Ionic conductivity and dielectric properties of bulk SPP-PEG hydrogel as Na+ ion based SPE material for energy storage applications

Author(s):  
Rudramani Tiwari ◽  
Dipendra Kumar Verma ◽  
Devendra Kumar ◽  
Shashikant Yadav ◽  
Krishna Kumar ◽  
...  

Green SPP-PEG hydrogel material, containing Na+ ions, has been synthesized by green chemistry methodology using sodium polyphosphate and polyethylene glycol in water. Hydrogel has amorphous morphology and sandwiched matrix with...

Polymers ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 1981
Author(s):  
Rafael Del Olmo ◽  
Nerea Casado ◽  
Jorge L. Olmedo-Martínez ◽  
Xiaoen Wang ◽  
Maria Forsyth

Mixed ionic-electronic conductors, such as poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS) are postulated to be the next generation materials in energy storage and electronic devices. Although many studies have aimed to enhance the electronic conductivity and mechanical properties of these materials, there has been little focus on ionic conductivity. In this work, blends based on PEDOT stabilized by the polyelectrolyte poly(diallyldimethylammonium) (PolyDADMA X) are reported, where the X anion is either chloride (Cl), bis(fluorosulfonyl)imide (FSI), bis(trifluoromethylsulfonyl)imide (TFSI), triflate (CF3SO3) or tosylate (Tos). Electronic conductivity values of 0.6 S cm−1 were achieved in films of PEDOT:PolyDADMA FSI (without any post-treatment), with an ionic conductivity of 5 × 10−6 S cm−1 at 70 °C. Organic ionic plastic crystals (OIPCs) based on the cation N-ethyl-N-methylpyrrolidinium (C2mpyr+) with similar anions were added to synergistically enhance both electronic and ionic conductivities. PEDOT:PolyDADMA X / [C2mpyr][X] composites (80/20 wt%) resulted in higher ionic conductivity values (e.g., 2 × 10−5 S cm−1 at 70 °C for PEDOT:PolyDADMA FSI/[C2mpyr][FSI]) and improved electrochemical performance versus the neat PEDOT:PolyDADMA X with no OIPC. Herein, new materials are presented and discussed including new PEDOT:PolyDADMA and organic ionic plastic crystal blends highlighting their promising properties for energy storage applications.


2016 ◽  
Vol 42 (1) ◽  
pp. 1740-1745 ◽  
Author(s):  
Soo-Bin Kang ◽  
Hyung Sun Kim ◽  
Jung Geun Lee ◽  
Chun-Kil Park ◽  
Jungho Ryu ◽  
...  

2020 ◽  
Vol 8 (45) ◽  
pp. 23965-23973
Author(s):  
Hangfeng Zhang ◽  
Bin Yang ◽  
A. Dominic Fortes ◽  
Haixue Yan ◽  
Isaac Abrahams

The structural and dielectric properties of barium/strontium substituted Bi0.5Na0.5TiO3 were examined in compositions of general formula (Ba0.4Sr0.6TiO3)x(Bi0.5Na0.5TiO3)1−x.


2016 ◽  
Vol 685 ◽  
pp. 418-422 ◽  
Author(s):  
Wen-Bo Li ◽  
Di Zhou ◽  
Bin He ◽  
Fei Li ◽  
Li-Xia Pang ◽  
...  

ChemSusChem ◽  
2010 ◽  
Vol 3 (12) ◽  
pp. 1390-1397 ◽  
Author(s):  
Daniela La Rosa ◽  
Giuseppe Monforte ◽  
Claudia D'Urso ◽  
Vincenzo Baglio ◽  
Vincenzo Antonucci ◽  
...  

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