scholarly journals Preparation and thermal cross-linking mechanism of co-polyester fiber with flame retardancy and anti-dripping by in situ polymerization

RSC Advances ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 168-180
Author(s):  
Keyu Zhu ◽  
Zhenlin Jiang ◽  
Xiaotong Xu ◽  
Yun Zhang ◽  
Min Zhu ◽  
...  
Keyword(s):  
Flame Retardancy ◽  
In Situ Polymerization ◽  
Polyester Fiber ◽  
Cross Linking

Scheme of proposed thermal cross-linking mechanism.

New Low Toxic Water-Soluble Monomers for Gelcasting of Ceramic Powders

2010 ◽  
Vol 62 ◽  
pp. 163-168 ◽  
Author(s):  
Mikolaj Szafran ◽  
Agnieszka Szudarska ◽  
Paulina Bednarek
Keyword(s):  
In Situ Polymerization ◽  
Polymer Network ◽  
Water Soluble ◽  
Cross Linking ◽  
Alumina Powder ◽  
Hydroxyl Groups ◽  
Ceramic Powders ◽  
Ceramic Slurry ◽  
Low Toxic

In this paper the two new low toxic water-soluble monomers: glycerol monoacrylate and 3-O-acrylic-D-glucose are introduced and their application in gelcasting of alumina powder is reported, in comparison with 2-hydroxyethyl acrylate, the commercial monomer. Both synthesized substances do not need an addition of cross-linking agent to the ceramic slurry, because hydrogen bonds can be formed in the polymer network, owing to the presence of two or more hydroxyl groups in their molecules, unlike in the case of 2-hydroxyethyl acrylate. Rheological behavior of alumina gelcasting suspensions containing these monomers has been studied, as well as the characteristics of raw and sintered elements formed from these slurries by initializing an in situ polymerization.

In situ polymerization of tropoelastin in the absence of chemical cross-linking

Biomaterials ◽  
2009 ◽  
Vol 30 (4) ◽  
pp. 431-435 ◽  
Author(s):  
Suzanne M. Mithieux ◽  
Yidong Tu ◽  
Emine Korkmaz ◽  
Filip Braet ◽  
Anthony S. Weiss
Keyword(s):  
In Situ Polymerization ◽  
Cross Linking ◽  
Chemical Cross Linking

In situ polymerization of polyaniline on cotton fabrics with phytic acid as a novel efficient dopant for flame retardancy and conductivity switching

2020 ◽  
Vol 44 (8) ◽  
pp. 3504-3513 ◽  
Author(s):  
Qingqing Zhou ◽  
Jiayi Chen ◽  
Tianchi Zhou ◽  
Jianzhong Shao
Keyword(s):  
Flame Retardant ◽  
Phytic Acid ◽  
Cotton Fabric ◽  
Flame Retardancy ◽  
In Situ Polymerization ◽  
Cotton Fabrics ◽  
Water Bath ◽  
Conductivity Switching ◽  
Ice Water

A flame-retardant conductive cotton fabric switch was successfully prepared by the in situ polymerization of polyaniline doped with novel phytic acid (PA) by impregnation in an ice water bath for 24 h.

Preparation and characterizations of flame retardant melamine cyanurate/polyamide 6 composite fibers via in situ polymerization

2016 ◽  
Vol 87 (5) ◽  
pp. 561-569 ◽  
Author(s):  
Yuanyuan Li ◽  
Yunzhi Lin ◽  
Kai Sha ◽  
Ru Xiao
Keyword(s):  
Flame Retardant ◽  
Flame Retardancy ◽  
Melt Spinning ◽  
Cyanuric Acid ◽  
In Situ Polymerization ◽  
Polyamide 6 ◽  
Composite Fibers ◽  
Limiting Oxygen Index ◽  
Melamine Cyanurate

To improve the flame retardancy of polyamide 6 (PA6) fibers, melamine cyanurate (MCA)/PA6 composites were synthesized via in situ polymerization of ɛ-caprolactam in the presence of adipic acid-melamine salt and cyanuric acid-hexane diamine salt. The flame retardant MCA/PA6 composite fibers were prepared by melt spinning. The structure and properties of MCA/PA6 composites and MCA/PA6 composite fibers were studied by Fourier transform infrared spectra, X-ray diffraction, differential scanning calorimetry, thermogravimetric analysis, scanning electron microscopy, tensile tests, vertical burning tests (UL94) and limiting oxygen index (LOI) tests. Experimental results indicated that the MCA/PA6 composites loaded with 8 wt% of additives can achieve UL94 V-0 rating with an LOI value of 29.3%. The tenacity at break of PA6 fiber decreased from 4.85 to 3.11 cN·dtex–1 for MCA/PA6-8 composite fiber. However, the MCA/PA6 composite fibers can effectively suppress the propagation of flame in fabric. This means that the in situ polymerization approach paves the way for the preparation of MCA/PA6 composites that have good spinnability and flame retardancy.

scholarly journals In-Situ Polymerization of Maleic Acid in Presence of Aloe vera Gel for Development of Eco-Friendly Eri Silk based Handlooms

2021 ◽  
Author(s):  
Ashis Narayan Amita Banerjee ◽  
Abhijeet Majumdar ◽  
Dibyendu Bikash Datta ◽  
Debasish Das
Keyword(s):  
Carboxylic Acid ◽  
Maleic Acid ◽  
In Situ Polymerization ◽  
Aloe Vera ◽  
Environmentally Friendly ◽  
Cross Linking ◽  
Silk Fabric ◽  
Polycarboxylic Acids ◽  
Eri Silk

Abstract Polycarboxylic acid compounds such as butane-tetra-carboxylic acid, cyclopentane-tetra-carboxylic acid, and citric acid offer an environmentally friendly, non-toxic, and safe alternative to toxic formaldehyde condensate resin as a silk cross-linking agent. However, the sodium salts of phosphorus-containing mineral acids used as esterification catalysts with such polycarboxylic acids are not environmentally friendly because of their reported adverse effects on the aquatic environment and soil. Also, finishes based on such non-polymeric polycarboxylic acids cannot retain or improve the strength and moisture-regain characteristics of silk. Moreover, most polycarboxylic acids are too expensive for practical exploitation. In view of the above, the present work was aimed at establishing the optimum condition for the application of vinyl monomer containing carboxylic acid like maleic acid in presence of initiator and catalysts on silk fabric in the presence of ammonium persulphate as the free radical polymerization catalyst and trisodium citrate as the esterification catalyst. In this study, eri silk-based handloom fabrics were finished with Aloe vera gel and maleic acid as a cross-linking agent using the pad-dry-cure method. Water-soluble Aloe vera gel with varying concentrations of 5 to 15% (w/v) was also added in the finishing bath to add antibacterial activity to the fabric along with the anti-crease properties. Evaluation of attainable changes or improvements in the eri silk based handloom fabric properties in respect of tensile strength, wrinkle recovery, flexibility, antimicrobial, porosity and moisture regain on such treatments have been done. Besides this, changes in the chemical nature of silk fabric on such modifications have been studied by infrared (IR) spectroscopy and reported in this research article. The study proposes thermal curing system is conducive for in-situ polymerization of maleic acid in presence of Aloe vera for the development of eco-friendly eri silk based handlooms with antibacterial and anti-crease properties, without a significant loss in strength properties. The effects of the antimicrobial agent were assessed even after the 10 wash cycle.

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