Ligands for the alkali metals. Part 6. Some bis(crown) Schiff bases which form pocket complexes with alkali-metal cations of appropriate size

1982 ◽  
pp. 2331 ◽  
Author(s):  
Timothy M. Handyside ◽  
Joyce C. Lockhart ◽  
Martin B. McDonnell ◽  
P. V. Subba Rao
Keyword(s):  
Alkali Metal ◽  
Schiff Bases ◽  
Alkali Metals ◽  
Metal Cations ◽  
Alkali Metal Cations

Theoretical Insights into Promotion Effect of Alkali Metal Cations on Electroreduction Mechanism of CO2 into C1 Products at Cu(111)/H2O Interface

2021 ◽  
Author(s):  
Lihui Ou ◽  
Hai Yang ◽  
Jun-Ling Jin ◽  
Yuandao Chen
Keyword(s):  
Alkali Metal ◽  
Alkali Metals ◽  
Metal Cations ◽  
Alkali Metal Cations ◽  
Promotion Effect ◽  
Co2 Electroreduction ◽  
Mechanistic Understanding ◽  
Electrochemical Interfaces

Mechanistic understanding on promotion effect of alkali metals on CO2 electroreduction into C1 products is carried out at Cu(111)/H2O electrochemical interfaces in this paper, in which Na and Cs with...

Association of radical anions with alkali metal cations; I. Modified π(PPP-like) method for the investigation of ion pairs

1980 ◽  
Vol 45 (2) ◽  
pp. 339-350 ◽  
Author(s):  
Stanislav Miertuš ◽  
Ondrej Kyseľ ◽  
Pavol Mach
Keyword(s):  
Alkali Metal ◽  
Alkali Metals ◽  
Ion Pairs ◽  
Metal Cations ◽  
Radical Anions ◽  
Alkali Metal Cations

A simple π-approximation (PPP-like) method was modified to enable study of the association of radical anions with alkali metals. The possible uses of the method are demonstrated by the calculations of the different properties of the pyrazine-Me (Me = Li, Na, Cs) system.

scholarly journals Enhancing electrocatalytic hydrogen evolution by nickel salicylaldimine complexes with alkali metal cations in aqueous media

2016 ◽  
Vol 52 (14) ◽  
pp. 2948-2951 ◽  
Author(s):  
Haiyan Shao ◽  
Subas K. Muduli ◽  
Phong D. Tran ◽  
Han Sen Soo
Keyword(s):  
Alkali Metal ◽  
Hydrogen Evolution ◽  
Coordination Sphere ◽  
Alkali Metals ◽  
Aqueous Media ◽  
Metal Cations ◽  
Alkali Metal Cations ◽  
Second Coordination Sphere

The pendant, chelating ethers in the second coordination sphere of nickel salicylaldimine complexes bind alkali metals to promote hydrogen evolution electrocatalysis.

scholarly journals The phenoxyl group-modulated interplay of cation–π and σ-type interactions in the alkali metal series

2020 ◽  
Vol 22 (46) ◽  
pp. 27105-27120
Author(s):  
Giacomo Prampolini ◽  
Marco d'Ischia ◽  
Alessandro Ferretti
Keyword(s):  
Alkali Metal ◽  
Noncovalent Interactions ◽  
Metal Cations ◽  
Alkali Metal Cations ◽  
Striking Effect

An extensive exploration of the interaction PESs of phenol and catechol complexes with alkali metal cations reveals a striking effect of –OH substitution on the balance between cation-π and σ-type noncovalent interactions.

Influence of Alkali Metal Cations on the Photodimerization of Bromo Cinnamates Studied by Solid-State NMR

2020 ◽  
Vol 124 (50) ◽  
pp. 27614-27620
Author(s):  
Marufa Zahan ◽  
He Sun ◽  
Sophia E. Hayes ◽  
Harald Krautscheid ◽  
Jürgen Haase ◽  
...  
Keyword(s):  
Solid State ◽  
Alkali Metal ◽  
Solid State Nmr ◽  
Metal Cations ◽  
Alkali Metal Cations

Derivation of Class II Force Fields. 4. van der Waals Parameters of Alkali Metal Cations and Halide Anions

1997 ◽  
Vol 101 (39) ◽  
pp. 7243-7252 ◽  
Author(s):  
Zhengwei Peng ◽  
Carl S. Ewig ◽  
Ming-Jing Hwang ◽  
Marvin Waldman ◽  
Arnold T. Hagler
Keyword(s):  
Alkali Metal ◽  
Force Fields ◽  
Van Der Waals ◽  
Metal Cations ◽  
Class Ii ◽  
Alkali Metal Cations ◽  
Halide Anions
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