scholarly journals Completely green synthesis of rose-shaped Au nanostructures and their catalytic applications

RSC Advances ◽  
2021 ◽  
Vol 11 (55) ◽  
pp. 34589-34598
Author(s):  
Jae Hwan Jeong ◽  
Astrini Pradyast ◽  
Hyeonbo Shim ◽  
Hee-Chul Woo ◽  
Mun Ho Kim
Keyword(s):  
Green Synthesis ◽  
Three Dimensional ◽  
Hierarchical Structures ◽  
One Pot ◽  
Catalytic Applications ◽  
The One

A novel protocol for the one-pot, template/seed-free, and completely green synthesis of rose-shaped Au nanostructures with unique three-dimensional hierarchical structures was developed.

A novel, facile, rapid, solvent free protocol for the one pot green synthesis of chromeno[2,3-d]pyrimidines using reusable nano ZnAl2O4– a NOSE approach and photophysical studies

RSC Advances ◽  
2015 ◽  
Vol 5 (9) ◽  
pp. 6578-6587 ◽  
Author(s):  
Balijapalli Umamahesh ◽  
Triveni Rajashekhar Mandlimath ◽  
Kulathu I. Sathiyanarayanan
Keyword(s):  
Green Synthesis ◽  
Solvent Free ◽  
Pyrimidine Derivatives ◽  
One Pot ◽  
Photophysical Studies ◽  
The One

The preparation of an eco-friendly, highly stable, reusable nano ZnAl2O4was used as an excellent catalyst for the pseudo four component synthesis of a library of fluorescent chromeno[2,3-d]pyrimidine derivatives.

A novel one-dimensional silver cylinder stabilized by mixed 2-mercaptobenzoic acid and ethylenediamine ligands

2012 ◽  
Vol 68 (8) ◽  
pp. m229-m232
Author(s):  
Di Sun ◽  
Zhi-Hao Yan
Keyword(s):  
Three Dimensional ◽  
Van Der Waals Interactions ◽  
Two Dimensional ◽  
Binding Modes ◽  
Supramolecular Framework ◽  
One Pot ◽  
Tetrahedral Geometry ◽  
Coordination Environment ◽  
One Dimensional ◽  
The One

A novel infinite one-dimensional silver cylinder, namely poly[μ-ethylenediamine-μ5-(2-sulfanidylbenzoato)-μ4-(2-sulfanidylbenzoato)-tetrasilver(I)], [Ag4(C7H4O2S)2(C2H8N2)]n, has been synthesized by one-pot reaction of equivalent molar silver nitrate and 2-mercaptobenzoic acid (H2mba) in the presence of ethylenediamine (eda). One Ag atom is located in an AgS2NO four-coordinated tetrahedral geometry, two other Ag atoms are in an AgS2O three-coordinated T-shaped geometry and the fourth Ag atom is in an AgSNO coordination environment. The two mba ligands show two different binding modes. The μ2-N:N′-eda ligand, acting as a bridge, combines with mba ligands to extend the AgIions into a one-dimensional silver cylinder incorporating abundant Ag...Ag interactions ranging from 2.9298 (11) to 3.2165 (13) Å. Interchain N—H...O hydrogen bonds extend the one-dimensional cylinder into an undulating two-dimensional sheet, which is further packed into a three-dimensional supramolecular framework by van der Waals interactions; no π–π interactions were observed in the crystal structure.

scholarly journals Green Synthesis and Electrochemical Properties of Mono- and Dimers Derived from Phenylaminoisoquinolinequinones

Molecules ◽  
2019 ◽  
Vol 24 (23) ◽  
pp. 4378 ◽  
Author(s):  
Juana Andrea Ibacache ◽  
Jaime A. Valderrama ◽  
Judith Faúndes ◽  
Alex Danimann ◽  
Francisco J. Recio ◽  
...  
Keyword(s):  
Green Synthesis ◽  
Electrochemical Properties ◽  
Square Wave Voltammetry ◽  
Oxidation Process ◽  
Oxidative Amination ◽  
One Pot ◽  
Wave Voltammetry ◽  
Controlled Potential ◽  
The One ◽  
Controlled Potential Coulometry

In the search for new quinoid compounds endowed with potential anticancer activity, the synthesis of novel heterodimers containing the cytotoxic 7-phenylaminoisoquinolinequinone and 2-phenylaminonaphthoquinone pharmacophores, connected through methylene and ethylene spacers, is reported. The heterodimers were prepared from their respective isoquinoline and naphthoquinones and 4,4′-diaminodiphenyl alkenes. The access to the target heterodimers and their corresponding monomers was performed both through oxidative amination reactions assisted by ultrasound and CeCl3·7H2O catalysis “in water”. This eco-friendly procedure was successfully extended to the one-pot synthesis of homodimers derived from the 7-phenylaminoisoquinolinequinone pharmacophore. The electrochemical properties of the monomers and dimers were determined by cyclic and square wave voltammetry. The number of electrons transferred during the oxidation process, associated to the redox potential EI1/2, was determined by controlled potential coulometry.

scholarly journals One-pot green synthesis of antimicrobial chitosan derivative nanocomposites to control foodborne pathogens

RSC Advances ◽  
2022 ◽  
Vol 12 (2) ◽  
pp. 1095-1104
Author(s):  
Mahmoud H. Abu Elella ◽  
Ahmed Esmail Shalan ◽  
Magdy W. Sabaa ◽  
Riham R. Mohamed
Keyword(s):  
Green Synthesis ◽  
Silver Nitrate ◽  
Foodborne Pathogens ◽  
Antimicrobial Agents ◽  
Water Soluble ◽  
Chitosan Derivative ◽  
One Pot ◽  
The One

This study aimed to show the efficacy of the one-pot green biosynthesis of nanocomposites as effective antimicrobial agents based on a water-soluble biodegradable polysaccharide and silver nitrate (AgNO3).

scholarly journals In situ synthesis, crystal structures, topology and photoluminescent properties of poly[di-μ-aqua-diaqua[μ3-4-(1H-tetrazol-1-id-5-yl)benzoato-κ4 O:O,O′:O′′]barium(II)] and poly[μ-aqua-diaqua[μ3-4-(1H-tetrazol-1-id-5-yl)benzoato-κ4 O:O,O′:O′]strontium(II)]

2020 ◽  
Vol 76 (6) ◽  
pp. 877-883
Author(s):  
Mohamed Abdellatif Bensegueni ◽  
Aouatef Cherouana ◽  
Hocine Merazig
Keyword(s):  
Coordination Compounds ◽  
Alkaline Earth ◽  
Three Dimensional ◽  
Hydrothermal Conditions ◽  
One Pot ◽  
Structural Differences ◽  
Supramolecular Networks ◽  
The One ◽  
Mode Of Coordination

Two alkaline-earth coordination compounds, [Ba(C8H4N4O2)(H2O)4] n , (I), and [Sr(C8H4N4O2)(H2O)3] n , (II), from the one-pot hydrolysis transformation of benzoyl chloride and the in situ self-assembled [2 + 3] cycloaddition of nitrile are presented. These coordination compounds are prepared by reacting 4-cyanobenzoyl chloride with divalent alkaline-earth salts (BaCl2 and SrCl2) in aqueous solution under hydrothermal conditions. The mononuclear coordination compounds (I) and (II) show the same mode of coordination of the organic ligands. The cohesion of the crystalline structures is provided by hydrogen bonds and π-stacking interactions, thus forming three-dimensional supramolecular networks. The two compounds have a three-dimensional (3,6)-connected topology, and the structural differences between them is in the number of water molecules around the alkaline earth metals. Having the same emission frequencies, the compounds exhibit photoluminescence properties with a downward absorption value from (I) to (II).

scholarly journals H3PW12O40 Anchored on the Three-Dimensional and Networked SBA-15 as an Efficient and Recyclable Catalyst for Mannich Reaction

2019 ◽  
Vol 64 (1) ◽  
Author(s):  
Tengfei Zhang ◽  
Wei Zhang ◽  
Hao Dong ◽  
Qing Liu
Keyword(s):  
Mannich Reaction ◽  
Three Dimensional ◽  
Impregnation Method ◽  
X Ray Diffraction ◽  
Reaction Conditions ◽  
One Pot ◽  
Solvent Free Condition ◽  
Transmission Electron ◽  
Ft Ir ◽  
The One

Abstract. The three-dimensional and networked SBA-15 (3D-SBA-15) supported phosphotungstic acid (PW) was used as heterogeneous catalyst for the one-pot three-components Mannich reaction at room temperature. The H3PW12O40/3D-SBA-15 catalyst was prepared using an impregnation method and confirmed by series of characterizations such as Fourier-transform infrared spectra (FT-IR), scanning electron microscope (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), N2 physisorption and thermogravimetric (TG) analysis. 50PW/3D-SBA-15 catalyst with H3PW12O40 loading of 50 wt% showed the highest yield of 93% in 1.8 h for the Mannich reaction of benzaldehyde, aniline and acetophenone under solvent-free condition. A series of β-aminoketone derivatives were synthesized successfully in the presence of this catalyst. In addition, H3PW12O40/3D-SBA-15 catalyst can be easily recovered and reused four times without significant decrease of the activity. This work provides an improved modification of the three-component Mannich reaction in terms of mild reaction conditions, clean reaction profiles, small quantity of catalyst and a simple workup procedure.                                                Resumen.  El ácido fosfotungstico (PW) se soportó en sílice SBA-15 (3D-SBA-15) y se usó como catalizador heterogéneo en la reacción de Mannich en un solo paso de tres componentes a temperatura ambiente. El catalizador H3PW12O40/3D-SBA-15 se preparó mediante impregnación y se caracterizó por espectroscopia de infrarrojo (FT-IR), microscopia electrónica de barrido (SEM), microscopía electrónica de transmisión (TEM), difracción de rayos-X (XRD), fisisorción de N2 y análisis termogravimétrico (TG). El catalizador 50PW/3D-SBA-15, con una carga de H3PW12O40 del 50% en peso, mostró el rendimiento más alto del 93% en 1.8 h para la reacción de Mannich entre benzaldehído, anilina y acetofenona, sin disolvente. Se sintetizó una serie de derivados de β-aminocetona en presencia de este catalizador. Además, el catalizador H3PW12O40/3D-SBA-15 puede recuperarse fácilmente y reutilizarse cuatro veces sin pérdida significativa de la actividad. Este trabajo reporta una modificación de la reacción de Mannich de tres componentes bajo condiciones de reacción suaves, perfiles de reacción limpios, pequeña cantidad de catalizador y un procedimiento de tratamiento simple.

Green synthesis of 1H-pyrazolo[1,2-b]phthalazinedione-2-carbonitriles in the presence of L-proline

2021 ◽  
Vol 08 ◽  
Author(s):  
Davood Habibi ◽  
Saeedeh Shojaei ◽  
Somayyeh Heydari
Keyword(s):  
Organic Chemistry ◽  
Natural Products ◽  
Green Synthesis ◽  
Organic Materials ◽  
Aromatic Aldehydes ◽  
One Pot ◽  
Diverse Range ◽  
Three Component Reaction ◽  
The One ◽  
Green Conditions

Background: The multi component reaction (MCRs) is a method extensively used in organic chemistry as a tool in the synthesis of nitrogen containing heterocycles found in many natural products, medicinally relevant substances and organic materials. Objective: This paper describes the synthesis of a diverse range of 1H-pyrazolo[1,2-b]phthalazine-2-carbonitriles of considerable chemical and biological interests. Conclusion: Various 3-amino-5,10-dioxo-1-phenyl-5,10-dihydro-1H-pyrazolo[1,2-b]phthalazine-2-carbo -nitriles were synthesized via the one-pot three component reaction of phthalhydrazides, aromatic aldehydes and malononitrile in the presence of the proline as an organocatalyst in ethanol at refluxing temperature under the green conditions in excellent yields.

Nano magnetic sulfated zirconia (Fe3O4@ZrO2/SO42−): an efficient solid acid catalyst for the green synthesis of α-aminonitriles and imines

2015 ◽  
Vol 39 (6) ◽  
pp. 4821-4829 ◽  
Author(s):  
Hossein Ghafuri ◽  
Afsaneh Rashidizadeh ◽  
Behnaz Ghorbani ◽  
Majid Talebi
Keyword(s):  
Green Synthesis ◽  
Sulfated Zirconia ◽  
Solid Acid ◽  
Solid Acid Catalyst ◽  
Acid Catalyst ◽  
One Pot ◽  
Nano Catalyst ◽  
The One

In this research, nano magnetic sulfated zirconia was prepared through a green and facile method and acted as a novel, heterogeneous, efficient nano-catalyst for the one-pot three component synthesis of α-aminonitrile derivatives.

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