scholarly journals Copper nanoparticle anchored biguanidine-modified Zr-UiO-66 MOFs: a competent heterogeneous and reusable nanocatalyst in Buchwald–Hartwig and Ullmann type coupling reactions

RSC Advances ◽  
2021 ◽  
Vol 11 (36) ◽  
pp. 22278-22286
Author(s):  
Hojat Veisi ◽  
Narges Neyestani ◽  
Mozhgan Pirhayati ◽  
Sheida Ahany Kamangar ◽  
Shahram Lotfi ◽  
...  
Keyword(s):  
Surface Area ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
Coupling Reactions ◽  
Copper Nanoparticle ◽  
Cu Nanoparticles ◽  
Polymeric Structure ◽  
Metal Organic ◽  
Type Coupling

We have designed a functionalized metal–organic framework (MOF) of UiO topology as a support, with an extremely high surface area, adjustable pore sizes and stable crystalline coordination polymeric structure and implanted copper (Cu) nanoparticles thereon.

Formation of a Metal-Organic Framework with High Surface Area and Gas Uptake by Breaking Edges Off Truncated Cuboctahedral Cages

2013 ◽  
Vol 125 (43) ◽  
pp. 11492-11495 ◽  
Author(s):  
Ruirui Yun ◽  
Zhiyong Lu ◽  
Yi Pan ◽  
Xiaozeng You ◽  
Junfeng Bai
Keyword(s):  
Surface Area ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
Gas Uptake ◽  
Metal Organic ◽  
Organic Framework

scholarly journals A new metal–organic framework with ultra-high surface area

2014 ◽  
Vol 50 (26) ◽  
pp. 3450 ◽  
Author(s):  
Ronny Grünker ◽  
Volodymyr Bon ◽  
Philipp Müller ◽  
Ulrich Stoeck ◽  
Simon Krause ◽  
...  
Keyword(s):  
Surface Area ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
Metal Organic ◽  
Organic Framework

A high surface area Zr(IV)-based metal–organic framework showing stepwise gas adsorption and selective dye uptake

2015 ◽  
Vol 223 ◽  
pp. 104-108 ◽  
Author(s):  
Xiu-Liang Lv ◽  
Minman Tong ◽  
Hongliang Huang ◽  
Bin Wang ◽  
Lei Gan ◽  
...  
Keyword(s):  
Surface Area ◽  
Gas Adsorption ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
Dye Uptake ◽  
Metal Organic ◽  
Organic Framework

Novel crystalline nanoporous iron phosphonate based metal-organic framework as an efficient anode material for lithium ion batteries

2021 ◽  
Author(s):  
Debabrata Chakraborty ◽  
Tapabrata Dam ◽  
Arindam Modak ◽  
Kamal K Pant ◽  
Bijan Krishna Chandra ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Surface Area ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
Lithium Ion ◽  
Energy Research ◽  
Porous Architecture ◽  
Metal Organic ◽  
Organic Framework

Metal-organic framework (MOF) materials show extraordinary performances in several frontier applications of energy research due to their well-defined crystalline porous architecture, high surface area and periodicity of the functional groups...

scholarly journals Enhanced Fungicidal Efficacy by Co-Delivery of Azoxystrobin and Diniconazole with Cauliflower-Like Metal–Organic Frameworks NH2-Al-MIL-101

2021 ◽  
Vol 22 (19) ◽  
pp. 10412
Author(s):  
Huiping Chen ◽  
Yongpan Shan ◽  
Lidong Cao ◽  
Pengyue Zhao ◽  
Chong Cao ◽  
...  
Keyword(s):  
Surface Area ◽  
Plant Protection ◽  
Metal Organic Framework ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
High Surface Area ◽  
Release Time ◽  
Natural Ecosystems ◽  
Resistance Risk ◽  
Metal Organic

Long-term use of a single fungicide increases the resistance risk and causes adverse effects on natural ecosystems. Controlled release formulations of dual fungicides with different modes of action can afford a new dimension for addressing the current issues. Based on adjustable aperture and superhigh surface area, metal–organic frameworks (MOFs) are ideal candidates as pesticide release carriers. This study used Al3+ as the metal node and 2-aminoterephthalic acid as the organic chain to prepare aluminum-based metal–organic framework material (NH2-Al-MIL-101) with “cauliflower-like” structure and high surface area of 2359.0 m2/g. Fungicides of azoxystrobin (AZOX) and diniconazole (Dini) were simultaneously encapsulated into NH2-Al-MIL-101 with the loading content of 6.71% and 29.72%, respectively. Dual fungicide delivery system of AZOX@Dini@NH2-Al-MIL-101 demonstrated sustained and pH responsive release profiles. When the maximum cumulative release rate of AZOX and Dini both reached about 90%, the release time was 46 and 136 h, respectively. Furthermore, EC50 values as well as the percentage of inhibition revealed that AZOX@Dini@NH2-Al-MIL-101 had enhanced germicidal efficacy against rice sheath blight (Rhizoctonia solani), evidenced by the synergistic ratio of 1.83. The present study demonstrates a potential application prospect in sustainable plant protection through co-delivery fungicides with MOFs as a platform.

MIL-103, A 3-D Lanthanide-Based Metal Organic Framework with Large One-Dimensional Tunnels and A High Surface Area

2005 ◽  
Vol 127 (37) ◽  
pp. 12788-12789 ◽  
Author(s):  
Thomas Devic ◽  
Christian Serre ◽  
Nathalie Audebrand ◽  
Jérôme Marrot ◽  
Gérard Férey
Keyword(s):  
Surface Area ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
One Dimensional ◽  
Metal Organic ◽  
Organic Framework
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