MIL-103, A 3-D Lanthanide-Based Metal Organic Framework with Large One-Dimensional Tunnels and A High Surface Area

2005 ◽  
Vol 127 (37) ◽  
pp. 12788-12789 ◽  
Author(s):  
Thomas Devic ◽  
Christian Serre ◽  
Nathalie Audebrand ◽  
Jérôme Marrot ◽  
Gérard Férey
Keyword(s):  
Surface Area ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
One Dimensional ◽  
Metal Organic ◽  
Organic Framework

scholarly journals A Semiconductive and Microporous One-Dimensional Tubular Metal-Organic Framework

2020 ◽  
Author(s):  
Mehmet Menaf Ayhan ◽  
Ceyda Bayraktar ◽  
Kai Yu ◽  
Gabriel Hanna ◽  
Ozgur Yazaydin ◽  
...  
Keyword(s):  
Band Gap ◽  
Surface Area ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
One Dimensional ◽  
Metal Organic ◽  
Direct Band ◽  
Indirect Band Gap ◽  
Organic Framework

<p>We report the first one-dimensional tubular metal-organic framework (MOF) [Ni(Cu-H6TPPA)]∙2DMA (H8TPPA = 5,10,15,20-tetrakis[p-phenylphosphonic acid] porphyrin) in the literature. The structure of this MOF, known as GTUB4, was solved using single crystal X-ray diffraction and its surface area was calculated to be 1102 m2/g, making it the phosphonate MOF with the highest reported surface area. GTUB4 also possesses a narrow indirect band gap of 1.9 eV and a direct band gap of 2.16 eV, making it a semiconducting MOF. Thermogravimetric analysis of GTUB4 suggests that it is thermally stable up to 400°C. Owing to its high surface area, low band gap, and thermal stability, GTUB4 could find applications as electrodes in supercapacitors.<br></p>

scholarly journals A Semiconductive and Microporous One-Dimensional Tubular Metal-Organic Framework

2020 ◽  
Author(s):  
Mehmet Menaf Ayhan ◽  
Ceyda Bayraktar ◽  
Kai Yu ◽  
Gabriel Hanna ◽  
Ozgur Yazaydin ◽  
...  
Keyword(s):  
Band Gap ◽  
Surface Area ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
One Dimensional ◽  
Metal Organic ◽  
Direct Band ◽  
Indirect Band Gap ◽  
Organic Framework

<p>We report the first one-dimensional tubular metal-organic framework (MOF) [Ni(Cu-H6TPPA)]∙2DMA (H8TPPA = 5,10,15,20-tetrakis[p-phenylphosphonic acid] porphyrin) in the literature. The structure of this MOF, known as GTUB4, was solved using single crystal X-ray diffraction and its surface area was calculated to be 1102 m2/g, making it the phosphonate MOF with the highest reported surface area. GTUB4 also possesses a narrow indirect band gap of 1.9 eV and a direct band gap of 2.16 eV, making it a semiconducting MOF. Thermogravimetric analysis of GTUB4 suggests that it is thermally stable up to 400°C. Owing to its high surface area, low band gap, and thermal stability, GTUB4 could find applications as electrodes in supercapacitors.<br></p>

Formation of a Metal-Organic Framework with High Surface Area and Gas Uptake by Breaking Edges Off Truncated Cuboctahedral Cages

2013 ◽  
Vol 125 (43) ◽  
pp. 11492-11495 ◽  
Author(s):  
Ruirui Yun ◽  
Zhiyong Lu ◽  
Yi Pan ◽  
Xiaozeng You ◽  
Junfeng Bai
Keyword(s):  
Surface Area ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
Gas Uptake ◽  
Metal Organic ◽  
Organic Framework

scholarly journals A new metal–organic framework with ultra-high surface area

2014 ◽  
Vol 50 (26) ◽  
pp. 3450 ◽  
Author(s):  
Ronny Grünker ◽  
Volodymyr Bon ◽  
Philipp Müller ◽  
Ulrich Stoeck ◽  
Simon Krause ◽  
...  
Keyword(s):  
Surface Area ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
Metal Organic ◽  
Organic Framework

A high surface area Zr(IV)-based metal–organic framework showing stepwise gas adsorption and selective dye uptake

2015 ◽  
Vol 223 ◽  
pp. 104-108 ◽  
Author(s):  
Xiu-Liang Lv ◽  
Minman Tong ◽  
Hongliang Huang ◽  
Bin Wang ◽  
Lei Gan ◽  
...  
Keyword(s):  
Surface Area ◽  
Gas Adsorption ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
Dye Uptake ◽  
Metal Organic ◽  
Organic Framework

Novel crystalline nanoporous iron phosphonate based metal-organic framework as an efficient anode material for lithium ion batteries

2021 ◽  
Author(s):  
Debabrata Chakraborty ◽  
Tapabrata Dam ◽  
Arindam Modak ◽  
Kamal K Pant ◽  
Bijan Krishna Chandra ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Surface Area ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
Lithium Ion ◽  
Energy Research ◽  
Porous Architecture ◽  
Metal Organic ◽  
Organic Framework

Metal-organic framework (MOF) materials show extraordinary performances in several frontier applications of energy research due to their well-defined crystalline porous architecture, high surface area and periodicity of the functional groups...

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