Recent Developments in Stimuli-Responsive Luminescent Polymers Composed of Boron Compounds

2021 ◽  
Author(s):  
Shunichiro Ito ◽  
Masayuki Gon ◽  
Kazuo Tanaka ◽  
Yoshiki Chujo

Stimuli-responsive luminescent materials have received tremendous attention as next-generation smart materials for various applications such as biomedical probes, visualization of pollutants, sensing toxic gases, and so on. Boron-containing luminophores have...

2019 ◽  
Author(s):  
Bin Liu ◽  
Haoke Zhang ◽  
shunjie liu ◽  
JingZhi Sun ◽  
Xing-Hong Zhang ◽  
...  

<p>This article highlights the recent developments of unorthodox luminescent polymers without large p-conjugated structure and their luminescence mechanism in last 2–3 years. Non-conjugated luminescent polymers (NCLPs) will be a wonderful polymer that will provide new soft luminescent materials. Uniting polymer synthesis and photophysical science, <i>Polymerization-Induced Emission</i> (PIE) is proposed for making NCLPs because the advanced polymerization methods have unlimited opportunities to the development of new soft luminescent polymers owing to the multi-level structures of polymers. The importance of this paper is to inspire more thoughts on the emission mechanism of the non-conjugated polymers and developing new soft luminescent materials.</p>


2019 ◽  
Author(s):  
Bin Liu ◽  
Haoke Zhang ◽  
shunjie liu ◽  
JingZhi Sun ◽  
Xing-Hong Zhang ◽  
...  

<p>This article highlights the recent developments of unorthodox luminescent polymers without large p-conjugated structure and their luminescence mechanism in last 2–3 years. Non-conjugated luminescent polymers (NCLPs) will be a wonderful polymer that will provide new soft luminescent materials. Uniting polymer synthesis and photophysical science, <i>Polymerization-Induced Emission</i> (PIE) is proposed for making NCLPs because the advanced polymerization methods have unlimited opportunities to the development of new soft luminescent polymers owing to the multi-level structures of polymers. The importance of this paper is to inspire more thoughts on the emission mechanism of the non-conjugated polymers and developing new soft luminescent materials.</p>


Author(s):  
Khodadad Mostakim ◽  
Nahid Imtiaz Masuk ◽  
Md. Rakib Hasan ◽  
Md. Shafikul Islam

The advancement in 3D printing has led to the rapid growth of 4D printing technology. Adding time, as the fourth dimension, this technology ushered the potential of a massive evolution in fields of biomedical technologies, space applications, deployable structures, manufacturing industries, and so forth. This technology performs ingenious design, using smart materials to create advanced forms of the 3-D printed specimen. Improvements in Computer-aided design, additive manufacturing process, and material science engineering have ultimately favored the growth of 4-D printing innovation and revealed an effective method to gather complex 3-D structures. Contrast to all these developments, novel material is still a challenging sector. However, this short review illustrates the basic of 4D printing, summarizes the stimuli responsive materials properties, which have prominent role in the field of 4D technology. In addition, the practical applications are depicted and the potential prospect of this technology is put forward.


Author(s):  
Yunhui Hao ◽  
Lei Gao ◽  
Xiunan Zhang ◽  
Rongli Wei ◽  
Ting Wang ◽  
...  

Stimuli-responsive molecular crystals are fascinating for their potential as adaptive smart materials. However, achieving one crystal that could respond to multiple stimuli and perform multiple functionalities simultaneously is still challenging....


2021 ◽  
Author(s):  
Hiroko Tokoro ◽  
Asuka Namai ◽  
Shin-ichi Ohkoshi

Recent developments in magnetic films composed of epsilon-iron oxide are introduced. The film performance is studied and improved toward the next-generation of high-density magnetic recording media.


2020 ◽  
Vol 2020 ◽  
pp. 1-24 ◽  
Author(s):  
Carmen Cretu ◽  
Loredana Maiuolo ◽  
Domenico Lombardo ◽  
Elisabeta I. Szerb ◽  
Pietro Calandra

The involvement of metal ions within the self-assembly spontaneously occurring in surfactant-based systems gives additional and interesting features. The electronic states of the metal, together with the bonds that can be established with the organic amphiphilic counterpart, are the factors triggering new photophysical properties. Moreover, the availability of stimuli-responsive supramolecular amphiphile assemblies, able to disassemble in a back-process, provides reversible switching particularly useful in novel approaches and applications giving rise to truly smart materials. In particular, small amphiphiles with an inner distribution, within their molecular architecture, of various polar and apolar functional groups, can give a wide variety of interactions and therefore enriched self-assemblies. If it is joined with the opportune presence and localization of noble metals, whose chemical and photophysical properties are undiscussed, then very interesting materials can be obtained. In this minireview, the basic concepts on self-assembly of small amphiphilic molecules with noble metals are shown with particular reference to the photophysical properties aiming at furnishing to the reader a panoramic view of these exciting problematics. In this respect, the following will be shown: (i) the principles of self-assembly of amphiphiles that involve noble metals, (ii) examples of amphiphiles and amphiphile-noble metal systems as representatives of systems with enhanced photophysical properties, and (iii) final comments and perspectives with some examples of modern applications.


Polymer ◽  
2020 ◽  
pp. 123259
Author(s):  
Youwei Ma ◽  
Qingchen Ren ◽  
Zhiyong Liu ◽  
Kaiqi Wang ◽  
Shuai Zhou ◽  
...  

2021 ◽  
Author(s):  
Daniela M. Zanata ◽  
Maria Isabel Felisberti

Amphiphilic and stimuli-responsive triblock copolymers are an important class of smart materials due to their low critical micellar concentration in solution and capacity of self-assembly into different structures depending on...


2019 ◽  
Vol 2019 ◽  
pp. 1-18 ◽  
Author(s):  
Dinesh K. Patel ◽  
Yu-Ri Seo ◽  
Ki-Taek Lim

Stimuli-responsive materials, also known as smart materials, can change their structure and, consequently, original behavior in response to external or internal stimuli. This is due to the change in the interactions between the various functional groups. Graphene, which is a single layer of carbon atoms with a hexagonal morphology and has excellent physiochemical properties with a high surface area, is frequently used in materials science for various applications. Numerous surface functionalizations are possible for the graphene structure with different functional groups, which can be used to alter the properties of native materials. Graphene-based hybrids exhibit significant improvements in their native properties. Since functionalized graphene contains several reactive groups, the behavior of such hybrid materials can be easily tuned by changing the external conditions, which is very useful in biomedical applications. Enhanced cell proliferation and differentiation of stem cells was reported on the surfaces of graphene-based hybrids with negligible cytotoxicity. In addition, pH or light-induced drug delivery with a controlled release rate was observed for such nanohybrids. Besides, notable improvements in antimicrobial activity were observed for nanohybrids, which demonstrated their potential for biomedical applications. This review describes the physiochemical properties of graphene and graphene-based hybrid materials for stimuli-responsive drug delivery, tissue engineering, and antimicrobial applications.


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