Recent Advances in Electrocatalytic Synthesis of 2,5-Furandicarboxylic Acid from 5-(Hydroxymethyl)furfural

2021 ◽  
Author(s):  
Yiyue Zhao ◽  
Mengke Cai ◽  
Jiahui Xian ◽  
Yamei Sun ◽  
Guangqin Li
Keyword(s):  
Biomass Conversion ◽  
Energy Crisis ◽  
Hydroxymethyl Furfural ◽  
Environmental Deterioration ◽  
Recent Advances ◽  
Furandicarboxylic Acid

Biomass conversion and biorefinery provide a feasible and novel way to release the increasingly serious energy crisis and environmental deterioration. 2,5-furandicarboxylic acid (FDCA) has received increasing attention as a significant...

Recent Advances of 2D Nanomaterials in the Electrode Materials of Lithium-Ion Batteries

NANO ◽  
2019 ◽  
Vol 14 (02) ◽  
pp. 1930001 ◽  
Author(s):  
Xiaobei Zang ◽  
Teng Wang ◽  
Zhiyuan Han ◽  
Lingtong Li ◽  
Xin Wu
Keyword(s):  
Lithium Ion Batteries ◽  
Electrode Materials ◽  
Electronic Devices ◽  
High Capacity ◽  
Lithium Ion ◽  
Energy Crisis ◽  
Two Dimensional ◽  
Long Cycle Life ◽  
Recent Advances ◽  
2D Nanomaterials

The upcoming energy crisis and the increasing power requirements of electronic devices have drawn enormous attention to research in the field of energy storage. Owing to compelling electrochemical and mechanical properties, two-dimensional nanomaterials can be used as electrodes on lithium-ion batteries to obtain high capacity and long cycle life. This review summarized the recent advances in the application of 2D nanomaterials on the electrode materials of lithium-ion batteries.

scholarly journals Pd/Au Based Catalyst Immobilization in Polymeric Nanofibrous Membranes via Electrospinning for the Selective Oxidation of 5-Hydroxymethylfurfural

Processes ◽  
2020 ◽  
Vol 8 (1) ◽  
pp. 45 ◽  
Author(s):  
Danilo Bonincontro ◽  
Francesco Fraschetti ◽  
Claire Squarzoni ◽  
Laura Mazzocchetti ◽  
Emanuele Maccaferri ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
Large Scale ◽  
Catalytic Performance ◽  
High Yield ◽  
Key Factors ◽  
Hydroxymethyl Furfural ◽  
Catalyst Immobilization ◽  
Polymeric Component ◽  
Furandicarboxylic Acid ◽  
Nanofibrous Membranes

Innovative nanofibrous membranes based on Pd/Au catalysts immobilized via electrospinning onto different polymers were engineered and tested in the selective oxidation of 5-(hydroxymethyl)furfural in an aqueous phase. The type of polymer and the method used to insert the active phases in the membrane were demonstrated to have a significant effect on catalytic performance. The hydrophilicity and the glass transition temperature of the polymeric component are key factors for producing active and selective materials. Nylon-based membranes loaded with unsupported metal nanoparticles were demonstrated to be more efficient than polyacrylonitrile-based membranes, displaying good stability and leading to high yield in 2,5-furandicarboxylic acid. These results underline the promising potential of large-scale applications of electrospinning for the preparation of catalytic nanofibrous membranes to be used in processes for the conversion of renewable molecules.

Two-dimensional metal–organic framework nanosheets for highly efficient electrocatalytic biomass 5-(hydroxymethyl)furfural (HMF) valorization

2020 ◽  
Vol 8 (39) ◽  
pp. 20386-20392
Author(s):  
Mengke Cai ◽  
Yawei Zhang ◽  
Yiyue Zhao ◽  
Qinglin Liu ◽  
Yinle Li ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Two Dimensional ◽  
Biomass Valorization ◽  
Hydroxymethyl Furfural ◽  
Highly Efficient ◽  
Electrocatalytic Performance ◽  
Metal Organic ◽  
Furandicarboxylic Acid ◽  
Organic Framework

2D metal–organic frameworks (MOFs) could promote biomass valorization, and electrooxidation of 5-(hydroxymethyl)furfural (HMF) into 2,5-furandicarboxylic acid (FDCA) with a highly efficient electrocatalytic performance.

Unsaturated Polyester Resins and Fiber-Reinforced Polymer Composites from Plant Biomass

2020 ◽  
Vol 869 ◽  
pp. 169-174
Author(s):  
Victor Klushin ◽  
Ekaterina Shabliy ◽  
Dmitry Petrenko
Keyword(s):  
Polymer Composites ◽  
Plant Biomass ◽  
Unsaturated Polyester ◽  
Fiber Reinforced Polymer ◽  
Fiber Reinforced ◽  
Polyester Resins ◽  
Hydroxymethyl Furfural ◽  
Reinforced Polymer ◽  
Fiber Reinforced Polymer Composites ◽  
Furandicarboxylic Acid

We are the first to report the synthesis of maleic acid in quantitative yield by oxidation of 5-hydroxymethyl furfural with hydrogen peroxide in the presence of sodium bicarbonate in an aqueous medium under ambient conditions without the using of toxic catalysts and solvents. 5-hydroxymethyl furfural and 2,5-furandicarboxylic acid have been prepared from hexose plant biomass. Based on maleic anhydride and 2,5-furandicarboxylic acid, unsaturated polyesters were synthesized for the first time from renewable raw materials only. A fiber-reinforced polymer composite based on these polyester resins have been prepared. Strength properties of carbon and glass fiber-reinforced polymer composites are 1.5 times superior to the strength of similar phthalic acid based composites.

Electrocatalytic Oxidation of Biomass-derived 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic acid Coupled with H2 Evolution

2021 ◽  
Vol 25 ◽  
Author(s):  
Ye Meng ◽  
Hu Li
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Electrocatalytic Oxidation ◽  
Value Added ◽  
Energy Crisis ◽  
Redox Mediators ◽  
Hydrogen Fuel ◽  
H2 Evolution ◽  
Fossil Energy ◽  
Furandicarboxylic Acid

: Simultaneous electrocatalytic conversion of biomass into high-value products and electrolysis of water for hydrogen are promising strategies to relieve the fossil energy crisis. Herein, we overview the recent advances and perspectives in the electrocatalytic oxidation of 5-hydroxymethylfurfural (HMF) and water reduction to synchronously produce value-added 2,5-furandicarboxylic acid (FDCA) and hydrogen fuel. Two strategies of bifunctional electrocatalysts and redox mediators are discussed. Oxidation of HME to FDCA was found to be more thermodynamically and kinetically favorable than the oxygen evolution reaction (OER). Moreover, the opportunities and challenges brought by them are presented.

Tunable mixed oxides based on CeO2 for the selective aerobic oxidation of 5-(hydroxymethyl)furfural to FDCA in water

2018 ◽  
Vol 20 (17) ◽  
pp. 3921-3926 ◽  
Author(s):  
Maria Ventura ◽  
Francesco Nocito ◽  
Elvira de Giglio ◽  
Stefania Cometa ◽  
Angela Altomare ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
Mixed Oxides ◽  
Aerobic Oxidation ◽  
Hydroxymethyl Furfural ◽  
Furandicarboxylic Acid ◽  
Selective Aerobic Oxidation

The selective oxidation of 5-HMF towards 2,5-furandicarboxylic acid (FDCA) has been achieved with 99% yield in water, using oxygen as the oxidant over CuO·MnO2·CeO2 mixed oxides.

Synthesis of Furanic Polyamides and Composite Coatings from Plant Biomass

2019 ◽  
Vol 816 ◽  
pp. 84-89
Author(s):  
V.A. Klushin ◽  
U.A. Chus ◽  
Nina Smirnova
Keyword(s):  
Molecular Weight ◽  
Plant Biomass ◽  
Biomass Conversion ◽  
Composite Coatings ◽  
Two Phase ◽  
Coating Materials ◽  
Organic System ◽  
Furandicarboxylic Acid ◽  
First Time ◽  
Aliphatic Polyamide

We report, for the first time, the synthesis of polyamide composite coating based on renewable plant biomass sources. 2,5-furandicarboxylic acid (FDCA) was prepared by catalytic oxidation of 5-hydroxymethylfurfural (HMF) obtained by plant biomass conversion. FDCA was used in the synthesis of aliphatic and aromatic furanic polyamides. Two approaches to furanic PAs synthesis have been investigated: (i) synthesis of hexamethylenediamine furanoate salt and its subsequent polycondensation; (ii) synthesis of FDCA dichloride and its subsequent polycondensation in a two-phase aqueous-organic system. The effect of the nature of organic solvent (tetraclormetan, dichloromethane, N-methyl-2-pyrrolidone) and the nature of diamine (hexamethylenediamine and paraphenylenediamine) on the yield and molecular weight of furanic polyamide was studied. The synthesized aliphatic polyamide was used for enamel fabrication. Colloidal graphite and activated carbon obtained from the waste of biomass conversion into HMF were used as fillers. The furanic PA composite coatings on steel provide the lower coefficient of friction and lower wear compared with that of commercial polyamide (PA6) coatings and can be considered as novel promising anti-friction coating materials.

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