room temperature with metal-loaded photocatalysts, where methane...

scholarly journals Room-temperature carbon monoxide oxidation by oxygen over Pt/Al2O3 mediated by reactive platinum carbonates

2015 ◽  
Vol 6 (1) ◽  
Author(s):  
Mark A. Newton ◽  
Davide Ferri ◽  
Grigory Smolentsev ◽  
Valentina Marchionni ◽  
Maarten Nachtegaal
Keyword(s):  
Carbon Monoxide ◽  
Room Temperature ◽  
Carbon Monoxide Oxidation
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