Green water-induced spinel heterostructure interface enabling high performance lithium and manganese rich oxides

Author(s):  
Wenqiang Tu ◽  
Xian-Shu Wang ◽  
Wenying Tian ◽  
Yunan Zhou ◽  
Chuan Li ◽  
...  

Lithium and manganese rich oxides (LMROs) are promising candidates for the next-generation high-energy lithium-ion batteries. However, intrinsic problems associated with low initial Coulombic efficiency and inferior rate capability impede the...

2018 ◽  
Vol 2 (10) ◽  
pp. 1822-1828 ◽  
Author(s):  
Yan Li ◽  
Xinhai Li ◽  
Zhixing Wang ◽  
Huajun Guo ◽  
Tao Li ◽  
...  

LiNi0.8Co0.1Mn0.1O2 cathode derived from a novel [email protected](OH)2 hierarchical precursor exhibits improved tap density and initial coulombic efficiency, as well as excellent cycling stability and superior rate capability.


2015 ◽  
Vol 3 (6) ◽  
pp. 2634-2641 ◽  
Author(s):  
Hui Liu ◽  
Cheng Chen ◽  
Chunyu Du ◽  
Xiaoshu He ◽  
Geping Yin ◽  
...  

A lithium-rich Li1.2Ni0.13Co0.13Mn0.54O2 material coated by fast Li+ and electron conductors exhibits outstanding rate capability, cyclability and initial coulombic efficiency.


RSC Advances ◽  
2015 ◽  
Vol 5 (77) ◽  
pp. 63012-63016 ◽  
Author(s):  
Yourong Wang ◽  
Wei Zhou ◽  
Liping Zhang ◽  
Guangsen Song ◽  
Siqing Cheng

A SiO2@NiO core–shell electrode exhibits almost 100% coulombic efficiency, excellent cycling stability and rate capability after the first few cycles.


2013 ◽  
Vol 1540 ◽  
Author(s):  
Chia-Yi Lin ◽  
Chien-Te Hsieh ◽  
Ruey-Shin Juang

ABSTRACTAn efficient microwave-assisted polyol (MP) approach is report to prepare SnO2/graphene hybrid as an anode material for lithium ion batteries. The key factor to this MP method is to start with uniform graphene oxide (GO) suspension, in which a large amount of surface oxygenate groups ensures homogeneous distribution of the SnO2 nanoparticles onto the GO sheets under the microwave irradiation. The period for the microwave heating only takes 10 min. The obtained SnO2/graphene hybrid anode possesses a reversible capacity of 967 mAh g-1 at 0.1 C and a high Coulombic efficiency of 80.5% at the first cycle. The cycling performance and the rate capability of the hybrid anode are enhanced in comparison with that of the bare graphene anode. This improvement of electrochemical performance can be attributed to the formation of a 3-dimensional framework. Accordingly, this study provides an economical MP route for the fabrication of SnO2/graphene hybrid as an anode material for high-performance Li-ion batteries.


2019 ◽  
Vol 3 (9) ◽  
pp. 2361-2365 ◽  
Author(s):  
Xiaoyong Dou ◽  
Ming Chen ◽  
Jiantao Zai ◽  
Zhen De ◽  
Boxu Dong ◽  
...  

Silicon (Si) has been regarded as a promising next-generation anode material to replace carbon-based materials for lithium ion batteries (LIBs).


Nanoscale ◽  
2014 ◽  
Vol 6 (15) ◽  
pp. 8884-8890 ◽  
Author(s):  
Ye Wang ◽  
Guozhong Xing ◽  
Zhao Jun Han ◽  
Yumeng Shi ◽  
Jen It Wong ◽  
...  

Pre-lithiation of a MoS2/OLC nano-urchin hybrid structure shows great potential in developing good performance lithium ion batteries with ultra-high initial coulombic efficiency.


2018 ◽  
Vol 96 (3) ◽  
pp. 340-344
Author(s):  
Xia Zhang ◽  
Yan Li ◽  
Danqing Li ◽  
Yujun Zhang ◽  
Yuandong Xu

Molybdenum trioxide (MoO3) microplates are synthesized via the hydrothermal method and a simple heat treatment process without adding surfactant. Different hydrothermal reaction times and acidities are employed to explore the influence of preparation condition on the electrochemical performance for MoO3 microplates. These studies reveal that the hydrothermal time and acidity have a great impact on the morphology of MoO3 microplates. As anode materials for lithium-ion batteries (LIBs), the sheets-assembled MoO3 microplates with longer hydrothermal reaction time and proper acidity possess a superior morphology, which show better cycling performance and rate capability stability. The prepared MoO3 microplates display that the coulombic efficiency is around 100% during 50 cycles, demonstrating much better lithium storage properties. Considering the excellent electrochemical performance, the MoO3 microplates are considered to be a potential candidate in high-performance LIBs.


RSC Advances ◽  
2015 ◽  
Vol 5 (63) ◽  
pp. 50859-50864 ◽  
Author(s):  
Qingliang Xie ◽  
Zhibiao Hu ◽  
Chenhao Zhao ◽  
Shuirong Zhang ◽  
Kaiyu Liu

The LaF3-coated Li1.2Mn0.56Ni0.16Co0.08O2, compared with pristine Li1.2Mn0.56Ni0.16Co0.08O2, exhibits an enormous improvement in the initial coulombic efficiency and rate capability.


2017 ◽  
Vol 727 ◽  
pp. 688-692
Author(s):  
Ji Xiang Chen ◽  
Dong Lin Zhao ◽  
Ze Wen Ding ◽  
Cheng Li ◽  
Xia Jun Wang ◽  
...  

Shuttle-like CuO has been synthesized by treating commercial Cu(OH)2 powder at room temperature for an appropriate time. As anode material of lithium-ion batteries, shuttle-like CuO exhibits high specific capacity, high stability, and good rate performance, superior to commercial CuO powder. The shuttle-like CuO exhibited a high specific capacitance of 456.8 mAh g-1 at a current density of 100 mAg-1 and maintained a good stability in 50 cycles, suggesting that it can be a promising candidate for lithium-ion batteries. The high specific capacitance and remarkable rate capability are promising for applications in lithium-ion batteries with both high energy and power densities.


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