Tuning of spin-crossover behavior in two cyano-bridged mixed-valence FeIII2FeII trinuclear complexes based on TpR ligand

2021 ◽  
Author(s):  
Arshia Sulaiman ◽  
Yi-Zhan Jiang ◽  
Mohammad Khurram Javed ◽  
Shu-Qi Wu ◽  
Zhaoyang Li ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Mixed Valence ◽  
The Past ◽  
Trinuclear Complexes ◽  
Crossover Behavior

Spin-crossover (SCO) complexes have been extensively studied in the past few decades owing to their bistable nature which find applications in myriad of areas. In order to enhance and optimize...

High temperature anionic Fe(III) spin crossover behavior in a mixed-valence Fe(II)/Fe(III) complex

2021 ◽  
Author(s):  
Zhi-Jian Ouyang ◽  
Xiao-Ying Mo ◽  
Jia-Qi Ye ◽  
Xiao-Xuan Yu ◽  
Shu-Yuan Huang ◽  
...  
Keyword(s):  
High Temperature ◽  
Structural Analysis ◽  
Spin Crossover ◽  
Mixed Valence ◽  
Ion Pair ◽  
Tridentate Ligand ◽  
Crossover Behavior ◽  
Crystal Structural

Two ion-pair Fe(III) complexes of (PPh4)[FeIII(HATD)2]·2H2O (1,H3ATD = azotetrazolyl-2,7-dihydroxynaphthalene) and [FeII(phen)3][FeIII(HATD)2]2·3DMA·3.5H2O (2, phen = 1,10-phenanthroline, DMA = N,N-dimethylformamide) were synthesized employing the tridentate ligand of H3ATD. The crystal structural analysis...

Symmetry Breaking and Two-Step Spin-Crossover Behavior in Two Cyano-Bridged Mixed-Valence {FeIII2(μ-CN)4FeII2} Clusters

2019 ◽  
Vol 58 (21) ◽  
pp. 14316-14324 ◽  
Author(s):  
Chunyang Zheng ◽  
Shuwen Jia ◽  
Yubao Dong ◽  
Juping Xu ◽  
Huanhuan Sui ◽  
...  
Keyword(s):  
Symmetry Breaking ◽  
Spin Crossover ◽  
Mixed Valence ◽  
Crossover Behavior

Effect of metal dilution on the spin-crossover behavior in [FexM1-x(phen)2(NCS)2] (M = Mn, Co, Ni, Zn)

1982 ◽  
Vol 21 (9) ◽  
pp. 3429-3433 ◽  
Author(s):  
P. Ganguli ◽  
P. Guetlich ◽  
E. W. Mueller
Keyword(s):  
Spin Crossover ◽  
Crossover Behavior

Modification of Spin Crossover Behavior through Solvent Assisted Formation and Solvent Inclusion in a Triply Interpenetrating Three-Dimensional Network

2007 ◽  
Vol 46 (10) ◽  
pp. 4220-4229 ◽  
Author(s):  
Matthias Bartel ◽  
Alina Absmeier ◽  
Guy N. L. Jameson ◽  
Franz Werner ◽  
Kenichi Kato ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Three Dimensional ◽  
Dimensional Network ◽  
Crossover Behavior

Spin-Crossover Behavior in Cyanide-Bridged Iron(II)−Copper(I) Bimetallic 1−3D Metal−Organic Frameworks

2009 ◽  
Vol 48 (8) ◽  
pp. 3371-3381 ◽  
Author(s):  
Gloria Agustí ◽  
M. Carmen Muñoz ◽  
Ana B. Gaspar ◽  
José A. Real
Keyword(s):  
Spin Crossover ◽  
Metal Organic Frameworks ◽  
Crossover Behavior ◽  
Metal Organic

scholarly journals Programmable spin-state switching in a mixed-valence spin-crossover iron grid

2014 ◽  
Vol 5 (1) ◽  
Author(s):  
Takuto Matsumoto ◽  
Graham N. Newton ◽  
Takuya Shiga ◽  
Shinya Hayami ◽  
Yuta Matsui ◽  
...  
Keyword(s):  
Spin State ◽  
Spin Crossover ◽  
Mixed Valence ◽  
State Switching

Electric field control of the optical properties in magnetic mixed-valence molecules

2014 ◽  
Vol 5 (9) ◽  
pp. 3598-3602 ◽  
Author(s):  
Andrew Palii ◽  
Juan M. Clemente-Juan ◽  
Boris Tsukerblat ◽  
Eugenio Coronado
Keyword(s):  
Optical Properties ◽  
Electric Field ◽  
Strong Influence ◽  
Spin Crossover ◽  
Mixed Valence ◽  
Field Control

In delocalized magnetic mixed-valence molecules the spin-crossover induced by an electric field may have a strong influence on their optical properties.

An Unprecedented Homochiral Mixed-Valence Spin-Crossover Compound

2003 ◽  
Vol 42 (14) ◽  
pp. 1614-1618 ◽  
Author(s):  
Yukinari Sunatsuki ◽  
Yuichi Ikuta ◽  
Naohide Matsumoto ◽  
Hiromi Ohta ◽  
Masaaki Kojima ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Mixed Valence

Reversible on-off switching of spin-crossover behavior via photochemical [2+2] cycloaddition reaction

2021 ◽  
Author(s):  
Long-Fei Wang ◽  
Bang-Heng Lv ◽  
Feng-Tai Wu ◽  
Guo-Zhang Huang ◽  
Ze-Yu Ruan ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Cycloaddition Reaction ◽  
Crossover Behavior

[FeIII(bztpen)(OCH3)](PF6)2: Stable Methoxide-Iron(III) Complex Exhibiting Spin Crossover Behavior in the Solid State

2010 ◽  
Vol 2010 (35) ◽  
pp. 5563-5567 ◽  
Author(s):  
Norma A. Ortega-Villar ◽  
M. Carmen Muñoz ◽  
José A. Real
Keyword(s):  
Solid State ◽  
Spin Crossover ◽  
Crossover Behavior
Sign in / Sign up

Export Citation Format

Share Document