Benzoxazole-polymer@CCTO hybrid nanoparticles prepared via RAFT polymerization: toward poly(p-phenylene benzobisoxazole) nanocomposites with enhanced high-temperature dielectric properties

2021 ◽  
Author(s):  
Junhao Jiang ◽  
Jinpeng Li ◽  
Jun Qian ◽  
Xiaoyun Liu ◽  
Peiyuan Zuo ◽  
...  
Keyword(s):  
High Temperature ◽  
Dielectric Properties ◽  
Energy Density ◽  
Polymer Nanocomposites ◽  
Raft Polymerization ◽  
Dielectric Materials ◽  
High Energy ◽  
High Energy Density ◽  
Hybrid Nanoparticles

Polymer nanocomposites with high energy density have become a research hotspot in the field of dielectric materials. However, the huge compatibility contrast between nanofillers and polymers always hinders the further...

Ultrahigh Charge-discharge Efficiency and High Energy Density of High-temperature Polymer Sandwiched

2021 ◽  
Author(s):  
Hanxi Chen ◽  
Zhongbin Pan ◽  
Yu Cheng ◽  
Xiangping Ding ◽  
Jinjun Liu ◽  
...  
Keyword(s):  
High Temperature ◽  
Energy Density ◽  
Elevated Temperatures ◽  
Dielectric Materials ◽  
High Energy ◽  
High Energy Density ◽  
Capacitive Energy Storage ◽  
New Generation ◽  
Discharge Efficiency ◽  
Charge Discharge

A new generation of high-temperature dielectric materials toward capacitive energy storage is highly demanded as power electronics are always exposed to elevated temperatures in high-power applications. Polymer dielectric materials, an...

High temperature and high energy density dielectric materials

2009 ◽  
Author(s):  
Clive A. Randall ◽  
Hideki Ogihara ◽  
Jeong-Ryeol Kim ◽  
Gai-Ying Yang ◽  
Craig S. Stringer ◽  
...  
Keyword(s):  
High Temperature ◽  
Energy Density ◽  
Dielectric Materials ◽  
High Energy ◽  
High Energy Density

scholarly journals Polymer Nanocomposites with High Energy Density Utilizing Oriented Nanosheets and High-Dielectric-Constant Nanoparticles

Materials ◽  
2021 ◽  
Vol 14 (17) ◽  
pp. 4780
Author(s):  
Yushu Li ◽  
Yao Zhou ◽  
Sang Cheng ◽  
Jun Hu ◽  
Jinliang He ◽  
...  
Keyword(s):  
Dielectric Constant ◽  
Energy Density ◽  
Polymer Nanocomposites ◽  
High Dielectric Constant ◽  
Vinylidene Fluoride ◽  
Dielectric Materials ◽  
High Energy ◽  
High Energy Density ◽  
Capacitive Energy Storage ◽  
High Dielectric

The development of high-energy-density electrostatic capacitors is critical to addressing the growing electricity need. Currently, the widely studied dielectric materials are polymer nanocomposites incorporated with high-dielectric-constant nanoparticles. However, the introduction of high-dielectric-constant nanoparticles can cause local electric field distortion and high leakage current, which limits the improvement in energy density. In this work, on the basis of conventional polymer nanocomposites containing high-dielectric-constant nanoparticles, oriented boron nitride nanosheets (BNNSs) are introduced as an extra filler phase. By changing the volume ratios of barium titanate (BT) and BNNSs, the dielectric property of polymer nanocomposites is adjusted, and thus the capacitive energy storage performance is optimized. Experimental results prove that the oriented BNNSs can suppress the propagation of charge carriers and decrease the conduction loss. Using poly(vinylidene fluoride-co-hexafluoropropylene) (P(VDF-HFP)) as the polymer matrix, the P(VDF-HFP)/BNNS/BT nanocomposite has a higher discharged energy density compared with the conventional nanocomposite with the freely dispersed BT nanoparticles.

High-Temperature Polyimide Dielectric Materials for Energy Storage: Theory, Design, Preparation and Properties

2021 ◽  
Author(s):  
Xue-Jie Liu ◽  
Ming-Sheng Zheng ◽  
George Chen ◽  
Zhi-Min Dang ◽  
Jun-Wei Zha
Keyword(s):  
High Temperature ◽  
Energy Storage ◽  
Energy Density ◽  
Electric Vehicles ◽  
Operating Temperature ◽  
Dielectric Materials ◽  
High Energy ◽  
High Energy Density ◽  
Temperature Resistance ◽  
Storage Theory

The high operating temperature of dielectric capacitors applied in electric vehicles, aerospace and underground exploration require dielectric materials with high temperature resistance and high energy density. Polyimide (PI) turns out...

scholarly journals Recent Advances in the Synthesis of Polymer-Grafted Low-K and High-K Nanoparticles for Dielectric and Electronic Applications

Molecules ◽  
2021 ◽  
Vol 26 (10) ◽  
pp. 2942
Author(s):  
Bhausaheb V. Tawade ◽  
Ikeoluwa E. Apata ◽  
Nihar Pradhan ◽  
Alamgir Karim ◽  
Dharmaraj Raghavan
Keyword(s):  
Energy Density ◽  
Polymer Nanocomposites ◽  
High Performance ◽  
Breakdown Strength ◽  
Polymer Nanocomposite ◽  
High Energy ◽  
Polymer Chains ◽  
High Energy Density ◽  
Grafted Nanoparticles ◽  
Grafting From

The synthesis of polymer-grafted nanoparticles (PGNPs) or hairy nanoparticles (HNPs) by tethering of polymer chains to the surface of nanoparticles is an important technique to obtain nanostructured hybrid materials that have been widely used in the formulation of advanced polymer nanocomposites. Ceramic-based polymer nanocomposites integrate key attributes of polymer and ceramic nanomaterial to improve the dielectric properties such as breakdown strength, energy density and dielectric loss. This review describes the ”grafting from” and ”grafting to” approaches commonly adopted to graft polymer chains on NPs pertaining to nano-dielectrics. The article also covers various surface initiated controlled radical polymerization techniques, along with templated approaches for grafting of polymer chains onto SiO2, TiO2, BaTiO3, and Al2O3 nanomaterials. As a look towards applications, an outlook on high-performance polymer nanocomposite capacitors for the design of high energy density pulsed power thin-film capacitors is also presented.

Enhanced dielectric properties and thermostability in polyimide composites with core-shell structured polyimide@BaTiO3 nanoparticles

2021 ◽  
pp. 095400832199352
Author(s):  
Wei Deng ◽  
Guanguan Ren ◽  
Wenqi Wang ◽  
Weiwei Cui ◽  
Wenjun Luo
Keyword(s):  
Dielectric Constant ◽  
Dielectric Loss ◽  
Energy Density ◽  
Breakdown Strength ◽  
In Situ Polymerization ◽  
Dielectric Materials ◽  
High Energy ◽  
Amic Acid ◽  
High Energy Density ◽  
Core Shell

Polymer composites with high dielectric constant and thermal stability have shown great potential applications in the fields relating to the energy storage. Herein, core-shell structured polyimide@BaTiO3 (PI@BT) nanoparticles were fabricated via in-situ polymerization of poly(amic acid) (PAA) and the following thermal imidization, then utilized as fillers to prepare PI composites. Increased dielectric constant with suppressed dielectric loss, and enhanced energy density as well as heat resistance were simultaneously realized due to the presence of PI shell between BT nanoparticles and PI matrix. The dielectric constant of PI@BT/PI composites with 55 wt% fillers increased to 15.0 at 100 Hz, while the dielectric loss kept at low value of 0.0034, companied by a high energy density of 1.32 J·cm−3, which was 2.09 times higher than the pristine PI. Moreover, the temperature at 10 wt% weight loss reached 619°C, demonstrating the excellent thermostability of PI@BT/PI composites. In addition, PI@BT/PI composites exhibited improved breakdown strength and toughness as compared with the BT/PI composites due to the well dispersion of PI@BT nanofillers and the improved interfacial interactions between nanofillers and polymer matrix. These results provide useful information for the structural design of high-temperature dielectric materials.

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