Photoreactions of transition metal complexes. Ligand reactivity as a probe for excited-state characterization

1973 ◽  
Vol 95 (13) ◽  
pp. 4367-4372 ◽  
Author(s):  
Phoebe P. Zarnegar ◽  
C. R. Bock ◽  
David G. Whitten
Keyword(s):  
Excited State ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Ligand Reactivity

Excited-State Mixed Valence in Transition Metal Complexes

2006 ◽  
Vol 45 (17) ◽  
pp. 6556-6558 ◽  
Author(s):  
Edward A. Plummer ◽  
Jeffrey I. Zink
Keyword(s):  
Excited State ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Mixed Valence

scholarly journals Tandem redox mediator/Ni(ii) trihalide complex photocycle for hydrogen evolution from HCl

2015 ◽  
Vol 6 (2) ◽  
pp. 917-922 ◽  
Author(s):  
Seung Jun Hwang ◽  
David C. Powers ◽  
Andrew G. Maher ◽  
Daniel G. Nocera
Keyword(s):  
Excited State ◽  
Transition Metal ◽  
Metal Complexes ◽  
Hydrogen Evolution ◽  
Transition Metal Complexes ◽  
Redox Mediator ◽  
Metal Catalyst ◽  
Nickel Metal ◽  
Excited State Lifetimes

The challenge that short excited state lifetimes of first-row transition metal complexes present to the photoactivation of M–X bonds has been overcome with a phosphine mediator coupled to a nickel metal catalyst.

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