scholarly journals An experimental and computational study for a Pd(II) catalysed hydroboration and reductive amination reaction of carbonyl compounds

2022 ◽  
Author(s):  
Tarun Kanti Panda ◽  
Shreya Mahato ◽  
Parveen Rawal ◽  
Ajitaro Devadkar ◽  
Mayank Joshi ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Reductive Amination ◽  
Computational Study ◽  
Catalytic Application ◽  
Amination Reaction ◽  
Salen Ligand

We report the synthesis, characterisation, and catalytic application of a palladium (II) complex [(4-{1,2-C6H4(N=CH-C6H4O)2}Pd] (1) supported by a dianionic salen ligand [1,2-C6H4(N=CH-C6H4O)2]2- (L) as a molecular pre-catalyst for the hydroboration...

One-Pot Reductive Amination of Carbonyl Compounds Using Sodium Borohydride–Amberlyst 15

2010 ◽  
Vol 40 (7) ◽  
pp. 951-956 ◽  
Author(s):  
Heshmatollah Alinezhad ◽  
Mahmood Tajbakhsh ◽  
Nastaran Mahdavi
Keyword(s):  
Sodium Borohydride ◽  
Carbonyl Compounds ◽  
Reductive Amination ◽  
One Pot ◽  
Amberlyst 15

Ambient-Temperature Synthesis of Primary Amines via Reductive Amination of Carbonyl Compounds

ACS Catalysis ◽  
2020 ◽  
Vol 10 (14) ◽  
pp. 7763-7772 ◽  
Author(s):  
Chao Xie ◽  
Jinliang Song ◽  
Manli Hua ◽  
Yue Hu ◽  
Xin Huang ◽  
...  
Keyword(s):  
Ambient Temperature ◽  
Carbonyl Compounds ◽  
Reductive Amination ◽  
Primary Amines ◽  
Temperature Synthesis

scholarly journals Computational investigation of the control of the thermodynamics and microkinetics of the reductive amination reaction by solvent coordination and a co-catalyst

RSC Advances ◽  
2018 ◽  
Vol 8 (64) ◽  
pp. 36662-36674 ◽  
Author(s):  
Esra Boz ◽  
Nurcan Ş. Tüzün ◽  
Matthias Stein
Keyword(s):  
Tertiary Amine ◽  
Reductive Amination ◽  
Computational Investigation ◽  
Reaction Parameters ◽  
Co Catalyst ◽  
Amination Reaction ◽  
Green Production

Green production of tertiary amine from sustainable sources can be controlled by appropriate choice of reaction parameters identified by computational means.

N-Phenyl-Substituted Pyrrolidines, Piperidines and Azabicyclics by a Tandem Reduction-Double Reductive Amination Reaction.

ChemInform ◽  
2003 ◽  
Vol 34 (26) ◽  
Author(s):  
Richard A. Bunce ◽  
Derrick M. Herron ◽  
Jason R. Lewis ◽  
Sharadsrikar V. Kotturi
Keyword(s):  
Reductive Amination ◽  
Amination Reaction

The effects of added ammonium chloride in the reductive amination of some carbonyl compounds over Ru and Pd catalysts

Tetrahedron ◽  
2005 ◽  
Vol 61 (8) ◽  
pp. 2105-2109 ◽  
Author(s):  
Tomoaki Ikenaga ◽  
Kumiko Matsushita ◽  
Junichi Shinozawa ◽  
Satoru Yada ◽  
Yuzuru Takagi
Keyword(s):  
Ammonium Chloride ◽  
Carbonyl Compounds ◽  
Reductive Amination ◽  
Pd Catalysts

Synthesis of tertiary amines by direct Brønsted acid catalyzed reductive amination

2020 ◽  
Vol 56 (61) ◽  
pp. 8691-8694
Author(s):  
Mohanad A. Hussein ◽  
An H. Dinh ◽  
Vien T. Huynh ◽  
Thanh Vinh Nguyen
Keyword(s):  
Carbonyl Compounds ◽  
Reductive Amination ◽  
Bronsted Acid ◽  
Tertiary Amines ◽  
Brønsted Acid ◽  
Triflic Acid ◽  
Brönsted Acid ◽  
Acid Catalyzed

Triflic acid efficiently promotes the reductive amination reactions of carbonyl compounds on a broad range of substrates.

scholarly journals Synthesis and structural characterization of amino-functionalized polysaccharides

2009 ◽  
Vol 7 (1) ◽  
pp. 66-73 ◽  
Author(s):  
Ioana Sisu ◽  
Valentina Udrescu ◽  
Corina Flangea ◽  
Sorin Tudor ◽  
Nicolae Dinca ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Thermal Analysis ◽  
Reductive Amination ◽  
Average Molecular Weight ◽  
Polymer Surface ◽  
Building Blocks ◽  
Collision Induced Dissociation ◽  
Amination Reaction ◽  
Composition And Structure

AbstractA variety of carbohydrates, in particular polysaccharides can be subjected to chemical modification to obtain derivatives with amphiphilic properties, which enable biochemical or biological reactions at the polymer surface. In the present work, a polydisperse maltodextrin mixture of average molecular weight 3000 was coupled with 1,6-hexamethylenediamine (HMD) via reductive amination reaction. Resulting products were characterized by thermal analysis and positive nanoelectrospray quadrupole time-of-flight (Q-TOF) mass spectrometry (MS) and tandem mass spectrometry (MS/MS). Both thermal analysis and MS screening confirmed the formation of the HMD-polysaccharide coupling products. Moreover, HMD-linked polysaccharide chains containing 2 to 26 glucose building blocks were identified by nanoESI Q-TOF MS. MS/MS fragmentation using collision-induced dissociation (CID) at low ion acceleration energies provided strong evidence for HMD-maltodextrin linkage formation and the set of sequence ions diagnostic for the composition and structure of a HMD-linked chain containing 18 glucose residues.

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