Redox-potential–structure relationships in metal complexes. Part 4. Electron-poor dinitrogen complexes of rhenium(I)

1981 ◽  
pp. 800-804 ◽  
Author(s):  
G. Jeffery Leigh ◽  
Robert H. Morris ◽  
Christopher J. Pickett ◽  
David R. Stanley ◽  
Joseph Chatt
Keyword(s):  
Redox Potential ◽  
Metal Complexes ◽  
Dinitrogen Complexes ◽  
Potential Structure

Controllable and stable organometallic redox mediators for lithium oxygen batteries

2020 ◽  
Vol 7 (1) ◽  
pp. 214-222 ◽  
Author(s):  
Won-Jin Kwak ◽  
Atif Mahammed ◽  
Hun Kim ◽  
Trung Thien Nguyen ◽  
Zeev Gross ◽  
...  
Keyword(s):  
Redox Potential ◽  
Metal Complexes ◽  
Redox Mediators ◽  
Lithium Oxygen Batteries

We introduce corrole-chelated metal complexes as stable redox mediators with adjustable redox potential in lithium–oxygen batteries.

scholarly journals Preparation of Polymer-Bound Dinitrogen Complexes by Direct Reactions of Polymer–Metal Complexes with Molecular Nitrogen

1981 ◽  
Vol 13 (3) ◽  
pp. 247-253 ◽  
Author(s):  
Yoshimi Kurimura ◽  
Yasuhide Uchino ◽  
Fumihiko Ohta ◽  
Chikako Saito ◽  
Mikio Koide ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Molecular Nitrogen ◽  
Dinitrogen Complexes ◽  
Direct Reactions ◽  
Polymer Metal

Research inspired by the chemistry of nitrogenase — Novel metal complexes and their reactivity toward dinitrogen, nitriles, and alkynes

2005 ◽  
Vol 83 (4) ◽  
pp. 358-374 ◽  
Author(s):  
Masanobu Hidai ◽  
Yasushi Mizobe
Keyword(s):  
Nitrogen Fixation ◽  
Metal Complexes ◽  
Active Site ◽  
Bond Cleavage ◽  
Catalytic Reactions ◽  
Tertiary Phosphine ◽  
Tertiary Phosphines ◽  
Dinitrogen Complexes ◽  
And Tungsten

Summarized here are our continuous studies of the last three decades concerning syntheses of new types of complexes learned from nitrogenase and their reactivites toward dinitrogen, nitriles, and alkynes. For Mo and W dinitrogen complexes with tertiary phosphine coligands, a variety of their intriguing reactivities have been demonstrated, and novel transformations of the N2 ligands into numerous nitrogen-containing ligands and compounds have been developed. The C≡N bond cleavage of certain nitriles also proceeds on the Mo site surrounded by tertiary phosphines. Stimulated by the sophisticated structure of the active site of nitrogenase, multinuclear metal–sulfur complexes have been synthesized in rational ways. New types of stoichiometric and catalytic reactions of alkynes have been found by using the thiolato-bridged diruthenium complexes and some cubane-type sulfido clusters containing a noble metal.Key words: nitrogen fixation, molybdenum and tungsten dinitrogen complexes, ruthenium thiolato complexes, metal sulfido clusters, nitriles, alkynes.

ChemInform Abstract: REDOX POTENTIAL-STRUCTURE RELATIONSHIPS IN

1980 ◽  
Vol 11 (14) ◽  
Author(s):  
J. CHATT ◽  
G. J. LEIGH ◽  
H. NEUKOMM ◽  
C. J. PICKETT ◽  
D. R. STANLEY
Keyword(s):  
Redox Potential ◽  
Potential Structure
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