Synergistic combination of the nanoporous system of MOF-808 with polyoxomolybdate to design an effective catalyst: simultaneous oxidative desulfurization and denitrogenation processes

2021 ◽  
Author(s):  
Simone Coelho Fernandes ◽  
Alexandre Viana ◽  
Baltazar de Castro ◽  
Luis Cunha-Silva ◽  
Salete S. Balula
Keyword(s):  
Oxidative Desulfurization ◽  
Effective Catalyst ◽  
In Situ Method ◽  
Synergistic Combination ◽  
First Time

The encapsulation of the polyoxomolybdate, H3(PMo12O40).nH2O (PMo12) in the nanoporous MOF-808 framework was carried-out for the first time by a straightforward in-situ method based on a “bottle-around-the ship” approach, to...

scholarly journals Novel Bionanocellulose/κ-Carrageenan Composites for Tissue Engineering

2018 ◽  
Vol 8 (8) ◽  
pp. 1352 ◽  
Author(s):  
Izabela Cielecka ◽  
Marcin Szustak ◽  
Edyta Gendaszewska-Darmach ◽  
Halina Kalinowska ◽  
Małgorzata Ryngajłło ◽  
...  
Keyword(s):  
Tissue Engineering ◽  
Chondrogenic Differentiation ◽  
Expression Patterns ◽  
Swelling Properties ◽  
In Situ Method ◽  
Chondrogenic Phenotype ◽  
The Impact ◽  
First Time ◽  
Water Holding

In this work, novel bacterial cellulose/κ-carrageenan (BNC/κ-Car) composites, being potential scaffolds for tissue engineering (TE), and outperforming the two polymers when used as scaffolds separately, were for the first time obtained using an in situ method, based on the stationary culture of bacteria Komagateibacter xylinus E25. The composites were compared with native BNC in terms of the morphology of fibers, chemical composition, crystallinity, tensile and compression strength, water holding capacity, water retention ratio and swelling properties. Murine chondrogenic ATDC5 cells were applied to assess the utility of the BNC/κ-Car composites as potential scaffolds. The impact of the composites on the cells viability, chondrogenic differentiation, and expression patterns of Col1α1, Col2α1, Runx2, and Sox9, which are indicative of ATDC5 chondrogenic differentiation, was determined. None of the composites obtained in this study caused the chondrocyte hypertrophy. All of them supported the differentiation of ATDC5 cells to more chondrogenic phenotype.

Preparation of high performance perovskite-sensitized nanoporous titanium dioxide photoanodes by in situ method for use in perovskite solar cells

2014 ◽  
Vol 2 (39) ◽  
pp. 16531-16537 ◽  
Author(s):  
Yaoming Xiao ◽  
Gaoyi Han ◽  
Yanping Li ◽  
Miaoyu Li ◽  
Yunzhen Chang ◽  
...  
Keyword(s):  
Titanium Dioxide ◽  
Solar Cells ◽  
High Performance ◽  
Perovskite Solar Cells ◽  
In Situ Method ◽  
First Time ◽  
Nanoporous Titanium Dioxide

A high performance Perovskite-sensitized nanoporous TiO2photoanode is prepared for the first time by anin situtechnique for use in perovskite solar cells; potentially improving their efficency.

Adsorption Density Calculations from in Situ FT-IR/IRS Data at Dilute Surfactant Concentrations

1989 ◽  
Vol 43 (8) ◽  
pp. 1456-1459 ◽  
Author(s):  
Jon J. Kellar ◽  
W. M. Cross ◽  
J. D. Miller
Keyword(s):  
Adsorption Isotherm ◽  
Internal Reflection ◽  
Surfactant Adsorption ◽  
In Situ Method ◽  
Ft Ir ◽  
Reflection Theory ◽  
Adsorption Density ◽  
First Time ◽  
Monolayer Coverage

Adsorption densities of the surfactant oleate at the surface of a fluorite crystal have been calculated from in situ FT-IR internal reflection spectroscopic (1RS) data at very low surfactant concentrations. For the first time, a complete adsorption isotherm (5 × 10−7 to 5 × 10−4 M) has been calculated from the in situ spectral data with the use of internal reflection theory. It was found that monolayer coverage occurred at very low surfactant concentrations (<10−5 M), while at higher bulk concentrations, adsorption consists of multilayers of what appears to be surface-precipitated calcium dioleate. Calculated absorption densities by this in situ method agree quite well with those found previously by more traditional experimental techniques. These results provide considerable confidence that quantitative in situ FT-IR/IRS analysis of surfactant adsorption at the surface of reactive internal reflection elements is possible.

Probing the Dynamic Self-Assembly Behaviour of Photoswitchable Wormlike Micelles in Real Time

2018 ◽  
Author(s):  
Elaine A. Kelly ◽  
Judith E. Houston ◽  
Rachel Evans
Keyword(s):  
Real Time ◽  
Absorption Spectroscopy ◽  
Self Assembly ◽  
Uv Light ◽  
Wormlike Micelles ◽  
Tetraethylene Glycol ◽  
Light Illumination ◽  
First Time ◽  
Dependent Processes

Understanding the dynamic self-assembly behaviour of azobenzene photosurfactants (AzoPS) is crucial to advance their use in controlled release applications such as<i></i>drug delivery and micellar catalysis. Currently, their behaviour in the equilibrium <i>cis-</i>and <i>trans</i>-photostationary states is more widely understood than during the photoisomerisation process itself. Here, we investigate the time-dependent self-assembly of the different photoisomers of a model neutral AzoPS, <a>tetraethylene glycol mono(4′,4-octyloxy,octyl-azobenzene) </a>(C<sub>8</sub>AzoOC<sub>8</sub>E<sub>4</sub>) using small-angle neutron scattering (SANS). We show that the incorporation of <i>in-situ</i>UV-Vis absorption spectroscopy with SANS allows the scattering profile, and hence micelle shape, to be correlated with the extent of photoisomerisation in real-time. It was observed that C<sub>8</sub>AzoOC<sub>8</sub>E<sub>4</sub>could switch between wormlike micelles (<i>trans</i>native state) and fractal aggregates (under UV light), with changes in the self-assembled structure arising concurrently with changes in the absorption spectrum. Wormlike micelles could be recovered within 60 seconds of blue light illumination. To the best of our knowledge, this is the first time the degree of AzoPS photoisomerisation has been tracked <i>in</i><i>-situ</i>through combined UV-Vis absorption spectroscopy-SANS measurements. This technique could be widely used to gain mechanistic and kinetic insights into light-dependent processes that are reliant on self-assembly.

The Total Synthesis of Rhabdastrellic Acid A

2018 ◽  
Author(s):  
Yaroslav Boyko ◽  
Christopher Huck ◽  
David Sarlah
Keyword(s):  
Total Synthesis ◽  
Late Stage ◽  
Cross Coupling ◽  
Side Chains ◽  
General Strategy ◽  
Modular Approach ◽  
Linear Sequence ◽  
Generating Sequence ◽  
First Time

<div>The first total synthesis of rhabdastrellic acid A, a highly cytotoxic isomalabaricane triterpenoid, has been accomplished in a linear sequence of 14 steps from commercial geranylacetone. The prominently strained <i>trans-syn-trans</i>-perhydrobenz[<i>e</i>]indene core characteristic of the isomalabaricanes is efficiently accessed in a selective manner for the first time through a rapid, complexity-generating sequence incorporating a reductive radical polyene cyclization, an unprecedented oxidative Rautenstrauch cycloisomerization, and umpolung 𝛼-substitution of a <i>p</i>-toluenesulfonylhydrazone with in situ reductive transposition. A late-stage cross-coupling in concert with a modular approach to polyunsaturated side chains renders this a general strategy for the synthesis of numerous family members of these synthetically challenging and hitherto inaccessible marine triterpenoids.</div>

scholarly journals Engineered Phage Endolysin Eliminates Gardnerella Biofilm without Damaging Beneficial Bacteria in Bacterial Vaginosis Ex Vivo

Pathogens ◽  
2021 ◽  
Vol 10 (1) ◽  
pp. 54
Author(s):  
Christine Landlinger ◽  
Lenka Tisakova ◽  
Vera Oberbauer ◽  
Timo Schwebs ◽  
Abbas Muhammad ◽  
...  
Keyword(s):  
Bacterial Vaginosis ◽  
Bactericidal Activity ◽  
High Selectivity ◽  
Ex Vivo ◽  
Vaginal Microbiome ◽  
Wild Type ◽  
Wild Type Enzyme ◽  
Promising Alternative ◽  
First Time

Bacterial vaginosis is characterized by an imbalance of the vaginal microbiome and a characteristic biofilm formed on the vaginal epithelium, which is initiated and dominated by Gardnerella bacteria, and is frequently refractory to antibiotic treatment. We investigated endolysins of the type 1,4-beta-N-acetylmuramidase encoded on Gardnerella prophages as an alternative treatment. When recombinantly expressed, these proteins demonstrated strong bactericidal activity against four different Gardnerella species. By domain shuffling, we generated several engineered endolysins with 10-fold higher bactericidal activity than any wild-type enzyme. When tested against a panel of 20 Gardnerella strains, the most active endolysin, called PM-477, showed minimum inhibitory concentrations of 0.13–8 µg/mL. PM-477 had no effect on beneficial lactobacilli or other species of vaginal bacteria. Furthermore, the efficacy of PM-477 was tested by fluorescence in situ hybridization on vaginal samples of fifteen patients with either first time or recurring bacterial vaginosis. In thirteen cases, PM-477 killed the Gardnerella bacteria and physically dissolved the biofilms without affecting the remaining vaginal microbiome. The high selectivity and effectiveness in eliminating Gardnerella, both in cultures of isolated strains as well as in clinically derived samples of natural polymicrobial biofilms, makes PM-477 a promising alternative to antibiotics for the treatment of bacterial vaginosis, especially in patients with frequent recurrence.

scholarly journals Application of Furcellaran Nanocomposite Film as Packaging of Cheese

Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1428
Author(s):  
Agnieszka Pluta-Kubica ◽  
Ewelina Jamróz ◽  
Gohar Khachatryan ◽  
Adam Florkiewicz ◽  
Pavel Kopel
Keyword(s):  
Silver Nanoparticles ◽  
Nanocomposite Film ◽  
Microbiological Quality ◽  
Inhibitory Effect ◽  
Quality Properties ◽  
In Situ Method ◽  
And Migration ◽  
Total Bacteria

There is a serious need to develop and test new biodegradable packaging which could at least partially replace petroleum-based materials. Therefore, the objective of this work was to examine the influence of the recently developed furcellaran nanocomposite film with silver nanoparticles (obtained by an in situ method) on the quality properties of two cheese varieties: a rennet-curd (gouda) and an acid-curd (quark) cheese. The water content, physicochemical properties, microbiological and organoleptic quality of cheese, and migration of silver nanoparticles were examined. Both the number of Lactococcus and total bacteria count did not differ during storage of gouda regardless of the packaging applied. The number of Lactococcus decreased in analogous quark samples. The use of the film slowed down and inhibited the growth of yeast in gouda and quark, respectively. An inhibitory effect of this film on mold count was also observed; however, only regarding gouda. The level of silver migration was found to be lower in quark than in gouda. The film improved the microbiological quality of cheeses during storage. Consequently, it is worth continuing research for the improvement of this film in order to enable its use in everyday life.

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