3D Printing of Metal-Organic Frameworks for Clean Energy and Environmental Applications

2021 ◽  
Author(s):  
Eleanor Rose Kearns ◽  
Rohan Gillespie ◽  
Deanna Michelle D'Alessandro
Keyword(s):  
3D Printing ◽  
Environmental Remediation ◽  
Metal Organic Frameworks ◽  
Clean Energy ◽  
Environmental Applications ◽  
The World ◽  
Co2 Levels ◽  
Metal Organic

The world is facing a climate emergency: unchecked pollution coupled with rising CO2 levels is putting unprecedented strain on the planet’s ecosystems. Technologies for environmental remediation are thus becoming increasingly...

Designing bipyridine-functionalized zirconium metal–organic frameworks as a platform for clean energy and other emerging applications

2018 ◽  
Vol 364 ◽  
pp. 33-50 ◽  
Author(s):  
Thach N. Tu ◽  
My V. Nguyen ◽  
Ha L. Nguyen ◽  
Brian Yuliarto ◽  
Kyle E. Cordova ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Clean Energy ◽  
Metal Organic ◽  
Zirconium Metal

Chromium Speciation in Zirconium‐Based Metal–Organic Frameworks for Environmental Remediation

2020 ◽  
Vol 26 (61) ◽  
pp. 13861-13872 ◽  
Author(s):  
Paula G. Saiz ◽  
Naroa Iglesias ◽  
Bárbara González Navarrete ◽  
Maibelin Rosales ◽  
Yurieth Marcela Quintero ◽  
...  
Keyword(s):  
Environmental Remediation ◽  
Metal Organic Frameworks ◽  
Chromium Speciation ◽  
Metal Organic

Reticular Chemistry and Metal-Organic Frameworks for Clean Energy

MRS Bulletin ◽  
2009 ◽  
Vol 34 (9) ◽  
pp. 682-690 ◽  
Author(s):  
Omar M. Yaghi ◽  
Qiaowei Li
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Frameworks ◽  
Clean Energy ◽  
Building Blocks ◽  
Zeolitic Imidazolate Frameworks ◽  
Design Concepts ◽  
Surface Areas ◽  
Molecular Building Blocks ◽  
Metal Organic ◽  
Molecular Aspects

AbstractReticular chemistry concerns the linking of molecular building blocks into predetermined structures using strong bonds. We have been working on creating and developing the conceptual and practical basis of this new area of research. As a result, new classes of crystalline porous materials have been designed and synthesized: metal-organic frameworks, zeolitic imidazolate frameworks, and covalent organic frameworks. Crystals of this type have exceptional surface areas (2,000−6,000 m2/g) and take up voluminous amounts of hydrogen (7.5 wt% at 77 K and 3−4 × 106 Pa), methane (50 wt% at 298 K and 2.5 × 106 Pa), and carbon dioxide (140 wt% at 298 K and 3 × 106 Pa). We have driven the basic science all the way to applications without losing sight of our quest for understanding the underlying molecular aspects of this chemistry. The presentation was focused on the design concepts, synthesis, and structure of these materials, with emphasis on their applications to onboard energy storage.

An Automated Machine Learning architecture for the accelerated prediction of Metal-Organic Frameworks performance in energy and environmental applications

2020 ◽  
Vol 300 ◽  
pp. 110160 ◽  
Author(s):  
Ioannis Tsamardinos ◽  
George S. Fanourgakis ◽  
Elissavet Greasidou ◽  
Emmanuel Klontzas ◽  
Konstantinos Gkagkas ◽  
...  
Keyword(s):  
Machine Learning ◽  
Metal Organic Frameworks ◽  
Environmental Applications ◽  
Metal Organic ◽  
Automated Machine Learning

scholarly journals Disappeared supramolecular isomer reappears with perylene guest

IUCrJ ◽  
2020 ◽  
Vol 7 (2) ◽  
pp. 324-330
Author(s):  
In-Hyeok Park ◽  
Atanu Dey ◽  
Kenta Sasaki ◽  
Masaaki Ohba ◽  
Shim Sung Lee ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Guest Molecule ◽  
Metal Organic Frameworks ◽  
Guest Molecules ◽  
Supramolecular Isomerism ◽  
The World ◽  
Different Types ◽  
Metal Organic ◽  
The Disappeared ◽  
Kinetic Form

Among different types of polymorphism, disappearing polymorphism deals with the metastable kinetic form which can not be reproduced after its first isolation. In the world of coordination polymers (CPs) and metal–organic frameworks (MOFs), despite the fact that many types of supramolecular isomerism exist, we are unaware of disappearing supramolecular isomerism akin to disappearing polymorphism. This work reports a MOF with dia topology that could not be reproduced, but subsequent synthesis yielded another supramolecular isomer, a double-pillared-layer MOF. When perylene was added in the same reaction, the disappeared dia MOF reappeared with perylene as a guest in the channels. Interestingly, the photoluminescence of the dia MOF with a perylene guest is dominated by the emission of the guest molecule. The influence of guest molecules on the stabilization of the supramolecular isomers of a MOF opens up a strategy to access MOFs with different structures.

One-pot synthesis of Cu-based metal-organic frameworks for environmental applications

2019 ◽  
Author(s):  
Monika Nehra ◽  
Deepak Kedia ◽  
Neeraj Dilbaghi ◽  
Ashraf Aly Hassan ◽  
Sandeep Kumar
Keyword(s):  
Metal Organic Frameworks ◽  
Environmental Applications ◽  
One Pot ◽  
One Pot Synthesis ◽  
Metal Organic
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