scholarly journals Ultrafast and long-time excited state kinetics of an NIR-emissive vanadium(III) complex I: Synthesis, spectroscopy and static quantum chemistry

2021 ◽  
Author(s):  
Matthias Dorn ◽  
Jens Kalmbach ◽  
Pit Boden ◽  
Ayla Kruse ◽  
Chahinez Dab ◽  
...  

In spite of intense, recent research efforts, luminescent transition metal complexes with Earth-abundant metals are still very rare owing to the small ligand field splitting of 3d transition metal complexes...

2021 ◽  
Author(s):  
Patrick Zobel ◽  
Thomas Knoll ◽  
Leticia Gonzalez

We report the non-adiabatic dynamics of VIIICl3(ddpd), a complex based on the Earth-abundant first-row transition metal vanadium with d2 electronic configuration which is able to emit phosphorescence in solution in...


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