Magneto-optical rotation studies of liquid mixtures. Part 6.—Specific interactions in mixtures of CCl4 with aliphatic and aromatic ketones and esters

1982 ◽  
Vol 78 (7) ◽  
pp. 2297 ◽  
Author(s):  
J. Graham Dawber
Keyword(s):  
Optical Rotation ◽  
Liquid Mixtures ◽  
Specific Interactions ◽  
Aromatic Ketones

Liquid mixtures involving complex formation : Extensions of the ideal associated solution theory

1977 ◽  
Vol 30 (7) ◽  
pp. 1401 ◽  
Author(s):  
DV Fenby ◽  
A Chand ◽  
A Inglese ◽  
JE Grolier ◽  
HV Kehiaian
Keyword(s):  
Hydrogen Bond ◽  
Complex Formation ◽  
Diethyl Ether ◽  
Liquid Mixtures ◽  
Specific Interactions ◽  
Bond Properties ◽  
Solution Theory ◽  
Associated Solution ◽  
The Ideal

Extensions of the ideal associated solution theory which take into account intermolecular interaction and/or size factors are derived and applied to triethylamine+ CHCl3 and diethyl ether+CHCl3. Evidence is presented for non-hydrogen-bonding specific interactions between the unlike molecules in these systems. Theories that do not take this into consideration are likely to be unsatisfactory for the determination of hydrogen-bond properties. With respect to the evaluation of ?net complex formation? properties, the extensions considered do not represent significant improvements of the simple theory. The molar enthalpies of mixing of triethylamine+CH3CCl, and diethyl ether+ CH3CCl3 have been measured at 288.15 and 298.15 K.

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