High temperature anionic Fe(III) spin crossover behavior in a mixed-valence Fe(II)/Fe(III) complex

2021 ◽  
Author(s):  
Zhi-Jian Ouyang ◽  
Xiao-Ying Mo ◽  
Jia-Qi Ye ◽  
Xiao-Xuan Yu ◽  
Shu-Yuan Huang ◽  
...  
Keyword(s):  
High Temperature ◽  
Structural Analysis ◽  
Spin Crossover ◽  
Mixed Valence ◽  
Ion Pair ◽  
Tridentate Ligand ◽  
Crossover Behavior ◽  
Crystal Structural

Two ion-pair Fe(III) complexes of (PPh4)[FeIII(HATD)2]·2H2O (1,H3ATD = azotetrazolyl-2,7-dihydroxynaphthalene) and [FeII(phen)3][FeIII(HATD)2]2·3DMA·3.5H2O (2, phen = 1,10-phenanthroline, DMA = N,N-dimethylformamide) were synthesized employing the tridentate ligand of H3ATD. The crystal structural analysis...

High-Temperature Spin Crossover Behavior in a Nitrogen-Rich FeIII-Based System

2013 ◽  
Vol 52 (4) ◽  
pp. 1825-1831 ◽  
Author(s):  
Cyril Cook ◽  
Fatemah Habib ◽  
Tomoko Aharen ◽  
Rodolphe Clérac ◽  
Anguang Hu ◽  
...  
Keyword(s):  
High Temperature ◽  
Spin Crossover ◽  
Crossover Behavior

Reversible thermo-induced spin crossover in a mononuclear cis-dicyanamido-cobalt(ii) complex containing a macrocyclic tetradentate ligand

2020 ◽  
Vol 49 (27) ◽  
pp. 9208-9212 ◽  
Author(s):  
Subrata Ghosh ◽  
Subramani Selvamani ◽  
Sakshi Mehta ◽  
Abhishake Mondal
Keyword(s):  
High Temperature ◽  
Spin Crossover ◽  
Tetradentate Ligand ◽  
Mononuclear Cobalt ◽  
Crossover Behavior ◽  
First Time

For the first time, a mononuclear cobalt(ii) complex with dicyanamide coligands exhibiting reversible spin crossover behavior at high temperature is reported.

Slow Magnetic Relaxation and Spin-Crossover Behavior in a Bicomponent Ion-Pair Cobalt(II) Complex

2017 ◽  
Vol 2017 (33) ◽  
pp. 3862-3867 ◽  
Author(s):  
Dong Shao ◽  
Lin-Dan Deng ◽  
Le Shi ◽  
Dong-Qing Wu ◽  
Xiao-Qin Wei ◽  
...  
Keyword(s):  
Magnetic Relaxation ◽  
Spin Crossover ◽  
Ion Pair ◽  
Crossover Behavior ◽  
Slow Magnetic Relaxation

Symmetry Breaking and Two-Step Spin-Crossover Behavior in Two Cyano-Bridged Mixed-Valence {FeIII2(μ-CN)4FeII2} Clusters

2019 ◽  
Vol 58 (21) ◽  
pp. 14316-14324 ◽  
Author(s):  
Chunyang Zheng ◽  
Shuwen Jia ◽  
Yubao Dong ◽  
Juping Xu ◽  
Huanhuan Sui ◽  
...  
Keyword(s):  
Symmetry Breaking ◽  
Spin Crossover ◽  
Mixed Valence ◽  
Crossover Behavior

Tuning of spin-crossover behavior in two cyano-bridged mixed-valence FeIII2FeII trinuclear complexes based on TpR ligand

2021 ◽  
Author(s):  
Arshia Sulaiman ◽  
Yi-Zhan Jiang ◽  
Mohammad Khurram Javed ◽  
Shu-Qi Wu ◽  
Zhaoyang Li ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Mixed Valence ◽  
The Past ◽  
Trinuclear Complexes ◽  
Crossover Behavior

Spin-crossover (SCO) complexes have been extensively studied in the past few decades owing to their bistable nature which find applications in myriad of areas. In order to enhance and optimize...

3D Structural Analysis of Selected High-Temperature Materials

2018 ◽  
Vol 55 (7) ◽  
pp. 424-446
Author(s):  
U. Jäntsch ◽  
M. Klimenkov ◽  
A. Möslang ◽  
F. Reinauer ◽  
J. Reiser ◽  
...  
Keyword(s):  
High Temperature ◽  
Structural Analysis ◽  
High Temperature Materials

Effect of metal dilution on the spin-crossover behavior in [FexM1-x(phen)2(NCS)2] (M = Mn, Co, Ni, Zn)

1982 ◽  
Vol 21 (9) ◽  
pp. 3429-3433 ◽  
Author(s):  
P. Ganguli ◽  
P. Guetlich ◽  
E. W. Mueller
Keyword(s):  
Spin Crossover ◽  
Crossover Behavior

Single-Crystal to Single-Crystal Structural Transformation and Photomagnetic Properties of a Porous Iron(II) Spin-Crossover Framework

2008 ◽  
Vol 130 (9) ◽  
pp. 2869-2876 ◽  
Author(s):  
Suzanne M. Neville ◽  
Gregory J. Halder ◽  
Karena W. Chapman ◽  
Martin B. Duriska ◽  
Peter D. Southon ◽  
...  
Keyword(s):  
Single Crystal ◽  
Structural Transformation ◽  
Spin Crossover ◽  
Porous Iron ◽  
Crystal Structural

Modification of Spin Crossover Behavior through Solvent Assisted Formation and Solvent Inclusion in a Triply Interpenetrating Three-Dimensional Network

2007 ◽  
Vol 46 (10) ◽  
pp. 4220-4229 ◽  
Author(s):  
Matthias Bartel ◽  
Alina Absmeier ◽  
Guy N. L. Jameson ◽  
Franz Werner ◽  
Kenichi Kato ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Three Dimensional ◽  
Dimensional Network ◽  
Crossover Behavior
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