scholarly journals Electrochromic properties of pyrene conductive polymers modified by chemical polymerization

RSC Advances ◽  
2021 ◽  
Vol 11 (62) ◽  
pp. 39291-39305
Author(s):  
Rui Li ◽  
Haoran Xu ◽  
Yuhang Zhang ◽  
Lijing Chang ◽  
Yang Ma ◽  
...  
Keyword(s):  
Conductive Polymers ◽  
Ring Structure ◽  
Chemical Polymerization ◽  
Electrochromic Properties ◽  
Benzene Rings

Pyrene is composed of four benzene rings and has a unique planar melting ring structure.

scholarly journals Reaction Mechanism and kinetics of In-Situ Polymerization of Pyrrole onto Textiles: A Review

2018 ◽  
Vol 1 (2) ◽  
Author(s):  
Subhankar Maity
Keyword(s):  
In Situ Polymerization ◽  
Conductive Polymers ◽  
Textile Composites ◽  
Electrochromic Devices ◽  
Factors Affecting ◽  
Chemical Polymerization ◽  
Textile Materials ◽  
Potential Applications ◽  
Kinetics Of

Research of electro-conductive textiles based on conductive polymers like polypyrrole, has increased in the recent years due to their high potential applications in various field. Conductive polymers behave like insulator in their neutral states with typical electrical conductivity in the range 10-10 to 10-25 Scm-1. These neutral polymers can be converted into semi-conductive or conductive states with conductivities range of 1 Scm-1 to 10-4 Scm-1 through chemical or electro-chemical redox reactions. By the applications of these polymers onto a textile surface, we can be able to obtain novel composites which are strong, flexible, light weight and highly electro-conductive. These textile composites are suitable for applications such as heating pads, sensors, corrosion-protecting materials, actuators, electrochromic devices, EMI shielding etc. The methods of applications of conductive polymers onto the textile surface such as in-situ chemical, in-situ electro-chemical, in-situ vapor phase, in-situ polymerization in a supercritical fluid, solution coating process are described here briefly. Merits and demerits of these methods are mentioned here. Reaction mechanisms of chemical and electro-chemical polymerization proposed by the different researcher are described. Different factors affecting the kinetics of chemical and electro-chemical polymerization are accounted. Influence of textile materials on the kinetics of chemical polymerization is reviewed and reported.

scholarly journals Physico-chemical factors conditioning the electronic conduction of conductive polymers

2021 ◽  
Vol 229 ◽  
pp. 01058
Author(s):  
Fatiha Saouti ◽  
Abdelouahed Charquaoui ◽  
Youssef Naimi
Keyword(s):  
Conductive Polymers ◽  
Chemical Properties ◽  
Synthetic Methods ◽  
Electronic Conduction ◽  
Chemical Polymerization ◽  
Gap Energy ◽  
Physico Chemical ◽  
Physicochemical Factors ◽  
Chemical Factors ◽  
Synthetic Work

The driving idea and the main objective of this synthetic work is the study of physicochemical factors such as the dielectric constant of the solvent, the polarizability of the chains and the Gap energy of the conductive polymers, these characteristics condition their properties. electrical and electrochemical. We focused our study on polyaniline, two synthetic methods are presented: chemical polymerization and electropolymerization with emphasis on the theoretical aspects of the phenomena involved as well as on the electrochemical methods used such as cyclic voltammetry. We have therefore developed with maximum clarity the links existing between the physico-chemical properties of polyaniline and its electrical conductivity.

Core/shell structured halloysite/polyaniline nanotubes with enhanced electrochromic properties

2018 ◽  
Vol 6 (21) ◽  
pp. 5707-5715 ◽  
Author(s):  
Fei Hu ◽  
Jianlong Xu ◽  
Sihang Zhang ◽  
Jie Jiang ◽  
Bin Yan ◽  
...  
Keyword(s):  
Shell Structure ◽  
Core Shell ◽  
Chemical Polymerization ◽  
Electrochromic Properties ◽  
Core Shell Structure ◽  
Polyaniline Nanotubes

Novel halloysite/polyaniline core/shell structure nanocomposites with remarkable electrochromic performances are fabricated by in situ chemical polymerization for electrochromic applications.

scholarly journals Controlling the electrochromic properties of conductive polymers using UV-light

2018 ◽  
Vol 6 (17) ◽  
pp. 4663-4670 ◽  
Author(s):  
Robert Brooke ◽  
Jesper Edberg ◽  
Donata Iandolo ◽  
Magnus Berggren ◽  
Xavier Crispin ◽  
...  
Keyword(s):  
Conductive Polymers ◽  
Uv Light ◽  
New Technique ◽  
Electrochromic Properties ◽  
Image Displays ◽  
Dual Image ◽  
A New Technique

A new technique for patterning and tuning of electrochromic properties of conductive polymers was used to make dual image displays.

Research Progress on Inherently Conducting Polymer Coated Paper

2011 ◽  
Vol 236-238 ◽  
pp. 1396-1400
Author(s):  
Xue Ren Qian
Keyword(s):  
Conducting Polymer ◽  
Conductive Polymers ◽  
Polymerization Process ◽  
Research Progress ◽  
Aqueous Electrolytes ◽  
Pulp Fibers ◽  
Coated Paper ◽  
Chemical Polymerization ◽  
Conductive Paper

In recent years, conductive paper produced by in-situ chemical polymerization of pyrrole and aniline in aqueous electrolytes has aroused a great interest. The in-situ chemical polymerization process is a process in which a monomer such as aniline or pyrrole is polymerized in the presence of pulp fibers. This approach can not only impart to paper specific functions, but also provide a new possibility for the processing and utilization of conductive polymers. In this paper, the research progress on inherently conducting polymer coated paper was overviewed.

Small Angle Electron Scattering From Vacuum Condensed Metallic Films

1968 ◽  
Vol 26 ◽  
pp. 380-381
Author(s):  
J. Silcox ◽  
R. H. Wade
Keyword(s):  
Electron Scattering ◽  
Small Angle ◽  
Ring Structure ◽  
Two Dimensional ◽  
Metallic Films ◽  
Micro Structure ◽  
Angle Scattering ◽  
The Fourier Transform ◽  
Source Of Information ◽  
Kinematical Theory

Recent work has drawn attention to the possibilities that small angle electron scattering offers as a source of information about the micro-structure of vacuum condensed films. In particular, this serves as a good detector of discontinuities within the films. A review of a kinematical theory describing the small angle scattering from a thin film composed of discrete particles packed close together will be presented. Such a model could be represented by a set of cylinders packed side by side in a two dimensional fluid-like array, the axis of the cylinders being normal to the film and the length of the cylinders becoming the thickness of the film. The Fourier transform of such an array can be regarded as a ring structure around the central beam in the plane of the film with the usual thickness transform in a direction normal to the film. The intensity profile across the ring structure is related to the radial distribution function of the spacing between cylinders.

Immunoelectron microscope detection of C-type natriuretic peptide in normal human atrial tissue

1993 ◽  
Vol 51 ◽  
pp. 388-389
Author(s):  
Chi-Ming Wei ◽  
Margaret Hukee ◽  
Christopher G.A. McGregor ◽  
John C. Burnett
Keyword(s):  
Amino Acid ◽  
Natriuretic Peptide ◽  
Vascular Tone ◽  
Cardiac Tissue ◽  
Ring Structure ◽  
Terminal Amino Acid ◽  
Amino Acid Peptide ◽  
Normal Human ◽  
Terminal Amino ◽  
The Brain

C-type natriuretic peptide (CNP) is a newly identified peptide that is structurally related to atrial (ANP) and brain natriuretic peptide (BNP). CNP exists as a 22-amino acid peptide and like ANP and BNP has a 17-amino acid ring formed by a disulfide bond. Unlike these two previously identified cardiac peptides, CNP lacks the COOH-terminal amino acid extension from the ring structure. ANP, BNP and CNP decrease cardiac preload, but unlike ANP and BNP, CNP is not natriuretic. While ANP and BNP have been localized to the heart, recent investigations have failed to detect CNP mRNA in the myocardium although small concentrations of CNP are detectable in the porcine myocardium. While originally localized to the brain, recent investigations have localized CNP to endothelial cells consistent with a paracrine role for CNP in the control of vascular tone. While CNP has been detected in cardiac tissue by radioimmunoassay, no studies have demonstrated CNP localization in normal human heart by immunoelectron microscopy.

Chow Rings, Decomposition of the Diagonal, and the Topology of Families (AM-187)

2017 ◽  
Author(s):  
Claire Voisin
Keyword(s):  
Recent Work ◽  
Chow Groups ◽  
Ring Structure ◽  
Complete Intersections ◽  
Algebraic Varieties ◽  
Chow Ring ◽  
Hodge Structures ◽  
Chow Rings ◽  
Geometric Methods ◽  
The Right

This book provides an introduction to algebraic cycles on complex algebraic varieties, to the major conjectures relating them to cohomology, and even more precisely to Hodge structures on cohomology. The book is intended for both students and researchers, and not only presents a survey of the geometric methods developed in the last thirty years to understand the famous Bloch-Beilinson conjectures, but also examines recent work by the author. It focuses on two central objects: the diagonal of a variety—and the partial Bloch-Srinivas type decompositions it may have depending on the size of Chow groups—as well as its small diagonal, which is the right object to consider in order to understand the ring structure on Chow groups and cohomology. An exploration of a sampling of recent works by the author looks at the relation, conjectured in general by Bloch and Beilinson, between the coniveau of general complete intersections and their Chow groups and a very particular property satisfied by the Chow ring of K3 surfaces and conjecturally by hyper-Kähler manifolds. In particular, the book delves into arguments originating in Nori's work that have been further developed by others.

A Thorough Theoretical Exploration of Intriguing Characteristics of Cyclo[18]carbon: Geometry, Bonding Nature, Aromaticity, Weak Interaction, Reactivity, Excited States, Vibrations, Molecular Dynamics and Various Molecular Properties

2019 ◽  
Author(s):  
Tian Lu ◽  
Qinxue Chen ◽  
Zeyu Liu
Keyword(s):  
Molecular Dynamics ◽  
Excited States ◽  
Electronic Excitation ◽  
Ring Structure ◽  
Molecular Properties ◽  
Molecular Vibration ◽  
Full Characterization ◽  
Long Time ◽  
Almost All

Although cyclo[18]carbon has been theoretically and experimentally investigated since long time ago, only very recently it was prepared and directly observed by means of STM/AFM in condensed phase (Kaiser et al., <i>Science</i>, <b>365</b>, 1299 (2019)). The unique ring structure and dual 18-center π delocalization feature bring a variety of unusual characteristics and properties to the cyclo[18]carbon, which are quite worth to be explored. In this work, we present an extremely comprehensive and detailed investigation on almost all aspects of the cyclo[18]carbon, including (1) Geometric characteristics (2) Bonding nature (3) Electron delocalization and aromaticity (4) Intermolecular interaction (5) Reactivity (6) Electronic excitation and UV/Vis spectrum (7) Molecular vibration and IR/Raman spectrum (8) Molecular dynamics (9) Response to external field (10) Electron ionization, affinity and accompanied process (11) Various molecular properties. We believe that our full characterization of the cyclo[18]carbon will greatly deepen researchers' understanding of this system, and thereby help them to utilize it in practice and design its various valuable derivatives.

A Thorough Theoretical Exploration of Intriguing Characteristics of Cyclo[18]carbon: Geometry, Bonding Nature, Aromaticity, Weak Interaction, Reactivity, Excited States, Vibrations, Molecular Dynamics and Various Molecular Properties

2019 ◽  
Author(s):  
Tian Lu ◽  
Qinxue Chen ◽  
Zeyu Liu
Keyword(s):  
Molecular Dynamics ◽  
Excited States ◽  
Electronic Excitation ◽  
Ring Structure ◽  
Molecular Properties ◽  
Molecular Vibration ◽  
Full Characterization ◽  
Long Time ◽  
Almost All

Although cyclo[18]carbon has been theoretically and experimentally investigated since long time ago, only very recently it was prepared and directly observed by means of STM/AFM in condensed phase (Kaiser et al., <i>Science</i>, <b>365</b>, 1299 (2019)). The unique ring structure and dual 18-center π delocalization feature bring a variety of unusual characteristics and properties to the cyclo[18]carbon, which are quite worth to be explored. In this work, we present an extremely comprehensive and detailed investigation on almost all aspects of the cyclo[18]carbon, including (1) Geometric characteristics (2) Bonding nature (3) Electron delocalization and aromaticity (4) Intermolecular interaction (5) Reactivity (6) Electronic excitation and UV/Vis spectrum (7) Molecular vibration and IR/Raman spectrum (8) Molecular dynamics (9) Response to external field (10) Electron ionization, affinity and accompanied process (11) Various molecular properties. We believe that our full characterization of the cyclo[18]carbon will greatly deepen researchers' understanding of this system, and thereby help them to utilize it in practice and design its various valuable derivatives.

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