Thermoelectric properties of the silver nitrate + sodium nitrate system

1961 ◽  
Vol 32 ◽  
pp. 197 ◽  
Author(s):  
Ralph Schneebaum ◽  
Benson Ross Sundheim
Keyword(s):  
Silver Nitrate ◽  
Thermoelectric Properties ◽  
Sodium Nitrate ◽  
Nitrate System

Thermoelectric Properties of the Molten Silver Nitrate-Sodium Nitrate System1

1965 ◽  
Vol 69 (4) ◽  
pp. 1204-1208 ◽  
Author(s):  
Benson Ross Sundheim ◽  
Jordan D. Kellner
Keyword(s):  
Silver Nitrate ◽  
Thermoelectric Properties ◽  
Sodium Nitrate

Thermoelectric Studies of Silver Nitrate in Sodium Nitrate – Potassium Nitrate Eutectic Melt

1971 ◽  
Vol 49 (12) ◽  
pp. 2044-2047
Author(s):  
L. G. Boxall ◽  
K. E. Johnson
Keyword(s):  
Seebeck Coefficient ◽  
Silver Nitrate ◽  
Mole Fraction ◽  
Sodium Nitrate ◽  
Nitrate Concentration ◽  
Potassium Nitrate ◽  
Silver Nitrate Concentration ◽  
Eutectic Melt

The Seebeck coefficient, εT, of the thermocell Ag(T)/AgNO3 in NaNO3 − KNO3/Ag (T + ΔT) was measured as a function of silver nitrate concentration and temperature. Extrapolation of the results to unit mole fraction, N, of AgNO3 gave the value εT0 = − 277.5 − 0.136T °C (µV deg−1).For several mixed melts of AgNO3 and an alkali nitrate the function [Formula: see text] was calculated and shown to be linear in N. P was extrapolated to finite values for the pure alkali nitrates.

Studies on the thermodynamics and conductances of molten salts and their mixtures. Part VI. Calorimetric studies of sodium chlorate and its mixtures with sodium nitrate

1968 ◽  
Vol 46 (8) ◽  
pp. 1287-1291 ◽  
Author(s):  
A. N. Campbell ◽  
E. T. van der Kouwe
Keyword(s):  
Sodium Nitrate ◽  
Molten Salts ◽  
Sodium Chlorate ◽  
Heat Of Fusion ◽  
Heat Of Mixing ◽  
Lithium Nitrate ◽  
Entropy Of Fusion ◽  
Direct Experiment ◽  
Calorimetric Studies ◽  
Nitrate System

The following properties have been determined by direct experiment for pure sodium chlorate and its mixtures with sodium nitrate: heat capacity (both solid and liquid) and heat of fusion. From these experimental quantities, the following properties have been derived: entropy of fusion, heat of mixing, and free energy and entropy of mixing. The results have been compared with our previous results for the corresponding lithium chlorate – lithium nitrate system. On the whole, the conclusion is justified that the structure of melts containing lithium chlorate is more complex than that of melts involving sodium chlorate.

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