Iridium-catalyzed highly stereoselective deoxygenation of tertiary cycloalkanols: stereoelectronic insights and synthetic applications

2021 ◽  
Author(s):  
Tingting Wang ◽  
Yang Chen ◽  
Ning Chen ◽  
Jiaxi Xu ◽  
Zhanhui Yang
Keyword(s):  
Tertiary Cycloalkanols

The sterically large iridium hydride delivers its hydride to the carbocation from the sterically least hindered direction of attack.

β-Amino tertiary cycloalkanols for the enantioselective protonation of enolic species produced by a palladium-induced cascade reaction

1998 ◽  
Vol 9 (11) ◽  
pp. 1847-1850 ◽  
Author(s):  
S.Jamal Aboulhoda ◽  
I. Reiners ◽  
J. Wilken ◽  
F. Hénin ◽  
J. Martens ◽  
...  
Keyword(s):  
Cascade Reaction ◽  
Tertiary Cycloalkanols

ChemInform Abstract: Novel Fluorination of Small-Ring Tertiary Cycloalkanols: Reaction of Diethylaminosulfur Trifluoride with Tertiary Cyclobutanols.

ChemInform ◽  
2010 ◽  
Vol 30 (15) ◽  
pp. no-no
Author(s):  
Masayuki Kirihara ◽  
Tomofumi Takuwa ◽  
Toshihiro Kambayashi ◽  
Takefumi Momose ◽  
Yoshio Takeuchi
Keyword(s):  
Small Ring ◽  
Tertiary Cycloalkanols

Alkynylation of Tertiary Cycloalkanols via Radical C–C Bond Cleavage: A Route to Distal Alkynylated Ketones

2015 ◽  
Vol 17 (19) ◽  
pp. 4798-4801 ◽  
Author(s):  
Shun Wang ◽  
Li−Na Guo ◽  
Hua Wang ◽  
Xin-Hua Duan
Keyword(s):  
Bond Cleavage ◽  
Tertiary Cycloalkanols

Novel Fluorination of Small-ring Tertiary Cycloalkanols: Reaction of Diethylaminosulfur Trifluoride with Tertiary Cyclobutanols

1998 ◽  
pp. 652-653 ◽  
Author(s):  
Masayuki Kirihara ◽  
Tomofumi Takuwa ◽  
Toshihiro Kambayashi ◽  
Takefumi Momose ◽  
Yoshio Takeuchi
Keyword(s):  
Small Ring ◽  
Tertiary Cycloalkanols

ChemInform Abstract: β-Amino Tertiary Cycloalkanols for the Enantioselective Protonation of Enolic Species Produced by a Palladium-Induced Cascade Reaction.

ChemInform ◽  
2010 ◽  
Vol 29 (41) ◽  
pp. no-no
Author(s):  
S. J. ABOULHODA ◽  
I. REINERS ◽  
J. WILKEN ◽  
F. HENIN ◽  
J. MARTENS ◽  
...  
Keyword(s):  
Cascade Reaction ◽  
Tertiary Cycloalkanols

Transition-metal free alkylarylation of acrylamides initiated by radical C–C bond cleavage of the tertiary cycloalkanols

RSC Advances ◽  
2016 ◽  
Vol 6 (32) ◽  
pp. 27000-27003 ◽  
Author(s):  
Li-Na Guo ◽  
Zhi-Qiang Deng ◽  
Yong Wu ◽  
Jie Hu
Keyword(s):  
Transition Metal ◽  
Formation Process ◽  
Bond Cleavage ◽  
Radical Cyclization ◽  
Cyclization Reaction ◽  
One Pot ◽  
Metal Free ◽  
Tertiary Cycloalkanols

An efficient Na2S2O8-promoted radical cyclization reaction of acrylamides with the tertiary cycloalkanols has been developed. This one pot procedure involves a tandem C–C bond cleavage and two C–C bonds formation process.

Silver-catalyzed C2-selective direct alkylation of heteroarenes with tertiary cycloalkanols

2017 ◽  
Vol 15 (2) ◽  
pp. 324-327 ◽  
Author(s):  
Shi-Chao Lu ◽  
Hong-Shuang Li ◽  
Shu Xu ◽  
Gui-Yun Duan
Keyword(s):  
Tertiary Cycloalkanols

A silver-catalyzed regioselective C2-alkylation of heteroarenes with primary radicals produced by tertiary cycloalkanols was developed.

Ag-Catalyzed Ring-Opening of Tertiary Cycloalkanols for C-H Functionalization of Cyclic Aldimines

2021 ◽  
Author(s):  
Jingjing Wang ◽  
Xue Liu ◽  
Ziyan Wu ◽  
Feng Li ◽  
Ming-liang Zhang ◽  
...  
Keyword(s):  
Ring Opening ◽  
Bond Cleavage ◽  
Tertiary Cycloalkanols

We firstly describe a silver-catalyzed direct C–H functionalization of cyclic aldimines with cyclopropanols and cyclobutanols via radical-mediated C-C bond cleavage strategy. The desired products were generated in decent yields with...

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