Multiblock Copolymer Synthesis via Reversible Addition–Fragmentation Chain Transfer Emulsion Polymerization: Effects of Chain Mobility within Particles on Control over Molecular Weight Distribution

2021 ◽  
Author(s):  
Glenn K. K. Clothier ◽  
Thiago R. Guimarães ◽  
Graeme Moad ◽  
Per B. Zetterlund
Keyword(s):  
Molecular Weight ◽  
Emulsion Polymerization ◽  
Molecular Weight Distribution ◽  
Weight Distribution ◽  
Chain Transfer ◽  
Multiblock Copolymer ◽  
Chain Mobility ◽  
Reversible Addition

Catalytic Chain Transfer Mediated Emulsion Polymerization: Compartmentalization and Its Effects on the Molecular Weight Distribution

2010 ◽  
Vol 43 (13) ◽  
pp. 5647-5658 ◽  
Author(s):  
Mary E. Thomson ◽  
Niels M. B. Smeets ◽  
Johan P. A. Heuts ◽  
Jan Meuldijk ◽  
Michael F. Cunningham
Keyword(s):  
Molecular Weight ◽  
Emulsion Polymerization ◽  
Molecular Weight Distribution ◽  
Weight Distribution ◽  
Chain Transfer ◽  
Catalytic Chain Transfer

Achieving molecular weight distribution shape control and broad dispersities using RAFT polymerizations

2021 ◽  
Author(s):  
Stephanie I. Rosenbloom ◽  
Renee J. Sifri ◽  
Brett P. Fors
Keyword(s):  
Molecular Weight ◽  
Molecular Weight Distribution ◽  
Weight Distribution ◽  
Shape Control ◽  
Chain Transfer ◽  
Distribution Shape ◽  
Reversible Addition ◽  
Transfer Agents

Metered additions of chain transfer agents are used to control molecular weight distribution (MWD) features in reversible addition-fragmentation chain-transfer polymerizations, giving polymers with tailored MWD shapes and dispersities as high as 6.2.

Effect of chain transfer with fracture on the molecular weight distribution of polymers and oligomers

1965 ◽  
Vol 7 (10) ◽  
pp. 2015-2020 ◽  
Author(s):  
V.V. Ivanov ◽  
A.A. Shaginyan ◽  
V.P. Volkov ◽  
N.S. Yenikolopyan
Keyword(s):  
Molecular Weight ◽  
Molecular Weight Distribution ◽  
Weight Distribution ◽  
Chain Transfer
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