Achieving molecular weight distribution shape control and broad dispersities using RAFT polymerizations

Polymer Chemistry ◽

10.1039/d1py00399b ◽

2021 ◽

Author(s):

Stephanie I. Rosenbloom ◽

Renee J. Sifri ◽

Brett P. Fors

Keyword(s):

Molecular Weight ◽

Molecular Weight Distribution ◽

Weight Distribution ◽

Shape Control ◽

Chain Transfer ◽

Distribution Shape ◽

Reversible Addition ◽

Transfer Agents

Metered additions of chain transfer agents are used to control molecular weight distribution (MWD) features in reversible addition-fragmentation chain-transfer polymerizations, giving polymers with tailored MWD shapes and dispersities as high as 6.2.

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Multiblock Copolymer Synthesis via Reversible Addition–Fragmentation Chain Transfer Emulsion Polymerization: Effects of Chain Mobility within Particles on Control over Molecular Weight Distribution

Macromolecules ◽

10.1021/acs.macromol.1c00345 ◽

2021 ◽

Author(s):

Glenn K. K. Clothier ◽

Thiago R. Guimarães ◽

Graeme Moad ◽

Per B. Zetterlund

Keyword(s):

Molecular Weight ◽

Emulsion Polymerization ◽

Molecular Weight Distribution ◽

Weight Distribution ◽

Chain Transfer ◽

Multiblock Copolymer ◽

Chain Mobility ◽

Reversible Addition

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Molecular-Weight Distribution of Living Chains in Polystyrene Prepared by Reversible Addition–Fragmentation Chain-Transfer Polymerization

Macromolecules ◽

10.1021/acs.macromol.9b01331 ◽

2019 ◽

Vol 52 (19) ◽

pp. 7448-7455 ◽

Cited By ~ 3

Author(s):

Kyoungho Kim ◽

Junyoung Ahn ◽

Mirim Park ◽

Hana Lee ◽

Yeon Ji Kim ◽

...

Keyword(s):

Molecular Weight ◽

Molecular Weight Distribution ◽

Weight Distribution ◽

Chain Transfer ◽

Reversible Addition ◽

Chain Transfer Polymerization

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Effect of polyfunctional chain transfer agents on the molecular weight distribution in free-radical polymerization, 3 Polymerization of methyl methacrylate in the presence of polyfunctional chain transfer agents

Macromolecular Chemistry and Physics ◽

10.1002/macp.1995.021960915 ◽

1995 ◽

Vol 196 (9) ◽

pp. 2905-2913 ◽

Cited By ~ 12

Author(s):

Cui Ming Yuan ◽

Giuseppe Di Silvestro

Keyword(s):

Molecular Weight ◽

Free Radical ◽

Methyl Methacrylate ◽

Radical Polymerization ◽

Molecular Weight Distribution ◽

Weight Distribution ◽

Chain Transfer ◽

Free Radical Polymerization ◽

Transfer Agents

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Molecular weight distribution and controllability in living polymerization with chain-transfer agents

Polymer ◽

10.1016/s0032-3861(97)00625-3 ◽

1998 ◽

Vol 39 (13) ◽

pp. 2789-2793 ◽

Cited By ~ 2

Author(s):

Jin-Wuk Kim ◽

Ki-Jun Lee ◽

Hong H. Lee

Keyword(s):

Molecular Weight ◽

Molecular Weight Distribution ◽

Weight Distribution ◽

Chain Transfer ◽

Living Polymerization ◽

Transfer Agents

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Effect of polyfunctional chain transfer agents on molecular weight distribution in free-radical polymerization, 1. The ideal case: C equals one

Macromolecular Theory and Simulations ◽

10.1002/mats.1994.040030116 ◽

1994 ◽

Vol 3 (1) ◽

pp. 193-202 ◽

Cited By ~ 8

Author(s):

Cui Ming Yuan ◽

Giuseppe Di Silvestro ◽

Mario Farina

Keyword(s):

Molecular Weight ◽

Free Radical ◽

Radical Polymerization ◽

Molecular Weight Distribution ◽

Weight Distribution ◽

Chain Transfer ◽

Free Radical Polymerization ◽

Ideal Case ◽

The Ideal ◽

Transfer Agents

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Random Sampling Technique To Predict the Molecular Weight Distribution in Free-Radical Polymerization That Involves Polyfunctional Chain Transfer Agents

Macromolecules ◽

10.1021/ma950693h ◽

1996 ◽

Vol 29 (2) ◽

pp. 693-704 ◽

Cited By ~ 21

Author(s):

Hidetaka Tobita

Keyword(s):

Molecular Weight ◽

Free Radical ◽

Radical Polymerization ◽

Molecular Weight Distribution ◽

Weight Distribution ◽

Random Sampling ◽

Chain Transfer ◽

Free Radical Polymerization ◽

Sampling Technique ◽

Transfer Agents

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Molecular weight distribution formed during free-radical polymerization in the presence of polyfunctional chain transfer agents

Journal of Polymer Science Part B Polymer Physics ◽

10.1002/(sici)1099-0488(19990615)37:12<1267::aid-polb7>3.0.co;2-2 ◽

1999 ◽

Vol 37 (12) ◽

pp. 1267-1275 ◽

Cited By ~ 3

Author(s):

Hidetaka Tobita ◽

Tetsuya Mima ◽

Akinobu Okada ◽

Junichi Mori ◽

Toshio Tanabe

Keyword(s):

Molecular Weight ◽

Free Radical ◽

Radical Polymerization ◽

Molecular Weight Distribution ◽

Weight Distribution ◽

Chain Transfer ◽

Free Radical Polymerization ◽

Transfer Agents

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Modeling the molecular weight distribution of block copolymer formation in a reversible addition-fragmentation chain transfer mediated living radical polymerization

Journal of Polymer Science Part A Polymer Chemistry ◽

10.1002/pola.21069 ◽

2005 ◽

Vol 43 (22) ◽

pp. 5643-5651 ◽

Cited By ~ 55

Author(s):

Michael J. Monteiro

Keyword(s):

Molecular Weight ◽

Block Copolymer ◽

Radical Polymerization ◽

Molecular Weight Distribution ◽

Weight Distribution ◽

Chain Transfer ◽

Living Radical Polymerization ◽

Reversible Addition

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Effect of polyfunctional chain transfer agents on molecular weight distribution in free-radical polymerization, 2. The case C ≤ 1

Macromolecular Theory and Simulations ◽

10.1002/mats.1994.040030117 ◽

1994 ◽

Vol 3 (1) ◽

pp. 203-218 ◽

Cited By ~ 5

Author(s):

Cui Ming Yuan ◽

Mario Farina

Keyword(s):

Molecular Weight ◽

Free Radical ◽

Radical Polymerization ◽

Molecular Weight Distribution ◽

Weight Distribution ◽

Chain Transfer ◽

Free Radical Polymerization ◽

Transfer Agents

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New Telechelic Polymers and Sequential Copolymers by Polyfunctional Initiator-Transfer Agents (Inifers). VI. Chain Transfer, Molecular Weight Distribution, and NMR Study of Telechelic α,ω-Di(tert-chloro)-polyisobutylene

Journal of Macromolecular Science Part A - Chemistry ◽

10.1080/00222338108066442 ◽

1981 ◽

Vol 15 (2) ◽

pp. 215-230 ◽

Cited By ~ 24

Author(s):

A. Fehérvári ◽

J. P. Kennedy ◽

F. Tüdös

Keyword(s):

Molecular Weight ◽

Molecular Weight Distribution ◽

Weight Distribution ◽

Chain Transfer ◽

Telechelic Polymers ◽

Nmr Study ◽

Transfer Agents

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