The twinned Pd nanocatalyst exhibits sustainable NRR electrocatalytic performance by promoting the desorption of NH3

Author(s):  
Jianping Lai ◽  
Wenwen Cai ◽  
Yi Han ◽  
Yue Pan ◽  
Xinyi Zhang ◽  
...  

As ammonia is an important chemical raw material, a lot of efforts have been made in the field of electrochemical nitrogen reduction (NRR) to promote artificial nitrogen fixation. At present,...

Author(s):  
Chengqiang Gan ◽  
Wenya Yan ◽  
Yichi Zhang ◽  
Qianqian Jiang ◽  
Jianguo Tang

Ammonia (NH3) is an important chemical substance, widely used in agriculture, pharmaceuticals and industry. Nitrogen is 78% of the atmosphere, which is also the main raw material for the production...


Catalysts ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 974
Author(s):  
Bing Han ◽  
Haihong Meng ◽  
Fengyu Li ◽  
Jingxiang Zhao

Under the current double challenge of energy and the environment, an effective nitrogen reduction reaction (NRR) has become a very urgent need. However, the largest production of ammonia gas today is carried out by the Haber–Bosch process, which has many disadvantages, among which energy consumption and air pollution are typical. As the best alternative procedure, electrochemistry has received extensive attention. In this paper, a catalyst loaded with Fe3 clusters on the two-dimensional material C2N (Fe3@C2N) is proposed to achieve effective electrochemical NRR, and our first-principles calculations reveal that the stable Fe3@C2N exhibits excellent catalytic performance for electrochemical nitrogen fixation with a limiting potential of 0.57 eV, while also suppressing the major competing hydrogen evolution reaction. Our findings will open a new door for the development of non-precious single-cluster catalysts for effective nitrogen reduction reactions.


Author(s):  
Yu Zhang ◽  
Shihai Cao ◽  
Chu Liang ◽  
Jiaming Shen ◽  
Yeqing Chen ◽  
...  

Author(s):  
Xiaolin Wang ◽  
Li-Ming Yang

We for the first time report the discovery of a series of highly efficient electrocatalysts, i.e., transition metal anchored N/O-codoped graphene, for nitrogen fixation via high-throughput screening combined with first-principles...


Nanoscale ◽  
2019 ◽  
Vol 11 (21) ◽  
pp. 10439-10445 ◽  
Author(s):  
Xiaolan Xue ◽  
Renpeng Chen ◽  
Changzeng Yan ◽  
Yi Hu ◽  
Wenjun Zhang ◽  
...  

Bi2MoO6/OV-BiOBr heterojunctions are synthesized and show good photocatalytic activities for nitrogen reduction to ammonia under ambient conditions.


2019 ◽  
Vol 16 (32) ◽  
pp. 34-41
Author(s):  
Guilherme Rufatto SCHMIDT

Herb-mate is a raw material of great importance to Southern Brazil, considering its annual production of approximately 650,000 tons of leaves. The hot mate, known as chimarrão, is the most appreciated beverage and its consumption is linked to the traditions and cultural habits predominantly in the south of the country. Considering its huge importance, the objective of the work was to evaluate the production of laboratory herbmate for chimarrão in order to establish a comparison with the products available on the market. Therefore, it was considered the current legislation and the analysis of its organoleptic and granulometric properties, humidity level and concentration of some toxic metals quantified by inductively coupled plasma optical emission spectrometry. The manufacturing of the final product was made in three steps: first of all, the leaves were submitted to direct fire, then they were dried at a temperature of 40 Cº for 24 hours and, finally, they were ground in a knife mill for 10 minutes. The obtained results showed, in most of the analyzed characteristics, a great similarity between the laboratorial and commercial herb, obtaining approval from 90% of chimarrão consumers who participated in the organoleptic tests. However, the coloration was considered darker and can be explained by logistic problems between the plantation and the laboratory. There was also a divergence in the metals analysis, which showed a higher lead and cadmium concentration when compared to the herbs found on the supermarket shelves. Alarming numbers for consumers were found, since the commercial herbs pointed levels above the recommended for all analyzed metals, which indicate the urgent need for better inspection, as well as improved manufacturing practices of the final product and a better raw material cultivation.


2016 ◽  
Vol 70 (6) ◽  
pp. 613-627 ◽  
Author(s):  
Djordje Medarevic ◽  
Dusan Losic ◽  
Svetlana Ibric

Diatoms are widespread unicellular photosynthetic algae that produce unique highly ordered siliceous cell wall, called frustule. Micro- to nanoporous structure with high surface area that can be easily modified, high mechanical resistance, unique optical features (light focusing and luminescence) and biocompatibility make diatom frustule as a suitable raw material for the development of devices such as bio- and gas sensors, microfluidic particle sorting devices, supercapacitors, batteries, solar cells, electroluminescent devices and drug delivery systems. Their wide availability in the form of fossil remains (diatomite or diatomaceous earth) as well as easy cultivation in the artificial conditions further supports use of diatoms in many different fields of application. This review focused on the recent achievements in the diatom bioapplications such as drug delivery, biomolecules immobilization, bio- and gas sensing, since great progress was made in this field over the last several years.


Author(s):  
Łukasz Łuniewski ◽  
Barbara Gołębiewska

The aim of the research was to evaluate the sources of financing agricultural activities in farms specialized in milk production. The subject of research was a group of family farms located in the Podlaskie and Mazowieckie voivodeships (provinces). The criterion for farm division was the number of cows in the basic herd. There was also an assessment of the most important factors conducive to the development of dairy farms. To do so, the opinions of dairy farmers were used, and their views in this regard were expressed on a five-point Likert scale. The research was conducted on a sample of 100 farms in 2021. The interpretation of the results was made in relation to the criterion adopted in the division of farms into quartiles. It was found that the main source of financing activities in dairy farms was own funds. The highest share of farms using commercial loans was in the group of farms with the largest number of cows. With an increase in the number of cows in a herd, the area of farms increased, which is understandable due to the need to produce roughage. The most important factors influencing the development possibilities of agricultural holdings were the uninterrupted collection of raw material and a stable milk purchase price, which guaranteed the farmers’ financial liquidity.


2018 ◽  
Vol 17 (1) ◽  
pp. 70
Author(s):  
S.M. Sarwadana ◽  
B.R.T. Putri ◽  
K.K. Dinata

Activities of science and technology for innovation and creativity campus aims are: (1) thecommercialization of science and technology campus creativity as a source of financing for the developmentof institutions; (2) stimulate the entrepreneurial spirit among beings campus, and (3) help people get seeds ofdrought-tolerant maize varieties. Methods of execution include the business aspects of the planned businessactivities consist of: provision of raw materials, production processes, management, marketing, humanresources, facilities, and financial. The raw material is obtained from units of science and technology fornovation and creativity campus and through partnerships with farmers' seed corn. The production processstarted from seed, sorting, and packaging. Marketing is done directly, partnerships with local governmentsand konsiniasi with kiosk / farm shop. Results show that the activities of science and technology unit forinnovation and creativity campus drought-tolerant maize seed has gone well characterized by supportinfrastructure adequate maize seed production; IbIKK unit operates under the management of PSAgroecotechnology Faculty of Agriculture, University of Udayana; Of investment made in 2014 amountingto Rp. 39,550,000; Result of sales corn seeds turnover in 2014 amounted to 400 kg (Rp. 12 million); and netcash flow amounted to 17,672,400.


2014 ◽  
Vol 79 (4) ◽  
pp. 782-793 ◽  
Author(s):  
John W. Ives ◽  
Duane Froese ◽  
Matthew Collins ◽  
Fiona Brock

AbstractThe Grenfell bone rod resembles other instances of Clovis-era organic or osseous technology and has on a number of occasions been considered with other Clovis bone, antler, and ivory rods or beveled artifacts. It had been suspected of being constructed from proboscidean long bone. As an early discovery (made in 1883), the Grenfell artifact had somewhat obscure provenience details and a lengthy curatorial history. We describe accelerator mass spectrometry and zooarchaeology by mass spectrometry methods that allow rapid, minimally destructive determinations of both the age and the raw material composition of osseous artifacts. Our analysis reveals that the Grenfell artifact is actually a terminal Paleoindian-era manifestation made of bison bone. Similar methods could be more widely applied in North America in order to build more refined data sets for osseous technologies. These results also reveal the ease with which archaeologists can secure additional information from existing collections, highlighting our ethical obligations to do so.


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